Novel sensitized bubble carrier colloidal emulsion explosive and preparation method thereof

A technology of emulsified explosives and sensitized gas, which is applied in the direction of explosives, etc., can solve the problems of unsuitability for specialized chemical factories, high performance of emulsified explosives, and high manufacturing cost, and achieve the effects of small environmental impact, excellent explosive performance, and easy operation of the production process

Active Publication Date: 2017-07-04
宜兴市阳生化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method has the cheapest cost and the simplest process, but has short storage performance and is not suitable for production in specialized factories.
Physical sensitization mostly uses hollow resin microspheres, hollow glass microspheres, and expanded perlite as carriers, and introduces air bubbles into the emulsified matrix to achieve the purpose of sensitization. This method is relatively simple to operate and has relatively stable performance, but the manufacturing cost is relatively high.
Chemical sensitization generally uses nitrite, bicarbonate, organic azo compounds, and nitroso compounds as gas-generating agents to generate gas through chemical reactions and introduce the gas into the emulsified matrix to achieve the purpose of sensitization. The process of this method is relatively complicated. But the cost is low, and the performance of the produced emulsion explosive is relatively high

Method used

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  • Novel sensitized bubble carrier colloidal emulsion explosive and preparation method thereof
  • Novel sensitized bubble carrier colloidal emulsion explosive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] This embodiment provides a novel sensitized bubble carrier colloidal emulsifier explosive, and the components are as follows by mass percentage:

[0047] Inorganic oxidant salt: 65 parts, water: 5 parts, paraffin wax: 6 parts, vaseline: 3 parts, animal oil: 3 parts, vegetable oil: 3 parts, polyisobutene dianhydride-triethanolamine emulsifier: 3 parts, compound flame suppressant: 5 parts, MgH 2 : 2 parts, resin microspheres: 1 part, sodium nitrite: 0.5 parts, acetic acid: 0.3 parts;

[0048]The inorganic oxidant salt is a mixture of ammonium nitrate, sodium nitrate and urea, and the percentage by weight is ammonium nitrate: 80%, sodium nitrate: 10%, urea: 5%, potassium perchlorate: 5%; the composite flame suppressant is sodium chloride, The mixture of potassium chloride and ammonium chloride has a weight ratio of sodium chloride: potassium chloride: ammonium chloride = 1.5:2:1.

[0049] The preparation method of polyisobutylene diacid anhydride-triethanolamine emulsifi...

Embodiment 2

[0053] This embodiment provides a novel sensitized bubble carrier colloidal emulsifier explosive, and the components are as follows by mass percentage:

[0054] Inorganic oxidant salt: 70 parts, water: 8 parts, paraffin wax: 4 parts, vaseline: 2 parts, animal oil: 2 parts, vegetable oil: 2 parts, polyisobutylene dianhydride-triethanolamine emulsifier: 4 parts, compound flame suppressant: 3 parts, MgH 2 : 2.8 parts, resin microspheres: 1.4 parts, sodium nitrite: 0.55 parts, sulfuric acid: 0.5 parts,

[0055] Wherein: the inorganic oxidizing agent salt is the mixture of ammonium nitrate, sodium nitrate and urea, and percentage by weight is: ammonium nitrate: 85%, sodium nitrate: 10%, potassium perchlorate: 5%; The mixture of potassium and ammonium chloride has a weight ratio of sodium chloride: potassium chloride: ammonium chloride = 1.5:2:1.

[0056] The preparation method of polyisobutylene diacid anhydride-triethanolamine emulsifier is as follows:

[0057] (1) Take 100g o...

Embodiment 3

[0060] This embodiment provides a novel sensitized bubble carrier colloidal emulsifier explosive, and the components are as follows by mass percentage:

[0061] Inorganic oxidant salt: 68 parts, water: 10 parts, paraffin wax: 4.8 parts, vaseline: 2.4 parts, animal oil: 2.4 parts, vegetable oil: 2.4 parts, polyisobutylene diacid anhydride-triethanolamine emulsifier: 2 parts, composite flame suppressant: 1 part, sensitizer: 2 parts, H foaming agent: 1 part, phosphoric acid: 0.1 part;

[0062] Wherein: the inorganic oxidizing agent salt is the mixture of ammonium nitrate, sodium nitrate and urea, and percentage by weight is: ammonium nitrate: 82%, sodium nitrate: 12%, urea: 1%, potassium perchlorate: 5%, compound flame suppressant is chlorine A mixture of sodium chloride, potassium chloride and ammonium chloride, the weight ratio of which is sodium chloride: potassium chloride: ammonium chloride = 1.5:2:1.

[0063] The preparation method of polyisobutylene diacid anhydride-triet...

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Abstract

The invention discloses novel sensitization bubble carrier colloidal emulsion explosive. The colloidal emulsion explosive comprises the following components: inorganic oxidizer salt, water, a compound oil phase, an emulgator, a compound flame inhibitor, a sensitizer, a foaming agent and a foaming accelerant, wherein the inorganic oxidizer salt is a mixture of ammonium nitrate, sodium nitrate and urea. The invention also designs a preparation method of the novel sensitization bubble carrier colloidal emulsion explosive. The preparation method comprises the following steps: firstly preparing a water phase, adding an oil phase to the water phase for mixing, then sequentially emulsifying and sensitizing, and finally filling to obtain a finished product. The novel sensitization bubble carrier colloidal emulsion explosive is good in water resistance, excellent in explosive performance, proper in sensitivity, suitable for blasting of various environments, simple and convenient in production process, low in affect on environment and low in cost.

Description

technical field [0001] The invention belongs to the field of explosive preparation, and in particular relates to a novel sensitized bubble carrier colloidal emulsion explosive and a preparation method thereof. Background technique [0002] Emulsion explosives are prepared by emulsification technology. The droplets of oxidant salt aqueous solution are uniformly dispersed in the oil-phase continuous medium containing porous substances such as dispersed air bubbles or hollow glass microspheres to form a water-in-oil emulsion. explosives. Emulsion explosives have excellent blasting performance and water resistance, are non-toxic and pollution-free during production, and are relatively safe during transportation, storage, and use. It is convenient to deliver and has become a key development product in my country's civil explosive equipment industry. [0003] With the development of continuous automation technology for emulsion explosive production lines in my country, the produc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C06B33/14
Inventor 苏丹苏南英许雷生张建新殷军君贾建强
Owner 宜兴市阳生化工有限公司
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