Solar cell module and method for manufacturing same
A solar cell and module technology, applied in electrical components, circuits, photovoltaic power generation, etc., can solve problems such as PID
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[0123] Hereinafter, the present invention will be described in more detail with reference to examples and comparative examples. The present invention is not limited to these examples. In the following examples and comparative examples, parts and % are based on weight unless otherwise specified.
[0124] The measuring method of the characteristic is shown below.
[0125] (1) Volume resistivity
[0126] The transparent resin and the heat-crosslinked sealing material were made into test pieces with a thickness of 0.9 to 1.2 mm, and the values at 25° C. were measured in accordance with JISC2139.
[0127] (2) PID test
[0128] A layer made of transparent resin and a sealing material layer mainly composed of ethylene-vinyl acetate copolymer were integrally laminated and fixed on the surface transparent glass (whiteboard glass or soda glass with a thickness of 3 mm), and embedded in the Crystalline silicon solar cell elements in the encapsulant and solar cell modules in the bac...
reference example 1
[0132] (sheet of modified polyethylene)
[0133] 1.5 parts of vinyltrimethoxysilane and 2,5- 0.15 parts of dimethyl-2,5-bis(t-butylperoxy)hexane were mixed. The mixture was extruded into strands while kneading using a twin-screw extruder (product name "TEM37B", manufactured by Toshiba Machine Co., Ltd.) under the conditions of a resin temperature of 200° C. and a residence time of the resin of 80 to 90 seconds. After natural cooling, it was finely cut with a pelletizer to obtain 97 parts of pellets of modified polyethylene (PE-S).
[0134] In the FT-IR spectrum of the pellets, at 1075, 808, 766 cm with those originating from vinyltrimethoxysilane -1 different positions at 1090cm -1 observed that originating from Si-OCH 3 The new absorption band of the base, and at 825, 739cm -1 observed that originating from Si-CH 2 The new absorption band of the base. From this, it was confirmed that the obtained modified polyethylene (PE-S) had a methoxysilyl group.
[0135] 2-(2H-be...
reference example 2
[0139] (Modified ethylene-α-olefin copolymer sheet)
[0140] Using pellets of a commercially available ethylene-octene copolymer (product name "Affinity (registered trademark) PL1880", melting point 100°C, manufactured by Dow Chemical Japan Co., Ltd.), the resin temperature was 190°C, and the residence time was 170 to 180 seconds. Otherwise, kneading was carried out in the same manner as in Reference Example 1 to obtain 90 parts of pellets of a modified ethylene-1-octene copolymer (EOC-S).
[0141] In the FT-IR spectrum of the pellets, at 1075, 808, 766 cm with those originating from vinyltrimethoxysilane -1 different positions at 1090cm -1 observed that originating from Si-OCH 3 The new absorption band of the base, and at 825, 739cm -1 observed that originating from Si-CH 2 The new absorption band of the base. From this, it was confirmed that the obtained modified ethylene-1-octene copolymer (EOC-S) had a methoxysilyl group.
[0142] Using the pellets of the obtained mo...
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