Low-temperature lead-acid battery cathode active substance and preparation method thereof

A negative electrode active material, lead-acid battery technology, applied in battery electrodes, circuits, electrical components, etc., can solve the problems of low temperature capacity and cycle life of batteries, affecting battery discharge performance, charging performance, etc., and achieve low temperature charging acceptance. Ability-enhancing effect

Inactive Publication Date: 2013-01-30
SHUANGDENG GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the continuous development of communication and energy storage fields, valve-regulated sealed lead-acid batteries are more and more applied to low-temperature environments, such as rural telecom repeaters in northern my country, alpine base stations, outdoor wind and solar energy storage applications, high-altitude Regions, etc. The valve-regulated sealed lead-acid batteries produced by the existing technology are used in the above-mentioned regions. In winter, the low-temperature capacity and cycle life will be reduced to below 70% of normal temperature in the environment below -10°C, and the low-temperature capacity in the environment of -40°C The cycle life will drop below 35% of that at normal temperature. The main reason is that the negative electrode active material of the valve-regulated sealed lead-acid battery produced by the existing technology will drop rapidly as the temperature decreases in the low-temperature environment, and the charging performance of the battery will be affected. , which in turn affects the discharge performance of the battery, resulting in a decrease in the low-temperature capacity and cycle life of the battery. Therefore, the development of a negative active material suitable for use in low-temperature environments has become the key to valve-regulated sealed lead-acid batteries suitable for use in low-temperature environments.

Method used

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  • Low-temperature lead-acid battery cathode active substance and preparation method thereof
  • Low-temperature lead-acid battery cathode active substance and preparation method thereof

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Embodiment Construction

[0013] The technical solutions and positive effects of the present invention are further described below through examples.

[0014] The components and mass percentages of low-temperature additives in Example 1 and Example 2 are shown in Table 1:

[0015] Table 1

[0016]

[0017] The components and mass percentages of the negative electrode active material in Example 1 and Example 2 are shown in Table 2:

[0018] Table 2

[0019]

[0020] In the table, the density of sulfuric acid is 1.32g / ml (25°C), and the binder is a common binder in this industry.

[0021] The preparation method of example one, example two is:

[0022] Prepare materials according to the proportions in Table 1 and Table 2: fully stir the prepared lead powder, binder, barium sulfate, lignin, and low-temperature additives in a dry state for 12 minutes (Example 1) and 13 minutes (Example 2) , add deionized water at a uniform speed within 7 minutes, stir while adding, continue stirring for 8 minutes (...

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Abstract

The invention relates to a low-temperature lead-acid battery cathode active substance and a preparation method thereof. The low-temperature lead-acid battery cathode active substance is formed by adding a low-temperature additive into lead powder, an adhesive, sulfuric acid, de-ionized water, barium sulfate and lignin components, wherein the low-temperature additive consists of a tanning agent, an mimosa extract, vapor-grown carbon fibers and humic acid. The components in the low-temperature lead-acid battery cathode active substance are reasonably proportioned and optimally combined, and a complete and standard preparation method is adopted; and pole plates manufactured from the manufactured cathode active substance can be assembled into a valve-regulated lead-acid battery, so that the low-temperature capacity can be greatly improved, the low-temperature cycle life can be greatly prolonged, and the valve-regulated lead-acid battery is applicable to a low-temperature environment of minus 10-minus 40 DEG C.

Description

technical field [0001] The invention relates to a negative electrode active material of a low-temperature lead-acid battery used in a low-temperature environment and a preparation method thereof, belonging to the field of lead-acid battery production. Background technique [0002] With the continuous development of communication and energy storage fields, valve-regulated sealed lead-acid batteries are more and more applied to low-temperature environments, such as rural telecom repeaters in northern my country, alpine base stations, outdoor wind and solar energy storage applications, high-altitude Regions, etc. The valve-regulated sealed lead-acid batteries produced by the existing technology are used in the above-mentioned regions. In winter, the low-temperature capacity and cycle life will be reduced to below 70% of normal temperature in the environment below -10°C, and the low-temperature capacity in the environment of -40°C The cycle life will drop below 35% of that at ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M4/57
CPCY02E60/12Y02E60/10
Inventor 徐冬明
Owner SHUANGDENG GRP
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