A kind of fire-proof and heat-insulating material for ship bulkhead and its preparation method and application
A technology for thermal insulation materials and bulkheads, which is applied in the direction of hull bulkheads, hulls, and ship construction, and can solve the problems of easy breakage, increased construction costs, and insignificant thermal insulation effect of fireproof and thermal insulation bulkheads, and achieves good porosity.
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Embodiment 1
[0038] Example 1 Preparation of epoxy-modified acrylic emulsion.
[0039] Component formula:
[0040]
[0041] Preparation:
[0042] (1) Preparation of emulsifier solution: mix the emulsifier of formula quantity with water to obtain emulsifier solution;
[0043] (2) Pre-emulsification: Add the three monomers of methyl methacrylate, butyl acrylate and styrene and the N-methylol acrylamide of the formula amount into the reaction kettle, and add the formula amount while stirring epoxy resin and make it dissolve, then add 1 / 2 amount of emulsifier solution, complete pre-emulsification through high-speed stirring to obtain pre-emulsion, set aside;
[0044] (2) Seed initiation: take 1 / 10 of the pre-emulsion, mix it with the remaining 1 / 2 amount of emulsifier solution, and then add it to the 2 In the protected reaction kettle, add the sodium bicarbonate of the recipe amount, slowly raise the temperature to 50 ° C, and stir, add the initiator of 1 / 2 the recipe amount, the tempera...
Embodiment 2
[0046] Example 2 Preparation method of xonotlite active slurry.
[0047] Get quartz powder and lime powder, wherein, SiO in the quartz powder 2 The content is greater than 98wt%, and the CaO content in the lime is 85-99%, according to CaO and SiO 2 The molar ratio is 1. Mix lime powder and quartz powder, and then mix the mass ratio of quartz powder and lime powder to water 25:1 to obtain a slurry. Stir the slurry evenly and transport it to a high-pressure reactor with a stirring device. In the kettle, heat up to 210-220°C at a rate of 1.5°C / min. The stirring speed is 150r / min during the heating stage and 50r / min during the heat preservation stage. After 5 hours of heat preservation, the temperature is naturally lowered, and hard silicon is obtained after cooling. Calcium stone active material slurry is for use.
Embodiment 3
[0048] Example 3 Preparation of fire-proof and heat-insulating materials.
[0049] 1. Raw material formula:
[0050]
[0051] 2. Preparation method:
[0052] Add 5 parts of glass fiber, 2 parts of cotton fiber, 5 parts of epoxy-modified acrylic emulsion, and 2 parts of water glass (modulus 2.5-3, the same below) to the active slurry containing 100 parts of xonotlite and mix well , and then injected into a mold with 2 parts of alkali-free glass fiber cloth, pressurized and dehydrated. The pressure is controlled at 1.0MPa during pressing. The pressed wet billet is put into a drying kiln for drying, and the temperature of the drying kiln is controlled at 150°C. After drying, spray 2 parts of organosilicon water-repellent agent on the surface for infiltration treatment, and the dried green body is inspected to obtain the finished product.
[0053] The main technical index tests of the fireproof and heat insulating material prepared in this embodiment are shown in Table 1: ...
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