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Adhesive article comprising an acrylic foam layer

An adhesive and foam layer technology, applied in film/sheet adhesives, adhesive types, ester copolymer adhesives, etc., can solve problems such as environmental management and processing costs affecting product formulation requirements

Inactive Publication Date: 2015-01-14
3M INNOVATIVE PROPERTIES CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition to performance characteristics, environmental management and processing costs also affect product formulation requirements

Method used

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  • Adhesive article comprising an acrylic foam layer
  • Adhesive article comprising an acrylic foam layer
  • Adhesive article comprising an acrylic foam layer

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment

[0014] The specific embodiments of the present invention are summarized as follows:

[0015] 1. An adhesive article comprising: a foam layer having first and second major sides; a pressure sensitive adhesive layer attached to at least one of the major sides of the foam layer, the pressure sensitive adhesive The layer comprises cross-linked rubber, wherein said foam layer comprises an acrylic polymer obtainable by polymerizing a polymerizable composition comprising one or more compounds having an average of 3 to 14 carbon atoms in the alkyl group Alkyl acrylate, one or more polar monomers and one or more polyfunctional monomers having at least two radically polymerizable groups.

[0016] 2. The adhesive article of embodiment 1, wherein the polymerizable composition comprises 83 to 97% by weight of the alkyl acrylate, 3 to 16% by weight of the polar monomer and 0.01 to 1% by weight of the polyfunctional monomer.

[0017] 3. The adhesive article of embodiment 1 or 2, wherein th...

example

[0116] testing method :

[0117] Dynamic Shear Test :

[0118] A modified version of ISO4587:2003 is adopted.

[0119] The strip to be tested is applied with its specific side to the painted steel substrate. On the opposite side of the tape, aluminum coupons (50 mm x 25 mm x 1 mm) were applied.

[0120] The adhesive tape area applied horizontally was 1.27 cm x 2.54 cm.

[0121] Painted steel panels used in this test method were obtained from the suppliers mentioned in a separate section below. Basic instructions on said paints are also provided in a separate section below.

[0122] Paint A and Paint B were cleaned by wiping with a tissue soaked in n-heptane. Paint C was cleaned by wiping with a tissue soaked in a 1:1 volume mixture of water and isopropanol. For testing, the painted steel sheet substrates were cut into test pieces (50 mm x 30 mm x 1 mm).

[0123] Subject the aluminum coupons to Scotchbrite TM no.7447 TM Light abrasiveness of a scrub pad (available ...

example A

[0160] The foam core (FC-1) having the composition shown in Table 3 was compounded according to the following procedure. Black pigmented EVA (4900 cmB) was dry fed into the first zone of a 90 mm co-rotating twin-screw extruder ("core extruder") (available from Berstorff, Hannover, Germany). Using a roll-fed extruder (available from Berstorff), both the acrylics AP-2 and AP-3 were heated and fed into the second zone of the core extruder. DUALITE U010-185D expandable microspheres (expandable microspheres having a shell composition comprising acrylonitrile and methacrylonitrile and an isopentane core, available from Henkel Corporation (Gulph Mills, Pennsylvania)) were fed into the core extrusion. Out of the Ninth District of the plane.

[0161] Table 3: Foam Core Composition FC-1 and Properties

[0162]

[0163]Three-layer coextruded tape samples were prepared by coextruding a first skin adhesive layer, a foamed core layer as an intermediate layer, and a second skin adhesi...

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Abstract

The present invention provides an adhesive article comprising a foam layer having first and second major sides and a pressure sensitive adhesive layer associated with at least one of the major sides for the foam layer, said pressure sensitive adhesive layer comprising a cross-linked rubber and wherein the foam layer comprises an acrylic polymer obtainable by polymerization a polymerizable composition comprising one or more alkyl acrylates having an average of 3 to 14 carbon atoms in the alkyl groups, one or more polar monomers and one or more multi-functional monomers having at least two free radical polymerizable groups.

Description

technical field [0001] The present invention relates to an adhesive article comprising an acrylic foam layer and a pressure sensitive adhesive layer comprising crosslinked rubber. The invention also relates to the manufacture and use of said adhesive articles. Background technique [0002] Adhesives and tapes are commonly used to bond two substrates together to form bonded composites. Particular adhesive tapes include those having a foam layer. Such adhesive tapes or adhesive articles are used, for example, in the automotive industry where they can be used to bond various components to the body of an automobile or other motor vehicle. Typically, they are used to bond components such as logos, plastic parts, and rubber gaskets to doors. [0003] Examples of adhesive tapes are disclosed in eg WO 2008 / 070386, US 6,503,621 and US 4,415,615. [0004] While a large number of adhesives and tapes are available, substrate developments and end-use requirements continue to drive th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J7/02C09J153/00C09J7/26
CPCC09J7/0214C08J3/28C09J7/0221C08J2309/00C09J7/0289C09J2409/00C08F220/06C08F2220/1825C09J2453/00C08F220/18C09J2433/006C09J2433/00C09J7/26C09J7/383C09J7/387C08F220/1804Y10T428/249983C09J7/385C09J7/22C09J133/04
Inventor 西格弗里德·K·韦尔克沃尔克·帕谢尔曼尼
Owner 3M INNOVATIVE PROPERTIES CO
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