High temperature resistant metal passivator

A metal passivator and high-temperature-resistant technology, applied in the coating process of metal materials, etc., can solve problems such as environmental pollution, surface corrosion of steel parts, high cost, etc., achieve broad social and economic benefits, good corrosion resistance, and reduce cleaning The effect of water

Inactive Publication Date: 2010-07-14
中国地质大学佛山研究院 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although chromate is used as a passivator with low cost and good corrosion resistance, it has high toxicity and is easy to cause cancer. After discharge, it will cause great pollution to the environment and is difficult to treat. Therefore, the use of chromate is strictly restricted.
[0005] Organic passivators are more expensive and emit various pungent odors. Long-term exposure has carcinogenic effects. Passivators are prone to produce bacteria, deteriorating water bodies and causing environmental pollution problems.
[000

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0029] Example 1

[0030] Under normal temperature and pressure, combine 93-95% by mass of water, 1-2% by mass of phosphate, 0.5-1% by mass of accelerator, 0.05-0.1% by mass of surfactant, 3 to 4 % By mass of high-temperature resistant passivation components are mixed and stirred for 5-10 minutes to prepare a high-temperature resistant metal passivation agent.

[0031] The phosphate can be one of disodium hydrogen phosphate, sodium dihydrogen phosphate, and sodium phosphate; the accelerator can be one of cerous carbonate dihydrate, cerium nitrate, and cerium nitrate; the surfactant can be Use one of OP-10, TX-100 and NP-5 or a mixed compound;

[0032] When the surface active agents OP-10, TX-100 and NP-5 are mixed, they are mixed according to a mass ratio of 2:1:1.

[0033] The high-temperature resistant passivation component can be one of zirconyl chloride and zirconyl nitrate; the passivation agent is adjusted with phosphoric acid, and its pH value is 3.0-5.0.

[0034] After the hig...

Example Embodiment

[0035] Example 2

[0036] Under normal temperature and pressure, mix 93% by mass of water, 2% by mass of phosphate, 0.5% by mass of accelerator, 0.1% by mass of surfactant, and 4% by mass of high-temperature passivation ingredients. , Stir for 5 minutes to prepare a high temperature resistant metal passivator.

[0037] The phosphate can be disodium hydrogen phosphate; the accelerator can be cerous carbonate dihydrate; the surfactant can be OP-10;

[0038] The high temperature resistant passivation component can be zirconyl chloride; the passivation agent is adjusted with phosphoric acid, and its pH value is 5.0.

[0039] After the high temperature resistant metal passivator is prepared, the steel can be passivated by dip coating or spraying.

Example Embodiment

[0040] Example 3

[0041] Under normal temperature and pressure, mix 95% by mass of water, 1% by mass of phosphate, 0.5% by mass of accelerator, 0.1% by mass of surfactant, and 3% by mass of high-temperature passivation ingredients. , Stir for 10 minutes to prepare a high temperature resistant metal passivator.

[0042] The phosphate can be sodium dihydrogen phosphate; the accelerator can be cerium nitrate; the surfactant can be TX-100;

[0043] The high temperature resistant passivation component can be zirconyl nitrate; the passivation agent is adjusted with phosphoric acid, and its pH value is 4.5.

[0044] After the high temperature resistant metal passivator is prepared, the steel can be passivated by dip coating or spraying.

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PUM

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Abstract

The invention relates to a high temperature resistant metal passivator, wherein the main raw materials thereof comprise the following components in percentage by mass: 93-95 percent of water, 1-2 percent of phosphate, 0.5-1 percent of accelerant, 0.05-0.1 percent of surfactant and 3-4 percent of high temperature resistant passivation component. The phosphate is one of disodium hydrogen phosphate, monobasic sodium phosphate and sodium phosphate; the accelerant is one of cerium carbonate dehydrate, cerium nitrate and cerous nitrate; the surfactant is one or the mixed compound of OP-10, TX-100 and NP-5, and the mass ratio of the mixed compound is 2:1:1; the high temperature resistant passivation component is one of zirconyl chloride and zirconyl nitrate; and the passivator is regulated through a phosphoric acid, and the pH value thereof is 3.0-5.0. A layer of uniform and compact passivation film is rapidly formed on the surface of a steel material processed through the high temperature resistant metal passivator, the film has strong corrosion-resistant performance, and a passivated steel part has good corrosion-resistant performance whether blow-dried or dried at the temperature of 200-250 DEG C.

Description

technical field [0001] The invention relates to a passivator, in particular to a high temperature resistant metal passivator. Background technique [0002] Spraying on the surface of steel materials is a common process. Before spraying, in order to improve the adhesion between the paint and the metal substrate and prevent surface corrosion, phosphating and passivation treatment methods must be adopted. [0003] At present, there are generally three types of passivating agents used for steel passivation treatment, namely: chromate, molybdate and organic passivating agent. [0004] Although chromate is used as a passivator with low cost and good corrosion resistance, it has high toxicity and is easy to cause cancer. After discharge, it causes great pollution to the environment and is difficult to treat. Therefore, the use of chromate is strictly restricted. [0005] Organic passivators are expensive, and emit various irritating odors. Long-term exposure has carcinogenic effec...

Claims

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Application Information

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IPC IPC(8): C23C22/07
Inventor 皮振邦李超高建平高丽丽
Owner 中国地质大学佛山研究院
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