Industrial production method and device of urea-formaldehyde slow-release compound fertilizer

A urea-formaldehyde slow-release and compound fertilizer technology, which is applied in fertilization devices, fertilizer mixtures, agriculture, etc., can solve the problems of lack of combination and optimization of urea-formaldehyde fertilizer systems, achieve good nitrogen slow-release performance, improve fertilizer utilization, and enhance resistance reverse effect

Active Publication Date: 2013-04-03
河南豫邮金大地科技服务有限公司
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Problems solved by technology

However, most of the above-mentioned Chinese patent documents describe the chemical synthesis method of urea-formaldehyde fertilizers and the physical blending with conventional fertilizers, etc., lacking the systematic combination and optimization of urea-formaldehyde fertilizers and conventional fertilizers in terms of production process equipment

Method used

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  • Industrial production method and device of urea-formaldehyde slow-release compound fertilizer

Examples

Experimental program
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Embodiment 1

[0032] Embodiment 1: An industrialized production device of urea-formaldehyde slow-release compound fertilizer, the production device includes a raw material mixer 1, a raw material belt conveyor 2, a raw material crusher 3, a raw material bucket elevator 4, a granulator 5, and a formaldehyde storage tank 6 , formaldehyde pump 7, urea bucket elevator 8, formaldehyde metering tank 9, acid metering tank 10, stirring reactor 11, metering pump 12, drying belt conveyor 13, blower 14, hot blast stove 15, dryer 16, cooling belt Machine 17, cooling machine 18, screening bucket elevator 19, screening machine 20, screening belt conveyor 21, powder dusting cylinder 22, finished bucket elevator 23, finished product silo 24, packaging scale 25; raw material mixer 1 discharge The mouth is set opposite to the feed end of the raw material belt conveyor 2, the discharge end of the raw material belt conveyor 2 is set opposite to the feed port of the crusher 3, and the discharge port of the raw m...

Embodiment 2

[0045] Example 2: An industrial production method of a urea-formaldehyde slow-release compound fertilizer. The steps are the same as in Example 1, except that in step (1), 20 wt% potassium hydroxide aqueous solution is used to adjust the pH value to 8.5-8.8.

Embodiment 3

[0046] Example 3: An industrial production method of a urea-formaldehyde slow-release compound fertilizer. The steps are the same as those in Example 1, except that in step (2), 20% phosphoric acid is used to adjust the pH value to 5.4-5.1.

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Abstract

The invention relates to an industrial production method and device of a urea-formaldehyde slow-release compound fertilizer and a device thereof. The industrial production method comprises the steps of adding water and oxidized starch to a reaction still and then pasting, adding urea of which the nitrogen content is 46wt% and formalin, stirring, dissolving and then adjusting the pH value to 8.5-8.8 by an alkaline matter, reacting at constant temperature of 60 DEG C to obtain reaction liquid; adjusting the pH value to 5.4-5.1 by the reaction liquid; reacting for 45 minutes at the constant temperature of 65-68 DEG C, then adjusting the pH value to 6.8-7.2, and terminating reaction to obtain the urea formaldehyde condensation product solution; mixing the urea formaldehyde condensation product solution with nitrogen, phosphorus and potassium materials, pelletizing, drying and cooling to below 35 DEG C, and screening to obtain the urea-formaldehyde slow-release compound fertilizer. The industrial production device of the urea-formaldehyde slow-release compound fertilizer is also provided by the invention. Urea formaldehyde is taken as a skeleton; rapid disintegration phenomenon of fertilizer particles caused by water absorption expansion is effectively prevented; the urea-formaldehyde slow-release compound fertilizer has good nutrient slow-release performance, and is high in pelletizing rate in the production process and strong in granule hardness, and the total nutrient content is improved.

Description

technical field [0001] 本发明涉及一种脲醛缓释复合肥料的工业化生产方法和装置,属于肥料生产的技术领域。 Background technique [0002] 我国是世界上最大的化肥生产和消费国,年消费量约占世界化肥消费总量35%左右,据统计,1996~2008年间,我国化肥使用量增长了36.9%,而粮食总产量却只增长了4.7%,不断增加的化肥投入并没有持续增加粮食产量。出现这一现象的原因是多方面的,肥料利用率降低导致增产效应下降无疑是一个重要的原因。目前发达国家化肥当季利用率平均为50-60%,而我国化肥当季利用率平均仅为30-35%。大量营养元素的流失浪费不仅给社会带来巨大的经济损失,而且还会造成严重的环境污染。提高肥料利用率,减少施肥量,节省施肥劳动力,显得尤为重要,缓 / 控释肥通过对养分释放率的调控而使之与作物养分吸收基本相同步,可以大大提高肥料养分利用率,减少农业面源污染,符合国家可持续发展战略的要求,因此缓控释肥料已成为21世纪肥料产业发展的主要方向之一。 [0003] 目前,国内外有机聚合物包膜控释肥的研究已经发展到了一个较高的高度,工艺技术已日趋成熟,养分控释性能良好,生产成本高的问题得到了初步解决,但距离其在大田作物上普遍应用尚待进一步降低生产成本;硫包膜肥料价格较低,但该工艺会大大降低大量元素的养分含量,使肥料总养分偏低;脲酶抑制剂和硝化抑制剂等稳定性肥料不能满足缓控释性能的要求,而且存在掺混不均匀、施用不方便的问题,因此开发一种施用方便、适合大田作物推广的缓控释肥料具有重要的现实意义。 [0004] 中国专利文献CN1198425A(98109068.0)公开了一种脲醛控释肥料的合成方法,在生产复合肥过程中加入脲醛肥与其它的化肥混合在一起,通过造粒机进行造粒,生产出一种缓释脲醛复合肥,目的是使肥料中的氮施入土壤,能缓慢释放,以满足作物生长的需要,减少氮素流失,提高肥料利用率;脲醛肥是由尿素与甲醛在酸性条件下缩合而成,脲醛肥缓释性能的强弱是决定于缩合物分子链的长短,它取决于甲醛,尿素相互作用的许多条件如尿素与甲醛的摩尔分子比、pH值、温度与反应时间。中国专利文献CN101391905A(200810225221.3)公开了脲醛肥料与脲醛复合肥料及其制备方法,包括如下步骤:1)将淀粉与水混合,糊...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00
CPCY02P60/21
Inventor 李广涛徐淑班陈德清
Owner 河南豫邮金大地科技服务有限公司
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