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Primer composition and optical semiconductor apparatus using same

A technology for optical semiconductor devices and primers, applied in semiconductor devices, coatings, electro-solid devices, etc., can solve the problems of insufficient heat resistance of primer films, resin deterioration, film cracks, etc., and achieve excellent adhesion, Corrosion prevention and high reliability effects

Active Publication Date: 2014-07-23
SHIN ETSU CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when using acrylic polymers containing SiH groups, the heat resistance of the primer film is not sufficient, and the resin deteriorates in the vicinity of semiconductor elements where a relatively high current flows in recent years.
On the other hand, although polysilazane compounds are excellent in heat resistance, polysilazane films are relatively stiff, so it is best to apply them to a structure in which a plurality of optical semiconductor elements called multi-chips are mounted. Once on the substrate, the film will rupture

Method used

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  • Primer composition and optical semiconductor apparatus using same
  • Primer composition and optical semiconductor apparatus using same
  • Primer composition and optical semiconductor apparatus using same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0116] Hereinafter, although a synthesis example, an Example, and a comparative example are shown and this invention is concretely demonstrated, this invention is not limited to the following example.

Synthetic example 1

[0117] [Synthesis Example 1] Synthesis of polysilazane compound

[0118] Put 1,000 g of ethyl acetate into a 2 L four-necked flask equipped with a coiled cooler and a thermometer, and add 3.8 g (0.015 mol) of methacryloxypropyl trichlorosilane into the ethyl acetate 1. 41.5 g (0.28 mol) of methyltrichlorosilane was stirred in an ice bath. 15 g (0.89 mol) of ammonia gas was blown in when the inside of the system became 10 degreeC or less, and it stirred for 3 hours after blowing in. After completion of the stirring, by-product ammonium chloride was filtered off to complete a 4% by mass polysilazane solution of ethyl acetate.

[0119] use 29 Si-NMR, 1 When the synthesized polysilazane compound was measured by H-NMR, the structure of the polysilazane was as shown below, and the weight average molecular weight measured by GPC (tetrahydrofuran solvent (THF solvent)) was 2,000.

[0120]

Synthetic example 2

[0121] [Synthesis Example 2] Synthesis of polysilazane compound

[0122] Put 1,000 g of ethyl acetate into a 2 L four-necked flask equipped with a coiled cooler and a thermometer, and add 19 g (0.15 mol) of dimethyldichlorosilane, methyltrichlorosilane, and 22.5g (0.15mol), stirred under ice bath conditions. 14 g (0.83 mol) of ammonia gas was blown in when the inside of the system became 10 degreeC or less, and it stirred for 3 hours after blowing in. After completion of the stirring, by-product ammonium chloride was filtered off to complete a 4% by mass polysilazane solution of ethyl acetate.

[0123] use 29 Si-NMR, 1 When the synthesized polysilazane compound was measured by H-NMR, the structure of the polysilazane was as shown below, and the weight average molecular weight measured by GPC (THF solvent) was 2,000.

[0124] ((CH 3 ) 2 Si(NH) 2 / 2 ) 0.5 (CH 3 Si(NH) 3 / 2 ) 0.5

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Abstract

The invention aims at providing a primer composition in which the adhesion between a substrate mounting an optical semiconductor device and a cured material of an addition reaction curing silicone composition that encapsulates the optical semiconductor device can be improved, the corrosion of a metal electrode on the substrate can be prevented, and the heat resistance and flexibility of a primer can be improved. In order to solve the problem, the primer composition is provided. The primer composition which adheres a substrate mounting an optical semiconductor device and a cured material of an addition reaction curing silicone composition that encapsulates the optical semiconductor device, includes (A) silazane compound or polysilazane compounds that has one or more silazane bonds in the molecule, (B) acrylic resin containing either one or both of acrylate ester and methacrylate ester that contains one or more SiH groups in the molecule, and (C) solvent.

Description

technical field [0001] The present invention relates to a primer composition and an optical semiconductor device using the primer composition. The primer composition is an addition reaction curing type that combines a substrate on which an optical semiconductor element is mounted and seals the optical semiconductor element. Adhesion of cured silicone composition. Background technique [0002] An LED lamp known as an optical semiconductor device has a light emitting diode (Light Emitting Diode, LED) as an optical semiconductor element, and the LED mounted on a substrate is sealed with a sealing material made of a transparent resin. Make a seal. Conventionally, epoxy resin-based compositions have been commonly used as sealing materials for sealing such LEDs. However, in epoxy resin-based sealing materials, along with recent miniaturization of semiconductor packages and higher brightness of LEDs, the amount of heat generated has increased and the wavelength of light has becom...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/16C09D133/12C09D151/00C09D7/12H01L33/56
CPCC08G77/62C09D183/16C08G77/12C08G77/20H01L2224/48091C09D133/12H01L33/56C08F220/14C08F230/085C08L83/00C08L33/00H01L2924/00014C08F230/08
Inventor 小材利之
Owner SHIN ETSU CHEM IND CO LTD