Pr3+ ions doped calcium, magnesium, zirconia, gadolinium and gallium garnet and melt method for crystal growth thereof
A technology of ion doping and crystal growth, applied in crystal growth, single crystal growth, single crystal growth and other directions, can solve the problems of low pumping efficiency, narrow ion absorption band, narrow spectral width and so on
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[0019] Example 1. Growth of Pr: (Ca, Mg, Zr) GGG crystals by melt method
[0020] (1), Pr: (Ca, Mg, Zr) GGG crystal growth ingredients:
[0021] Using Pr 6 o 11 , Gd2O 3 , Ga 2 o 3 , CaO, MgO, ZrO 2 As a raw material, the molar ratio of the following chemical formula is used for batching and fully mixed evenly:
[0022]
[0023]
[0024] If the segregation effect in the crystal growth process is considered, the segregation coefficient of a certain element in the Pr: (Ca, Mg, Zr) GGG crystal is k, k=0.01-1, then when the (1) When the mass of the compound of this element in the compound formula is W, it should be adjusted to W / k in the ingredients.
[0025] (2) Pressing and sintering of raw materials:
[0026] Press and sinter the uniformly mixed raw material components to obtain the initial raw material for crystal growth. The sintering temperature is 1000-1600°C and the time is 10-72 hours. The raw material after pressing can also be used as the initial raw mater...
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