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Technology for production of gasoline and combined production of natural gas and hydrogen through methanol synthesis of coke oven gas

A methanol synthesis and natural gas technology, applied in the petroleum industry, the preparation of liquid hydrocarbon mixtures, gas fuels, etc., can solve the problems of insufficient gasoline heat, complex process, pollution, etc., to avoid waste of excess heat, reduce methanol rectification units, The effect of increasing economic value

Active Publication Date: 2015-11-18
SEDIN ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented method offers ways to make better use of coking furnace gases while producing fuel products like diesel or kerosene without generating excess amounts of harmful emissions such as nitrogen oxide (NOx). By combining these two materials into one product instead of just making them separately, this innovation can increase income per share compared to traditional methods that require multiple steps involving different sources of energy.

Problems solved by technology

The present patents discuss various methods for converting crude oil into liquid fuel or gasoline without generating excessive CO2. These techniques involve upgraded hydrocarbon sources like natural bitumen, shale oil, tar sand deposit, etc., while minimizing capital costs associated with these materials. Additionally, there are other ways to achieve this objective: either reduce the cost per kiloil equivalent of coal based fuels or replace them entirely with biofucls derived liquids called biomass; or reformulate some fossils containing heavy metals instead of coking coal. Overall, these approaches aim towards more efficient and economically viable chemical industry solutions involving both methanoxide and biodiesel chemistry.

Method used

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  • Technology for production of gasoline and combined production of natural gas and hydrogen through methanol synthesis of coke oven gas
  • Technology for production of gasoline and combined production of natural gas and hydrogen through methanol synthesis of coke oven gas

Examples

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Embodiment 1

[0034] (1) The volume composition after dust removal and deoiling is H 2 60%, CO5.3%, CO 2 2.7%, CH 4 23.7%, N 2 4.6% and C n H m 3.7% of the coke oven gas enters the low-temperature methanol system 1, where the sulfur and carbon dioxide in the coke oven gas are removed at a temperature of -60°C and a pressure of 4 MPa, and the removed sulfur is sent to the sulfur recovery system for removal. 45% of the volume fraction of the removed carbon dioxide is mixed with the coke oven gas from the desulfurization tank 5 to enter the synthesis gas compressor unit 4, while the remaining 55% of the carbon dioxide is sold as a product, and the coke oven gas after the removal of sulfur and carbon dioxide enters deep cooling Methane separation 2. After cooling the coke oven gas to -70°C, the low-carbon hydrocarbons containing ethane, propane and a small amount of carbon dioxide separated at 4.0MPa are sent to the coke oven for combustion, and then the gas phase is further cooled to -150°C. 4.0...

Embodiment 2

[0039] (1) The volume composition after dust removal and deoiling is H 2 59.6%, CO5.0%, CO 2 3.0%, CH 4 25.8%, N 2 3.0% and C n H m 3.6% of the coke oven gas enters the low-temperature methanol system 1, where the sulfur and carbon dioxide in the coke oven gas are removed at a temperature of -50°C and a pressure of 3.8 MPa, and the removed sulfur is sent to the sulfur recovery system. 38% of the volume fraction of the removed carbon dioxide is mixed with the coke oven gas from the sulfur protection tank to enter the synthesis gas compressor unit 4, while the remaining 62% of the carbon dioxide is sold as a product. The coke oven gas after the removal of sulfur and carbon dioxide enters the deep Cold methane separation 2. After the coke oven gas is cooled to -74°C, low-carbon hydrocarbons containing ethane, propane and a small amount of carbon dioxide are separated at 3.8MPa and sent to the coke oven for combustion, and then the gas phase is further cooled to -155°C. The LNG prod...

Embodiment 3

[0044] (1) The volume composition after dust removal and deoiling is H 2 57.8%, CO5.7%, CO 2 2.6%, CH 4 24.2%, N 2 5.8% and C n H m 3.9% of the coke oven gas enters the low-temperature methanol system 1, where the sulfur and carbon dioxide in the coke oven gas are removed at a temperature of -40°C and a pressure of 3.6 MPa, and the removed sulfur is sent to the sulfur recovery system. 36% of the volume fraction of the removed carbon dioxide is mixed with the coke oven gas from the sulfur protection tank to enter the synthesis gas compressor unit 4, while the remaining carbon dioxide is sold as a product, and the coke oven gas after the removal of sulfur and carbon dioxide enters the cryogenic methane separation 2. After the coke oven gas is cooled to -76°C, the low-carbon hydrocarbons including ethane, propane and a small amount of carbon dioxide are separated at 3.6MPa and sent to the coke oven for combustion, and then the gas phase is further cooled to -160°C and separated at 3...

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Abstract

A technology for production of gasoline and combined production of natural gas and hydrogen through methanol synthesis of coke oven gas comprises the following steps: carrying out low temperature methanol washing on the coke oven gas to remove sulfur and carbon dioxide, carrying out deep cold methane separation on sulfur and carbon dioxide removed coke oven gas, sending a separated liquid methane product to an LNG storage tank, dividing the remaining coke oven gas into two parts, sending the first part to pressure swing adsorption to remove hydrogen sent to a gas cabinet as a product, mixing a pressure swing adsorption stripped gas with the second part of the coke oven gas going through a lateral line, further desulphurizing, mixing the obtained desulphurized gas mixture with parts of the carbon dioxide gas obtained after the low temperature methanol washing, a circulating gas of a methanol separator and parts of a circulating gas of a circulating gas compressor, carrying out methanol synthesis, carrying out an oil synthesis reaction, and carrying out oil product separation to obtain a fuel gas, liquefied petroleum gas, heavy oil and gasoline. The technology has the advantages of simple process flow, less device investment and low energy consumption.

Description

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Claims

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Application Information

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Owner SEDIN ENG
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