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Preparation method of microporous membrane with hydrophilicity and hydrophobicity

A microporous membrane and hydrophobic technology, applied in the field of preparation of microporous membranes, can solve the problems of easy change of stretched network pores, affecting filtration accuracy, and high technical difficulty, achieving stable and uniform shape of membrane pores, improving filtration efficiency, The effect of high filtration efficiency

Active Publication Date: 2014-05-14
上海一鸣过滤技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Advantages of PTFE: superior material performance, high filtration accuracy, low resistance, and low price; Disadvantages: It is difficult to change the technology into a hydrophilic membrane; since there is no support layer, the pores of the stretched network are easy to change, especially during the filtration process , the mesh hole is easy to expand and deform, which affects the filtration accuracy
Advantages of polyethersulfone membrane: superior material performance, high filtration accuracy, and stable membrane pore structure; disadvantages: high price, domestic continuous production cannot be achieved with current domestic technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A method for preparing a microporous membrane having both hydrophilicity and hydrophobicity, comprising the following steps:

[0021] (1) Put dimethylformamide in a jar, add 100g of polyethersulfone, add 80g of polyethylene glycol 400 as an additive, and 13g of glycerin, configure it to be fully dissolved, then airtightly stand for defoaming to obtain Casting solution;

[0022] (2) Control the temperature in the steam zone at 60°C and the relative humidity at 100%;

[0023] (3) Dip-coat the casting solution onto a polyester non-woven fabric with a thickness of 40 μm, and use a scraper to control the coating thickness to 200 μm. After evaporating for 5 minutes, measure the first bubble point pressure with a thickness of 25 μm using absolute ethanol as a medium The PTFE micro-membrane pores of 0.10MPA are compounded on one side on the polyester non-woven fabric soaked in the casting liquid. After being flattened by the device, they enter the steam area to form a film. Af...

Embodiment 2

[0025] A method for preparing a microporous membrane having both hydrophilicity and hydrophobicity, comprising the following steps:

[0026] (1) Preparation of casting solution for microporous membrane of hydrophilic support layer: first, dissolve sulfonated polyether sulfone in dimethylformamide solvent, and add polyvinyl acid as an additive to form a three-component membrane material / solvent / additive Element film making liquid, airtight defoaming, obtain coating liquid, the concentration of membrane material in this coating liquid is 5wt%, the concentration of additive is 2wt%;

[0027] (2) Phase conversion and composite film formation: Install polyester non-woven fabric on continuous film casting equipment, put the casting film solution into the material tank, use a scraper to dip the casting film solution evenly on the polyester non-woven fabric, After evaporating the solvent in the casting solution, compound a polytetrafluoroethylene microporous membrane on one side of th...

Embodiment 3

[0029] A method for preparing a microporous membrane having both hydrophilicity and hydrophobicity, comprising the following steps:

[0030] (1) Preparation of the casting solution for the microporous membrane of the hydrophilic support layer: firstly, nylon 6 is dissolved in formic acid solvent, and the additive calcium chloride is added to form a ternary membrane-making solution of membrane material / solvent / additive. Bubble, obtain coating solution, the concentration of membrane material in this coating solution is 18wt%, and the concentration of additive is 3wt%;

[0031] (2) Phase conversion and composite film formation: Install polyester non-woven fabric on continuous film casting equipment, put the casting film solution into the material tank, use a scraper to dip the casting film solution evenly on the polyester non-woven fabric, After evaporating the solvent in the casting solution, compound a polytetrafluoroethylene microporous membrane on one side of the polyester no...

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PUM

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Abstract

The invention relates to a preparation method of a microporous membrane with hydrophilicity and hydrophobicity. The preparation method comprises the following steps of: dissolving a membrane material into a solvent; adding an additive; defoaming hermetically to obtain a membrane coating liquid; coating the membrane coating liquid onto a polyester non-woven fabric; evaporating a solvent in the membrane coating liquid; compounding a hydrophobic control layer on one side of the polyester non-woven fabric; entering a steam region and performing phase transformation to gel into a membrane; and drying to obtain a product. Compared with the prior art, the preparation method has the advantages that: the microporous membrane with two different properties is obtained; the membrane hole shape of the microporous membrane is stable and uniform; during liquid filtering operation, the microporous membrane is convenient to use, so that the filtering efficiency and the filtering accuracy of the microporous membrane are increased; the entire microporous membrane has high porosity, and a control layer is very thin, so that filtering resistance is small, and the microporous membrane has very high filtering efficiencies on substances of over 0.2 mu during liquid filtering; and the microporous membrane is suitable for purifying processes such as degerming, fine particle removing and the like in industrial production.

Description

technical field [0001] The invention relates to a preparation method of a microporous membrane, in particular to a preparation method of a microporous membrane having both hydrophilicity and hydrophobicity. Background technique [0002] At present, it is often necessary to use two materials with different properties as filter media in the fine filtration process of materials in China. For example, in gas terminal filtration, domestic hydrophobic polytetrafluoroethylene biaxially stretched membrane is used as filter medium; in liquid terminal filtration, imported hydrophilic polyethersulfone phase conversion membrane is used as filter medium. Advantages of PTFE: superior material performance, high filtration accuracy, low resistance, and low price; Disadvantages: It is difficult to change the technology into a hydrophilic membrane; since there is no support layer, the pores of the stretched network are easy to change, especially during the filtration process , The mesh holes...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D69/02B01D69/10B01D69/12B01D67/00
Inventor 王革锋卢忠宝何秋良周浩
Owner 上海一鸣过滤技术有限公司
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