High-performance environment-friendly modified PBT (polybutylene terephthalate)

A high-performance, modified technology, which is applied in the field of PBT materials, can solve the problems of secondary pollution, harm to the environment and human health, and achieve the effects of cost reduction, good stability and high cost performance

Active Publication Date: 2015-04-22
东莞市百思特塑胶有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Domestic PBT technology development began in the 1970s. However, flame-retardant polymer materials still mainly use halogen-containing flame-retardant systems. Once this bromine-containing system is burned, it will emit a large amount of toxic gases and smoke. If it is recycled and incinerated Often cause secondary pollution, seriously endangering the environment and human health
In response to the above problems, the country has been adjusting the product structure of flame retardants and increasing the development of efficient, stable and environmentally friendly flame retardants; however, it has not yet been found in China to meet the requirements of environmental protection and fire resistance to UL94-V0. There are products that can meet the above requirements at the same time

Method used

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Experimental program
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Effect test

Embodiment

[0032] The modified PBT provided by the invention is prepared from the following raw material components:

[0033] Component A is obtained by mixing new PBT materials with recycled materials, and the recycled materials are used together with 20% of the new materials; Component B is an auxiliary material, which includes phosphorus nitrogen-based halogen-free flame retardants, ethylene-acrylate Terpolymer, silane coupling agent and glass fiber; when preparing, take 15% phosphorus nitrogen halogen-free flame retardant, 8% ethylene-acrylate terpolymer, 4% silane coupling Agent, 30% glass fiber and the balance are the ratio of PBT raw materials. By using twin-screw machine for molecular decomposition, recombination and granulation, the shear angle between the screw blocks of the twin-screw machine is less than 90 degrees.

[0034] The invention adopts the principle of condensed phase flame retardancy as the main principle and interruption of heat exchange as the supplementary princ...

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Abstract

The invention relates to the technical field of new materials, and particularly relates to high-performance environment-friendly modified PBT (polybutylene terephthalate) which is prepared from a component A and a component B, wherein the component A is a PBT raw material, and the PBT raw material is an original new material or is prepared by mixing a reclaimed material with a new material; and the component B is an auxiliary material, and the auxiliary material at least comprises halogen-free flame retardant, toughener, compatilizer and a glass fiber. In the preparation process, the high-performance environment-friendly modified PBT comprises the following specific components in percentage by weight: 15-20% of halogen-free flame retardant, 5-10% of toughener, 3-5% of compatilizer, 25-35% of glass fiber and the balance of PBT raw material; and the preparation process comprises the following steps: performing molecular decomposition, recombining, and granulating. According to the invention, the high-performance environment-friendly modified PBT is prepared by using PBT as a carrier and adding the halogen-free flame retardant, the toughener, the compatilizer, the glass fiber and other auxiliary materials; the invention can enhance the fire retardance degree and physical properties of the product, and ensures that the product meets the environmental requirements for no halogen and no phosphorus and conforms to industrial utilization; and the product is free of I and Br, thereby doing no harm to environment and health of people.

Description

Technical field [0001] The present invention involves new materials technology, especially PBT materials. Background technique [0002] PBT material refers to a type of plastic composed of polyetherazanide diol ester as the main body. The products made can be widely used in computers, automobile connectors, heat dissipation fans, AC / DC plugs, transformers, and other electronics., Electrical products. [0003] PBT materials are made of products, which usually refer to modified varieties. PBT (abbreviation of polytic benzenate dilate) is first developed in 1942 in German scientists P.SCHLACK.For industrial development, and listed on the name of CELANEX products, in 1970, 30%glass fiber enhanced plastic release markets. With the widespread application of PBT materials, the performance requirements for PBT materials have increased.And with sufficient stretching strength, bending strength, impact strength, etc. Therefore, it is necessary to add auxiliary materials such as flame retard...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L23/08C08L33/08C08K7/14B29C47/92B29C48/92
CPCB29C47/0011B29C47/92B29C48/04B29C48/40
Inventor 许志鹏
Owner 东莞市百思特塑胶有限公司
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