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Method for improving leaching rate of magnesium oxide in serpentine ammonium salt roasting product

A technology of roasted products and halite ammonium salts, which is applied in the direction of magnesium oxide, etc., can solve the problems of affecting performance, reducing the yield of magnesium products, and the negative impact of process closed loop, so as to achieve the effect of increasing yield and increasing utilization value

Active Publication Date: 2015-02-11
CHINA UNIV OF MINING & TECH (BEIJING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Magnesium extraction residue is used as a silicon-rich product for subsequent processing and utilization. If there are more magnesium components in it, it will seriously affect its product performance and product value.
In addition, the equilibrium design of the ammonia in the original loop and the ammonium sulfate obtained from the final crystallization will also be broken
In summary, in the process of extracting magnesium and enriching silicon by serpentine ammonium salt roasting method, the low magnesium oxide dissolution rate of the roasted product not only greatly reduces the yield of magnesium products, but also seriously affects the silicon products produced in the process. The performance of serpentine greatly reduces the efficiency and comprehensive utilization of serpentine, and also has a great negative impact on the closed cycle of the entire process.

Method used

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  • Method for improving leaching rate of magnesium oxide in serpentine ammonium salt roasting product
  • Method for improving leaching rate of magnesium oxide in serpentine ammonium salt roasting product
  • Method for improving leaching rate of magnesium oxide in serpentine ammonium salt roasting product

Examples

Experimental program
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Effect test

Embodiment 1

[0020] Example 1: ① Take some serpentine ore powder (Qinghai sample) that has been crushed to 100-200 mesh, and carry out ultra-fine grinding processing on it through an ultra-fine pulverizer until the average particle size of the powder is d 50 =3~4μm;

[0021] ② Take 1 part of the mineral powder that has been ultra-finely crushed in ①, add 1.5 parts of 60-200 mesh ammonium sulfate, and then add 0.03 parts of 80-200 mesh sodium sulfate, mix well and put it in the reactor. In a heating furnace, the temperature is raised to 600-700°C by program, and roasted at a constant temperature for 1 hour;

[0022] ③ After the roasting is completed, add 5-10 parts of warm water to the roasted product and fully stir to dissolve it in water, so that the soluble components in the product are completely dissolved;

[0023] ④ filter the suspension in ③, and wash the filter cake to obtain magnesium-enriched filtrate and magnesium-extracted filter residue respectively. The chemical composition ...

Embodiment 2

[0024] Embodiment 2: ① Take a number of asbestos tailings powders that have been crushed to 100-200 mesh, and use an ultra-fine pulverizer to perform ultra-fine grinding processing on them until the average particle size of the powder is d 50 =5~6μm;

[0025] ②Take 1 part of the ultrafinely crushed ore powder in ①, add 1.5 parts of 60-200 mesh ammonium sulfate, then add 0.15 parts of 80-200 mesh sodium sulfate, mix well and put it in the reactor. In a heating furnace, the temperature is raised to 600-700°C by program, and roasted at a constant temperature for 1 hour;

[0026] ③ After the roasting is completed, add 5-10 parts of warm water to the roasted product and fully stir to dissolve it in water, so that the soluble components in the product are completely dissolved;

[0027] ④ filter the suspension in ③, and wash the filter cake to obtain magnesium-enriched filtrate and magnesium-extracted filter residue respectively. The chemical composition and quality of the magnesiu...

Embodiment 3

[0028] Example 3: ① Take some serpentine ore powder (Inner Mongolia sample) that has been crushed to 100-200 mesh, and use an ultra-fine pulverizer to perform ultra-fine grinding processing on it until the average particle size of the powder is d 50 =7~8μm;

[0029] ② Take 1 part of the mineral powder that has been ultra-finely crushed in ①, add 1.3 parts of 60-200 mesh ammonium chloride, then add 0.1 part of 80-200 mesh sodium chloride, mix well and place it in the reactor, and put the reaction The device is placed in a heating furnace, and the temperature is raised to 350-500 ° C by program, and roasted at a constant temperature for 1 hour;

[0030] ③ After the roasting is completed, add 5-10 parts of warm water to the roasted product and fully stir to dissolve it in water, so that the soluble components in the product are completely dissolved;

[0031] ④ filter the suspension in ③, and wash the filter cake to obtain magnesium-enriched filtrate and magnesium-extracted filte...

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Abstract

A method for improving the leaching rate of magnesium oxide in a serpentine ammonium salt roasting product aims at solving the problems that magnesium oxide leaching rate is relatively low and magnesium-extracted residue is not high in utilization value in a conventional serpentine ammonium salt roasting magnesium extraction method. The technical scheme comprises: (1) performing pretreatment on serpentine mineral powder before mixing with an ammonium salt and roasting, performing ultrafine grinding on the mineral powder to an average particle size d50 of less 10 mu m; and (2) when mixing the ultrafine mineral powder and the ammonium salt, adding a sodium salt accounting for 2%-20% by mass of the mineral powder, mixing uniformly and roasting. The method of the invention is capable of improving the magnesium oxide extraction rate in serpentine from about 60% to 95% or more, and improving the silica content in the magnesium-extracted residue from about 60% to 80% or more, so that the method not only helps to substantially improve the yield of magnesium products in the serpentine ammonium salt roasting magnesium extraction method, but also helps to substantially improve the utilization value of obtained silicon products after magnesium is extracted, and helps to enable the closed cycle design of the conventional serpentine ammonium salt roasting method to be more practical and more feasible.

Description

technical field [0001] The invention relates to a method for increasing the dissolution rate of magnesium oxide in serpentine ammonium salt roasting products, belonging to the field of mineral processing. Background technique [0002] According to the different raw materials used in the processing process and the treatment methods of ore powder, the current processes for extracting magnesium and enriching silicon for deep processing of serpentine ore can be mainly divided into three types: acid leaching method, alkali fusion method and ammonium salt roasting method. Among them, the ammonium salt roasting method is a serpentine ore processing method that has emerged in recent years, and its main ideas and processes are: [0003] ①Crush the serpentine to be processed for magnesium extraction and silicon enrichment to a fineness of about 100-200 mesh, then add a certain proportion of ammonium salt (below 60 mesh) and fully mix with the ore powder; [0004] ②Place the mixed mat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01F5/06
Inventor 郑水林狄永浩宋贝刘超
Owner CHINA UNIV OF MINING & TECH (BEIJING)