Fluidized bed reactor

A fluidized bed reactor and reactor technology, applied in chemical instruments and methods, chemical/physical processes, etc., can solve problems such as high maintenance costs of circulating oil pumps, low reactor space utilization, and catalyst sinking and accumulation, etc., to achieve Shorten the residence time, improve the operation stability, and improve the effect of fluidization quality

Active Publication Date: 2012-01-25
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] US Re 25,770 describes a typical fluidized bed process, which adopts the operation mode of circulating oil pump, but this process method has the following shortcomings in practical application: less catalyst storage in the reactor, low space utilization of the reactor; circulating oil pump maintenance The maintenance cost is high, and once the circulating oil pump is malfunctioning or damaged, it will cause the catalyst to sink and accumulate, resulting in the forced shutdown of the device; It is easy to carry out secondary thermal cracking reaction coking and reduce product quality
The difference in flow rate increases with the diameter of the reactor, which may lead to coalescence of bubbles, formation of large bubbles, insufficient contact between gas and liquid phases, and poor fluidization

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment -1

[0032] Such as figure 1 For the structure of the ebullating bed hydrogenation reactor shown, the cold model test of the three-phase separator ebullating bed medium-sized reactor was carried out. The dimensions of the cold model medium-sized device are: the inner diameter of the reactor shell = 160mm, the height of the reactor shell = 3000mm, the effective volume of the shell is 60L, the height of the separator = 500mm, the diameter of the cylindrical part of the central tube of the separator = 135mm, the diameter of the upper opening of the inner cylinder = 190mm, the height of the cylindrical part of the lower part of the inner cylinder = 35mm, the diameter of the cylindrical part of the outer cylinder =160mm, the diameter of the upper opening of the tapered part of the outer cylinder = 285mm, the height of the cylindrical lower part of the outer cylinder = 30mm, the upper opening of the outer cylinder is higher than the upper opening of the inner cylinder, the lower opening o...

Embodiment -2

[0035] On the basis of the cold model test, a hydrodemetallization test of an island atmospheric residue was carried out on a 60L medium-sized unit. Wherein the size of the reactor is the same as in Example 1, and the test conditions and results are shown in Table 2.

Embodiment -3

[0043] The operating conditions are the same as in Example-1. The middle part of the ebullating bed reactor is provided with an internal member, which is a diamond-shaped cone with a certain cross-sectional area. %, it can guide the fluid, promote the distribution of the continuous phase and the dispersed phase, inhibit the formation and coalescence of large bubbles, improve the fluidization quality, make the radial velocity distribution of the fluid more uniform, and at the same time interfere with the strong turbulent flow and improve the transmission efficiency. Mass and heat transfer efficiency, the process is strengthened. It can be seen that the mass transfer rate increases with internals and better fluidization quality can be obtained.

[0044] Table 3 Comparison results with and without internal components

[0045]

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Abstract

The invention discloses a fluidized bed reactor comprising a reactor shell and a three-phase separator, wherein the three-phase separator is arranged at the upper part inside the reactor shell and is in a sleeve structure including an inner sleeve and an outer sleeve; the upper ends and the lower ends of the inner sleeve and the outer sleeve are in opened structures; the inner sleeve and the outer sleeve both comprise upper segments and lower segments which are connected with each other; the upper segments of the inner sleeve and the outer sleeve are both in reversed frustum-shaped structures, and the lower segments of the inner sleeve and the outer sleeve are both in cylinder-shaped structures; and an opening positioned on the upper end of the outer sleeve is higher than an opening positioned on the upper end of the inner sleeve. The fluidized bed reactor is mainly suitable for chemical reaction carried out under the condition that different liquid and gaseous matters contact with solid particles, has the advantages of large catalyst inventory, high reactor utility ratio, simple structure and easy operation and is suitable for long-periodic stable operation, and the like.

Description

technical field [0001] The invention relates to a gas-liquid-solid three-phase ebullating bed reactor, in particular to an improved three-phase ebullating bed hydrogenation for chemical reaction under the condition that different kinds of liquid and gas substances flow upward and contact with solid particles reactor. Background technique [0002] The heavy oil fluidized bed hydrogenation reactor belongs to the gas, liquid and solid three-phase fluidized bed reactor, which can process heavy and low-quality raw material oil with high metal and high asphaltene content, and has the advantages of small pressure drop, uniform temperature distribution, and can maintain the whole operation The catalyst activity in the periodic reactor is uniform, and fresh catalyst can be added and spent catalyst can be taken out during operation. [0003] US Re 25,770 describes a typical fluidized bed process, which adopts the operation mode of circulating oil pump, but this process method has the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/22
Inventor 刘建锟杨涛贾丽胡长禄陈涛
Owner CHINA PETROLEUM & CHEM CORP
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