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Method for processing anti-coking alloy material

A technology of alloy material and treatment method, applied in the field of anti-coking alloy material treatment, can solve the problems of stainless steel alloy material content and relationship definition, etc., and achieve the effect of continuous film thickness and high chemical stability

Active Publication Date: 2015-12-16
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The main technical innovation points of the above patents are to form Mn x Cr 3-x o 4 Spinel-based oxide film, but the above-mentioned patent does not define the content and relationship of Mn and Si in stainless steel alloy materials in detail, and the atmosphere gas for processing alloy materials does not contain hydrocarbons

Method used

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  • Method for processing anti-coking alloy material
  • Method for processing anti-coking alloy material
  • Method for processing anti-coking alloy material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~3

[0023] Prepare stainless steel samples with different Si and Mn contents. The basic composition is: Cr: 30-38wt.%, Ni: 42-48%, C: 0.3-0.5wt%, Fe: the balance. The specific composition is shown in Table 1. A mixed gas containing methane, water vapor and hydrogen is introduced at 1100°C, and the oxygen partial pressure is 3.0×10 -17 atm, processing 30h, the result is as follows figure 1 as shown, figure 1 Indicates that it contains different Si and Mn contents, the basic composition is: Cr: 30-38wt.%, Ni: 42–48%, C: 0.3-0.5wt%, Fe: balance, stainless steel at 1100 ℃ methane, hydrogen and water Steam (oxygen partial pressure is 3.0×10 -17 atm) initial 30-hour weight gain data in the mixed cracking atmosphere;

[0024] Each plus sign in the figure represents the experimental data of one sample.

Embodiment 4

[0036] Cut the comparison test piece and the alloy 14#, 15#, 16# test pieces into 5×5×2mm hanging piece samples, and the element composition of the test pieces is shown in Table 2.

[0037] Before the experiment, the weighed metal coupons were suspended in the furnace tube in turn, and the temperature was raised after the protection of He gas was introduced. The time from the initial room temperature to the cracking reaction temperature of 860°C was 90 minutes. After the temperature rises to the cracking temperature, the He gas is stopped, and at the same time, 2vol.%C 2 h 6 +98%vol.N 2 The mixed gas and 1.2vol.% water vapor are uniformly mixed and passed into the reaction furnace tube for cracking reaction, and the oxygen partial pressure is 7.0×10 -18 atm. The pyrolysis and coking reaction time is 20 hours. After the coking experiment is over, stop heating and feeding, protect with He gas, and cool down to room temperature naturally. Under the conditions of this experime...

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Abstract

The invention discloses a method for processing an anti-coking alloy material. The anti-coking alloy material is processed under an atmosphere with low oxygen partial pressure, thereby forming an anti-coking anti-carburization protective film on the surface of the alloy material. The atmosphere with low oxygen partial pressure comprises an oxidizing gas, a reducing gas, and / or an inert gas. The anti-coking alloy material is composed of Cr, Ni, C, Fe, Mn, Si, and trace elements, wherein the trace elements are selected from at least one of Al, Nb, Ti, W, Mo, and rare earth elements. In the alloy material, the content of Cr is 20-50 wt%, and the content of Mn and Si satisfies a relation as shown in the description. According to the method, the composite oxidation film is formed on the surface of the anti-coking alloy material under a common pyrolysis atmosphere of a carbon-hydrogen compound, wherein the film is thin and continuous, and is high in chemical stability under a high-temperature coking atmosphere.

Description

technical field [0001] The invention relates to the field of material processing, and more specifically, relates to a method for processing an anti-coking alloy material. Background technique [0002] During the ethylene production process, surface coking and carburization of the metal matrix will inevitably occur on the inner wall of the cracking furnace tube, which will cause two adverse consequences. On the one hand, coking will lead to a smaller inner diameter of the furnace tube, an increase in pressure drop, a reduction in the processing capacity of the device, an increase in the thermal resistance of the tube wall, a decrease in the heat transfer coefficient of the furnace tube, and an increase in energy consumption. For this reason, the cracking furnace usually has to be shut down every 30-60 days for decoking. This frequent decoking treatment seriously reduces production efficiency and increases production cost. On the other hand, the carbon deposited on the surfa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C8/10C22C30/00
Inventor 王国清郏景省王红霞王申祥张永刚张利军
Owner CHINA PETROLEUM & CHEM CORP