Compounds for Electronic Devices
A technology of electronic devices and compounds, applied in the field of compounds of formula, or, can solve the problems of limited organic electroluminescent devices, etc.
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[0173] A) Synthesis Example
[0174] The following syntheses were carried out in dry solvents under a protective gas atmosphere unless otherwise indicated. The raw materials or reactants that can be used are, for example, 3,4-dimethylpyrrolo[3,4-b]indole-3,4(2H)-dicarboxylate (Science of Synthesis 2002, 9441-552), 2- (3-bromophenyl)-4,6-diphenylpyrimidine, 4-(3-bromophenyl)-4,6-diphenylpyrimidine, 4-(3,5-dibromophenyl)-4 , 6-diphenylpyrimidine (WO2005 / 085387) and 2-(3,5-dibromophenyl)-4,6-diphenylpyrimidine.
[0175] Example compound 1
[0176] a) Diethyl 2-phenyl-2H-pyrrolo[3,4-b]indole-3,4-dicarboxylate
[0177]
[0178] 53 g (176 mmol) of diethyl pyrrolo[3,4-b]indole-3,4(2H)-dicarboxylate and 129 g (1059 mmol) of phenylboronic acid were dissolved in 2000 ml of dichloromethane and degassed. 71 ml of triarylamine and 40 g (356 mmol) of copper(II) acetate and 111 g of molecular sieves (0.4 NM) were added. The reaction mixture was then stirred at room temperature for 80...
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