Phosphorous, arsenic, and antimony co-doped n-type heavily doped Czochralski silicon single crystal and its silicon epitaxial wafer

Abstract

The invention discloses a phosphorus, arsenic and antimony co-doped N-type heavily-doped Czochralski silicon single crystal and a silicon epitaxial wafer thereof. The phosphorus, arsenic and antimony co-doped N-type heavily-doped Czochralski silicon single crystal takes phosphorus as the main doping element, and either or both of arsenic and antimony as auxiliary doping elements, the concentration of phosphorus is larger than or equal to 4.6*10<19> / cm<3>, phosphorus accounts for more than or equal to 60% of the doping elements, and the auxiliary doping elements accounts for 0.1-40% of the doping elements. The phosphorus, arsenic and antimony co-doped N-type heavily-doped Czochralski silicon single crystal can eliminate or remarkably reduce slip lines caused by lattice mismatching in the silicon epitaxial wafer, and can effectively reduce or eliminate mismatched dislocation lines generated when an epitaxial layer is grown on a polished wafer formed by processing of the N-type heavily-doped Czochralski silicon single crystal with high doping concentration; while the problems are solved, widening of a transition zone in a semi-conductor device after a high-temperature process is prevented; the industry practice that two or more of phosphorus, arsenic and antimony in a silicon single crystal cannot serve as dopants at the same time is changed.

Description

technical field [0001] The present invention relates to the field of Czochralski silicon single crystal. Background technique [0002] The heavily doped arsenic Czochralski silicon single crystal with arsenic as the main doping element (the concentration of arsenic is 1.2×10 19 -3.4×10 19 / cm 3 ) into a silicon polishing sheet, and then manufacture the polishing sheet into an epitaxial wafer with an epitaxial resistivity greater than 1 Ω.cm, and the epitaxial wafer undergoes high-temperature processing of the semiconductor device. figure 1 shown. The region of high to low resistivity between the silicon epitaxial layer and the polished substrate is called the epitaxial transition region. If the polished substrate contains a small amount of phosphorus in addition to arsenic, the corresponding epitaxial transition region is wider than the epitaxial transition region corresponding to the polished substrate containing only arsenic, and the concentration of phosphorus is grea...

AI Technical Summary

Problems solved by technology

[0005] Continuing to increase the concentration of doping elements in N-type heavily doped Czochralski silicon single crystals using phosphorus or arsenic as dopants alone (reducing the resistivity of silicon single crystals) will encounter the problem of severe epitaxial lattice mismatch , the semiconductor device yield loss caused by the lattice mismatch of such Czochralski silicon single-crystal processed epitaxial wafers becomes unacceptable

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