Preparation method of composite inorganic polymer stable algaecide and algae removing method

An inorganic polymer and algaecide technology, applied in inorganic chemistry, chemical instruments and methods, and alkali metal compounds, etc., can solve the problems of removal efficiency, separation of magnetic powder and flocs, and curing the symptoms rather than the root causes, so as to eliminate secondary problems. Pollution, maintaining water quality stability, improving the effect of transparency

Inactive Publication Date: 2013-04-10
HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Each of the above-mentioned algae removal methods has its own advantages and disadvantages, but the main disadvantage of clay algae removal is: only the algae are adsorbed and settled to the bottom of the water, and the algae that fall to the bottom of the water are still alive and will still survive and survive for a certain period of time. Secondly, the algae falling to the bottom of the water are in anoxic state, and if they rot, they will release hydrogen sulfide gas and algal toxins, which cannot be decomposed, and will lead to benthic organisms and spores after spreading in the water body. Organisms are smothered to death, seriously causing hypoxia in the sediment, causing secondary pollution and biological death, and even releasing harmful gases, further destroying the biological chain of the water body, and treating the symptoms but not the root cause
Although the composite of chitosan and magnetic powder can flocculate and effectively remove algae, its disadvantage is that the combination of magnetic powder and chitosan is not strong, resulting in the detachment of magnetic powder and floc, and the removal efficiency is affected.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A preparation method of a composite inorganic polymer stable algicide, comprising the following steps:

[0019] (1) The 400-mesh magnetic powder was irradiated with gamma rays with an energy of 4MeV and a dose of 30kGy for 30 minutes to improve the dispersion and specific surface area of ​​the magnetic powder and obtain modified magnetic powder;

[0020] (2) Mix the modified magnetic powder and acrylic acid evenly according to the mass ratio of 80:20, and then irradiate the ultraviolet rays with a wavelength of 354nm for 20 minutes. The mixture is 10 cm away from the light source, so that the magnetic powder and acrylic acid are grafted, and the acrylic acid is polymerized at the same time. Formation of magnetic powder-polyacrylic acid composite;

[0021] (3) Mix the magnetic powder-polyacrylic acid composite with attapulgite, activated carbon, and silane coupling agent KH550 according to the mass ratio of 60:20:15:5, and then use 110°C hydrothermal treatment for 10 min...

Embodiment 2

[0026] A preparation method of a composite inorganic polymer stable algicide, comprising the following steps:

[0027] (1) The 300-mesh magnetic powder was irradiated with gamma rays with an energy of 3 MeV and a dose of 20kGy for 20 minutes to improve the dispersion and specific surface area of ​​the magnetic powder and obtain modified magnetic powder;

[0028] (2) Mix the modified magnetic powder and acrylic acid evenly according to the mass ratio of 75:25, and then irradiate the ultraviolet rays with a wavelength of 354nm for 20 minutes. Magnetic powder-polyacrylic acid composite;

[0029] (3) Mix the magnetic powder-polyacrylic acid composite with attapulgite, activated carbon, and silane coupling agent KH550 according to the mass ratio of 60:10:25:5, and then use 105°C hydrothermal treatment for 20 minutes to form a magnetic powder-polyacrylic acid compound. Acrylic compound-attapulgite-activated carbon quaternary compound;

[0030] (4) Mix the magnetic powder-polyacryl...

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Abstract

The invention discloses a preparation method of a composite inorganic polymer stable algaecide and an algae removing method. The algaecide can effectively flocculate algae to form flocs; the algae can be removed from a water body quickly by the action of an external magnetic field; as magnetic powder and the flocs are closely combined, the flocs do not fall easily in a removing process; and the removing efficiency of the algae is improved. As the algaecide contains an efficient adsorbent, contaminants such as algal toxin, nitrogen and phosphorus in the water body can be adsorbed and enriched, and are removed together with the flocs. The composite algaecide has the advantages that the algaecide is stable, high in removing efficiency, and environment-friendly, and has potential application value and market competiveness.

Description

technical field [0001] The invention relates to a composite algaecide, in particular to a composite inorganic polymer stable algaecide used for removing algae in rivers, lakes and other water bodies. Background technique [0002] In recent years, the eutrophication of my country's water bodies has become very serious, and it has become a major problem in the environmental field that needs to be solved urgently. The algae flooding in rivers, lakes and seas has attracted widespread attention from all walks of life. Large-scale algae outbreaks have seriously damaged the balance and stability of aquatic ecosystems. threat to human survival. Only the economic losses caused by red tides to the coast amount to billions of yuan every year, so the algae outbreak has become a disaster. Currently more popular methods of algae removal can be roughly attributed to physical methods, chemical methods and biological methods. Physical method: Physical method (such as high-voltage ionizati...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/56C02F1/28C02F1/66C02F1/48B01J20/26B01J20/30B01J20/28C08L51/10C08L5/08C08K13/02C08K3/34C08K3/04C08K5/5419C08K3/16C08F292/00C08F2/48
Inventor 王相勤柳丹余增亮
Owner HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI
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