Dicing die-bonding film
A chip-bonding film and cutting film technology, applied in the direction of pressure-sensitive film/sheet, polyurea/polyurethane adhesive, film/sheet-shaped adhesive, etc., can solve the problem of not being able to easily pick up semiconductor chips, difficult to obtain cutting/ Die-bonding film, large area, etc., to achieve the effect of preventing the disappearance of the boundary surface, good pick-up, and realizing the peeling force
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Embodiment 1
[0097]
[0098] In a reaction vessel with a condenser tube, a nitrogen inlet tube, a thermometer and a stirring device, add 88.8 parts of 2-ethylhexyl acrylate (hereinafter referred to as "2EHA"), 11.2 parts of 2-hydroxyethyl acrylate (hereinafter referred to as "HEA"), 0.2 parts of benzoyl peroxide, and 65 parts of toluene were polymerized in a nitrogen stream at 61° C. for 6 hours to obtain an acrylic polymer A with a weight average molecular weight of 850,000. The weight average molecular weight is as follows. The molar ratio of 2EHA to HEA is 100 moles: 20 moles.
[0099] 12 parts (80 mol% with respect to HEA) of 2-methacryloyloxyethyl isocyanate (hereinafter referred to as "MOI") was added to this acrylic polymer A, and the process was carried out at 50° C. for 48 hours in an air stream. Addition reaction treatment gave acrylic polymer A'.
[0100] Then, 8 parts of polyisocyanate compound (trade name "Coroneto L", manufactured by Nippon Polyurethane Co., Ltd.) and 5 p...
Embodiment 2~15
[0116] In each of Examples 2-15, except having changed into the composition and content shown in following Table 1, it carried out similarly to said Example 1, and produced the dicing / die-bonding film.
[0117]
[0118] In addition, the meanings of the abbreviations described in Table 1 and Table 2 described later are as follows.
[0119] 2EHA: 2-Ethylhexyl Acrylate
[0120] i-OA: Isooctyl acrylate
[0121] i-NA: Isononyl Acrylate
[0122] BA: n-butyl acrylate
[0123] LA: lauryl acrylate
[0124] AA: Acrylic
[0125] HEA: 2-Hydroxyethyl Acrylate
[0126] 4HBA: 4-Hydroxybutyl Acrylate
[0127] AOI: 2-acryloyloxyethyl isocyanate
[0128] C / L: polyisocyanate compound (trade name "Coroneto L", manufactured by Nippon Polyurethane Co., Ltd.)
[0129] T / C: Epoxy crosslinking agent (trade name "Tetrade C", manufactured by Mitsubishi Gas Chemical Co., Ltd.)
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