Active turquoise blue dye production wastewater reclamation process

A dye wastewater and wastewater recycling technology, which is applied in the textile industry wastewater treatment, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc. Complete reuse, pH accurate, saving program effects

Active Publication Date: 2014-12-10
唐山明州科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These methods have achieved certain effects on the treatment of dye wastewater, but the wastewater has not been recycled.
Wastewater recycling is particularly important in areas where water is scarce. So far, there is no report on the recycling of reactive turquoise dye production wastewater to achieve zero discharge of process water.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Take the production wastewater of Naiman Mingzhou Chemical Technology Co., Ltd. Active Turquoise Blue 21 for chromaticity detection, the chromaticity is 210 times, and put it into the decolorization tank for decolorization and filtration. The decolorization pool includes a 200-mesh filter screen, on which there is a molecular sieve whose main component is silicon dioxide. The decolorized wastewater is collected into the wastewater collection tank. After the collection, the wastewater in the wastewater collection tank is added to the 10-ton neutralization reaction kettle, and then the lime milk is slowly added, stirred evenly while adding, and the neutralization reaction is detected in real time The pH value in the kettle, when the pH value is 7.5, stop adding milk of lime. Then, the material in the neutralization reactor is filtered by a filter press to obtain filtrate I and filter cake I. The filter cake I is used as an additive for adjusting the cement index, and the ...

Embodiment 2

[0022] Take the production wastewater of Naiman Mingzhou Chemical Technology Co., Ltd. Active Turquoise Blue 14 for chromaticity detection, the chromaticity is 40 times, collect it into the wastewater collection tank, after the collection, add the wastewater in the wastewater collection tank to 10 tons Then add milk of lime slowly, stir evenly while adding, and detect the pH value in the neutralization reactor in real time at the same time, when the pH value is 7.0, stop adding milk of lime. Then, add to the neutralization reactor according to the mass ratio of polyacrylamide and the liquid in the neutralization tank to be 0.5:10 4 The proportion of polyacrylamide solid is added; then, adopt filter press to carry out pressure filtration, obtain filtrate I and filter cake I, filter cake I is used as the additive for adjusting cement index, and filtrate I is added into replacement reactor and sodium carbonate for replacement reaction; then, the material in the replacement reacto...

Embodiment 3

[0024] Take the production wastewater of Naiman Mingzhou Chemical Technology Co., Ltd. Active Turquoise Blue 72 for chromaticity detection, the chromaticity is 160 times, and put it into the decolorization tank for decolorization and filtration. The decolorization tank includes a 300-mesh filter screen, and there is a molecular sieve whose main component is silicon dioxide on the filter screen. The decolorized wastewater is collected into the wastewater collection tank. After the collection, the wastewater in the wastewater collection tank is added to the 10-ton neutralization reaction kettle, and then the lime milk is slowly added, stirred evenly while adding, and the neutralization reaction is detected in real time The pH value in the kettle, when the pH value is 8.0, stop adding milk of lime. Then, add to the neutralization reactor according to the mass ratio of polyacrylamide and the liquid in the neutralization tank to be 1:10 4 The proportion of polyacrylamide solid is ...

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PUM

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Abstract

The invention discloses an active turquoise blue dye production wastewater reclamation process, which comprises the following steps: (1) directly transferring dye wastewater which is no more than 50 times in chromaticity to a wastewater collection tank, feeding dye wastewater which is more than 50 times in chromaticity to a decolorizing pool, physically decolorizing the dye wastewater in the decolorizing pool, and transferring the processed dye wastewater into the wastewater collection tank once again; (2) adding the dye wastewater in the wastewater collection tank of the step (1) into a neutralization kettle, and slowly adding lime milk while stirring uniformly; and stopping reaction when pH value is 7.0-8.5; (3) filter-pressing through a filter press to obtain filtrate I and a filter cake I; (4) adding the obtained filtrate I to a replacement kettle, and adding sodium carbonate for a replacement reaction; and (5) filter-pressing materials in the replacement kettle of the step (4) through the press filter to obtain filtrate II and a filter cake II. The wastewater processed by the process can be completely reclaimed for production of active turquoise blue dye, thus realizing a goal of clean production in a dye production process.

Description

technical field [0001] The invention relates to a process for recycling reactive turquoise dye production wastewater. Background technique [0002] In the process of dye synthesis and production, a large amount of mother liquor wastewater and washing wastewater will be produced. Because of its high COD value and chroma, if it is discharged directly without treatment, it will cause damage to the ecological environment of the water body and seriously pollute the environment. At present, many literatures have reported the treatment technologies of dye production wastewater, such as adsorption decolorization method, catalytic oxidation method, biochemical method, iron-carbon micro-electrolysis method, etc. These methods have achieved certain effects on the treatment of dye wastewater, but the wastewater has not been recycled. Wastewater recycling is particularly important in areas where water is scarce, and there is no report on the recycling of reactive turquoise dye productio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/08C02F103/30
Inventor 赵立红沈也红李永明
Owner 唐山明州科技有限公司
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