Device and method of electro-synthesis coupled membrane separation

A membrane separation and electrosynthesis technology, applied in semi-permeable membrane separation, chemical instruments and methods, biochemical equipment and methods, etc. The problem of single membrane type, etc., can improve the solute permeation amount and permeation speed, facilitate large-scale application, and expand the membrane area.

Active Publication Date: 2015-09-02
QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still some problems restricting the application of bioelectrochemical technology, such as alternative materials for electrodes, product separation devices, and catalyst selection and innovative reactor design, etc.
[0003] Electrochemical membrane reactor is a new type of high-efficiency sewage treatment and reuse technology that organically combines membrane separation technology and traditional electrochemical synthesis technology. It has been developed rapidly, but there are still some factors restricting the large-scale application of electrochemical membrane reactors, such as the small membrane area connected between the cathode chamber and the anode chamber, which limits the efficiency of mass transfer and product recovery. In addition, the membrane type is single , so that the application of electrochemical membrane reactor has certain limitations

Method used

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  • Device and method of electro-synthesis coupled membrane separation
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Examples

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Embodiment 1

[0034]A single-diffusion bioelectric synthesis device includes an anode chamber 1 of an electrolytic cell connected to the positive pole of a power supply, a cathode chamber 2 of an electrolytic cell connected to the negative pole of a power supply, a membrane separation unit 3 and a connecting pipe 4 . The membrane separation unit includes multiple sets of ion exchange membranes 5 arranged sequentially from the positive electrode to the negative electrode, and a membrane chamber is formed between two adjacent sets of ion exchange membranes. The anode connecting pipe is connected with the water outlet of the anode chamber of the electrolytic cell, and after passing through the anode membrane chambers, is connected with the water inlet of the anode chamber of the electrolytic cell to form a closed cycle. Similarly, the cathode connection pipe is connected to the water outlet of the cathode chamber of the electrolytic cell, and after passing between the cathode membrane chambers,...

Embodiment 2

[0037] A double-diffusion bioelectric synthesis device includes an anode chamber of an electrolytic cell connected to the positive pole of a power supply, a cathode chamber of an electrolytic cell connected to the negative pole of a power supply, a membrane separation unit, a drainage tank and a connecting pipe. The membrane separation unit includes a plurality of sets of anion exchange membranes, cation exchange membranes, anion exchange membranes and cation exchange membranes arranged alternately from the positive pole to the negative pole. The anode connecting pipe is connected to the water outlet of the anode chamber of the electrolytic cell, passes between the first anion exchange membrane and the first cation exchange membrane, and then is connected to the water inlet of the anode chamber of the electrolytic cell to form a closed cycle. Similarly, the cathode connecting pipe is connected with the water outlet of the cathode chamber of the electrolytic cell, and after pass...

Embodiment 3

[0041] A feed synthesis diffusion bioelectric synthesis device comprises an anode chamber of an electrolytic cell connected to the positive electrode of a power supply, a cathode chamber of an electrolytic cell connected to a negative electrode of a power supply, a membrane supply unit, a reaction cell and a connecting pipe. The membrane supply unit includes multiple sets of anion exchange membranes, cation exchange membranes, anion exchange membranes, and cation exchange membranes arranged alternately from the positive electrode to the negative electrode. The anode connecting pipe is connected to the water outlet of the anode chamber of the electrolytic cell, passes between the first anion exchange membrane and the first cation exchange membrane, and then is connected to the water inlet of the anode electrolytic cell to form a closed cycle. Similarly, the cathode connecting pipe is connected with the water outlet of the cathode chamber of the electrolytic cell, and after passi...

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Abstract

The invention provides a device and a method of electro-synthesis coupled membrane separation. The device comprises an electrolytic cell anode chamber connected with the anode of a power source, a cathode chamber connected with the cathode of the power source, a film unit and connecting pipelines; the membrane unit is a membrane separation unit or a membrane supply unit; one or more ion exchange membranes are arranged in the membrane unit; the ion exchange membranes are the same membranes or different membranes arranged at intervals; the anode chamber and the cathode chamber of the electrolytic cell are connected with the membrane unit by use of the connecting pipelines, respectively. The device is capable of realizing single diffusion, double diffusion, supply synthesis diffusion or supply diffusion between the anode chamber and the cathode chamber of the electrolytic cell, and used for selectively allowing target products or the precursor substances of the target products to pass through or reducing the accumulated inhibition effect of the target products in the system.

Description

technical field [0001] The invention belongs to the technical field of electrochemical synthesis, in particular to an improved electrosynthesis coupled membrane separation device and method for recovering high value-added products using microbial electrosynthesis technology. Background technique [0002] Bio-electrochemistry (BES) is the conversion of chemical energy contained in organic waste or biomass into electricity or hydrogen through microbial fuel cells (MFC) or electrolysis cells (MEC). / Process of chemical products. Compared with traditional energy conversion systems, the operating conditions of bioelectrochemical synthesis are relatively mild, and the range of organic substrates that can be used is relatively wide, and rare metals are not required as catalysts. The latest research on the production of products by bioelectrosynthesis has greatly expanded the application range of BES. However, there are still some problems restricting the application of bioelect...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D61/46B01D61/44C12M1/00
Inventor 张杨颜丙花杜娟
Owner QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI
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