Method for producing ytterbium-doped lithium nickel cobalt manganese oxide material used for lithium ion battery
A technology of nickel-cobalt lithium manganese oxide and lithium-ion batteries, which is applied in the field of preparation of ytterbium-doped nickel-cobalt lithium manganese oxide materials for lithium-ion batteries, and can solve the problems of difficult growth, small gram capacity, and no objective improvement in discharge capacity and other problems to achieve the effect of improving stability, alleviating volume expansion, and improving capacity fading
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Embodiment 1
[0030] A preparation method of ytterbium-doped nickel-cobalt lithium manganese oxide material for lithium-ion batteries, comprising the following steps:
[0031] a) Press LiNi 0.32 co 0.32 mn 0.32 Yb 0.04 o 2 The stoichiometric ratio of lithium carbonate, nickel oxide, cobalt oxide, manganese oxide and ytterbium oxide is weighed so that the molar ratio of Li, Ni, Co, Mn and Yb is 1:0.32:0.32:0.32:0.04, lithium carbonate, nickel oxide The total weight of cobalt oxide, manganese oxide and ytterbium oxide is 200 parts by weight;
[0032] b) Add 200 parts by weight of absolute ethanol to the raw material weighed in step a, and ball mill for 2 hours, then take it out and dry to obtain the raw material of ytterbium-doped nickel-cobalt lithium manganese oxide;
[0033] c) Add 60 parts by weight of acetate fiber and 300 parts by weight of potassium chloride sodium chloride mixed molten salt to the ytterbium-doped nickel-cobalt lithium manganese oxide raw material prepared in step...
Embodiment 2
[0036] A preparation method of ytterbium-doped nickel-cobalt lithium manganese oxide material for lithium-ion batteries, comprising the following steps:
[0037] a) Press LiNi 0.32 co 0.32 mn 0.32 Yb 0.04 o 2The stoichiometric ratio of lithium carbonate, nickel oxide, cobalt oxide, manganese oxide and ytterbium oxide is weighed so that the molar ratio of Li, Ni, Co, Mn and Yb is 1:0.32:0.32:0.32:0.04, lithium carbonate, nickel oxide The total weight of cobalt oxide, manganese oxide and ytterbium oxide is 200 parts by weight;
[0038] b) Add 240 parts by weight of absolute ethanol to the raw material weighed in step a, and ball mill for 3 hours, then take it out and dry to obtain the raw material of ytterbium-doped nickel-cobalt lithium manganese oxide;
[0039] c) Add 75 parts by weight of acetate fiber and 400 parts by weight of potassium chloride sodium chloride mixed molten salt to the ytterbium-doped nickel-cobalt lithium manganese oxide raw material prepared in step ...
Embodiment 3
[0042] A preparation method of ytterbium-doped nickel-cobalt lithium manganese oxide material for lithium-ion batteries, comprising the following steps:
[0043] a) Press LiNi 0.32 co 0.32 mn 0.32 Yb 0.04 o 2 The stoichiometric ratio of lithium carbonate, nickel oxide, cobalt oxide, manganese oxide and ytterbium oxide is weighed so that the molar ratio of Li, Ni, Co, Mn and Yb is 1:0.32:0.32:0.32:0.04, lithium carbonate, nickel oxide The total weight of cobalt oxide, manganese oxide and ytterbium oxide is 200 parts by weight;
[0044] b) Add 280 parts by weight of absolute ethanol to the raw material weighed in step a, and ball mill for 4 hours, then take it out and dry to obtain the raw material of ytterbium-doped nickel-cobalt lithium manganese oxide;
[0045] c) Add 90 parts by weight of acetate fiber and 500 parts by weight of potassium chloride sodium chloride mixed molten salt to the ytterbium-doped nickel-cobalt lithium manganese oxide raw material prepared in step...
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