Unlock instant, AI-driven research and patent intelligence for your innovation.

Heat-resistant alloy for ultra-supercritical thermal power steam turbine sets

An ultra-supercritical, heat-resistant alloy technology, applied in the field of heat-resistant alloys, can solve the problems of high cost and low thermal fatigue of nickel-based alloys

Inactive Publication Date: 2014-09-10
CENT IRON & STEEL RES INST
View PDF3 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional 12% Cr heat-resistant steel has high corrosion resistance and thermal strength, which can meet the requirements of the USC unit at 600 °C, but when the steam parameters are increased to 650 °C and 700 °C, the traditional martensite resistance Hot steel and austenitic heat-resistant steel can no longer meet the requirements of use, and due to the high thermal expansion coefficient will lead to low thermal fatigue performance, high-temperature alloys should be considered
At present, in 650°C units, high-temperature components mainly use nickel-based alloys such as Nimonic80A. Nickel-based alloys have the characteristics of high-temperature strength and good durability, but the cost of nickel-based alloys is relatively high.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Heat-resistant alloy for ultra-supercritical thermal power steam turbine sets
  • Heat-resistant alloy for ultra-supercritical thermal power steam turbine sets
  • Heat-resistant alloy for ultra-supercritical thermal power steam turbine sets

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] According to the above alloy range, 5 heats of test materials were smelted, and the Ni content was 32%, 34%, 36%, 38% and 40%, and the content of other alloy elements was not much different. The chemical composition is shown in Table 1. After the same heat treatment process, the room and high temperature mechanical properties of each test material were tested. The mechanical properties at room temperature are shown in Table 2. It can be seen that each test material has good room temperature strength, plasticity and toughness, and the comprehensive mechanical properties at room temperature are excellent.

[0012] Table 1 Embodiment 1 of the present invention uses chemical composition

[0013] serial number

C

Si

mn

P

S

Cr

Ni

Ti

Al

Nb

V

Ce

B

Zr

Fe

1

0.019

0.071

<0.005

<0.005

0.0019

22.09

32.30

1.70

1.68

1.51

0.12

0.0095

0.0023

0.04

Remain ...

Embodiment 2

[0020] The 1# and 2# alloys in Example 1 after heat treatment were subjected to long-term aging at 650°C, and the 4# and 5# alloys were subjected to long-term aging at 700°C. The aging time was 100h, 300h, 1000h and 3000h. The room and high temperature mechanical properties test results of each test material after long-term aging are shown in Table 4 and Table 5.

[0021] It can be seen from Table 4 that during the long-term aging process, the room temperature tensile strength of some test materials first increased and then decreased, and some test materials continued to rise, while the room temperature yield strength of each test material showed a gradual upward trend, and the plastic toughness showed a gradual downward trend .

[0022] Table 4 Comparison table of mechanical properties at room temperature in Example 2 of the present invention

[0023]

[0024] It can be seen from Table 5 that with the prolongation of the aging time, the 650°C high temperature tensile stre...

Embodiment 3

[0028] A 700°C endurance test was carried out on each test material in Example 1 after heat treatment, and the test results are shown in Table 6. Simultaneously, the 2# test material in the implementation example 1 after the heat treatment has been carried out the persistent experiment of 650 ℃, and the experimental results are shown in figure 1 , it can be seen that the extrapolated stress of the 650°C durability of the 2# test material is about 200MPa, and it has a high durability.

[0029] Table 6 Comparison Table of Durable Creep Performance of Embodiment 3 of the present invention

[0030]

[0031] In summary, G110 alloy can be used as an alternative material for long-term service heat-resistant components in high-temperature gas or steam corrosion environments with parameters of 650 ° C to 700 ° C.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a heat-resistant alloy for ultra-supercritical thermal power steam turbine sets, belonging to the technical field of heat-resistant alloys. The heat-resistant alloy comprises the following chemical components in percentage by weight: 0.005-0.1% of C, 30-40% of Ni, 15-25% of Cr, 1.0-5.0% of Al+Ti, 0.01-2.0% of Nb, 0.001-0.2% of V, 0.001-0.004% of B, 0.001-0.02% of Ce, 0.01-1% of Cu, 0.01-0.3% of Si, 0.001-0.05% of Mn, 0.01%max of S, 0.01%max of P and the balance of Fe. The heat-resistant alloy can be used for long-term service heat-resistant components in a 650-700 DEG C parameter high-temperature combustible gas or steam corrosion environment. The cost is obviously lowered than that of the nickel-base alloy.

Description

technical field [0001] The invention belongs to the technical field of heat-resistant alloys, and in particular provides a heat-resistant alloy for an ultra-supercritical thermal power steam turbine unit, which is used to prepare ultra-supercritical thermal power steam turbine unit components that work in a high-temperature gas or steam corrosion environment with parameters of 650°C to 700°C . Background technique [0002] In the next 10 years, my country's power structure will still be dominated by coal-fired power generation. It is estimated that by 2025, the proportion of thermal power units in my country's power structure will still be as high as 60% to 70%. Improving steam parameters of thermal power units can significantly increase coal utilization, reduce energy consumption and reduce CO 2 The emission of harmful gases such as coal is the development direction of thermal power plants. The traditional 12% Cr heat-resistant steel has high corrosion resistance and heat...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C22C38/54C22C30/02
Inventor 杨钢王鲁刘正东刘庆王立民包汉生赵吉庆何西扣
Owner CENT IRON & STEEL RES INST