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A kind of anti-fresh cement efflorescence primer styrene-acrylic emulsion and preparation method thereof

A styrene-acrylic emulsion and cement technology, applied in the direction of coating, can solve the problems of difficult to ensure the uniformity of the acid treatment layer, increase the construction cost, neutralization of the acid layer, etc., to improve the compactness and stability, and the reaction speed is fast. , the effect of improving the penetration ability

Active Publication Date: 2019-06-28
上海巴德富实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the alkaline substances in the depth of the cement layer are gradually precipitated, and it is difficult to completely neutralize them by rubbing the acid layer, resulting in phenomena such as efflorescence and salting out, which can only be alleviated but not eliminated.
Second, it is difficult to ensure the uniformity of the acid treatment layer. The acid content is lower on the top of the wall and higher on the bottom.
This phenomenon causes normal stratification of the upper part of the efflorescence and the lower part of the wall after the paint is wiped, so that the above-mentioned wall needs to be reworked, which greatly increases the construction cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0036] The preparation method of anti-fresh cement efflorescence primer styrene-acrylic emulsion of the present invention comprises the following steps:

[0037] (1) Pre-emulsification

[0038] a: Under normal temperature and pressure, mix 1-2 parts of anionic emulsifier and 20-30 parts of water in a pre-emulsification tank, stir well until dissolved;

[0039] b: Add styrene, methyl methacrylate, isooctyl acrylate, butyl acrylate, acrylic acid, methacrylic acid, methacrylamide and cross-linking monomer to the mixture obtained in step a, and keep stirring until uniform The pre-emulsion can be obtained;

[0040] (2) Polymerization

[0041] c: Add 60-100 parts of water and 4-18 parts of anionic emulsifier to the bottom of the reaction kettle, heat up to 80-90°C while stirring, then add special functional monomers, and stir for 20-40 minutes;

[0042] d: Add the pre-emulsion obtained in step b and 0.1-0.8 parts of initiator dropwise to the mixture obtained in step c to react, the...

Embodiment 1

[0050] The anti-fresh cement efflorescence primer styrene-acrylic emulsion of the present invention comprises water, styrene, methyl methacrylate, isooctyl acrylate, butyl acrylate, acrylic acid, methacrylic acid, methacrylamide, lauryl sulfate Sodium, trimethylolpropane trimethacrylate, silica sol, sodium persulfate, organic peroxide, sodium binitrite, the contents of the above components are calculated in parts by mass: 80 parts of water, 30 parts of styrene , 20 parts of methyl methacrylate, 10 parts of isooctyl acrylate, 20 parts of butyl acrylate, 0.5 parts of acrylic acid, 0.5 parts of methacrylic acid, 1 part of methacrylamide, 5 parts of sodium lauryl sulfate, trihydroxy 1 part of methylpropane trimethacrylate, 0.5 part of silica sol, 0.2 part of sodium persulfate, 0.1 part of organic peroxide, and 0.1 part of sodium binitrite.

[0051] The preparation method of anti-fresh cement efflorescence primer styrene-acrylic emulsion of the present invention comprises the follo...

Embodiment 2

[0064] The anti-fresh cement efflorescence primer styrene-acrylic emulsion of the present invention comprises water, styrene, methyl methacrylate, isooctyl acrylate, butyl acrylate, acrylic acid, methacrylic acid, methacrylamide, lauryl sulfate Sodium, sodium dodecylbenzenesulfonate, trimethylolpropane trimethacrylate, trimethylolpropane acrylate, tripropylene glycol diacrylate, divinylbenzene, silica sol, aluminum sol, sodium persulfate , ammonium persulfate, potassium persulfate, organic peroxide, sodium binitrite, and vitamin C. The contents of the above components are calculated in parts by mass: 130 parts of water, 60 parts of styrene, and 80 parts of methyl methacrylate , 20 parts of isooctyl acrylate, 80 parts of butyl acrylate, 5 parts of acrylic acid, 5 parts of methacrylic acid, 5 parts of methacrylamide, 10 parts of sodium dodecyl sulfate, 10 parts of sodium dodecylbenzenesulfonate , 1 part of trimethylolpropane trimethacrylate, 1 part of trimethylolpropane acrylate...

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Abstract

The invention provides primer styrene-acrylic emulsion resistant to fresh cement efflorescence. The primer styrene-acrylic emulsion resistant to fresh cement efflorescence comprises components of water, styrene, methyl methacrylate, iso-octyl acrylate, butyl acrylate, acrylic acid, methacrylic acid, methacrylamide, an anionic emulsifier, cross-linking monomers, special functional monomers, an initiator, an oxidizing agent and a reducing agent, and is prepared from the components in parts by mass as follows: 80-130 parts of water, 30-60 parts of styrene, 20-80 parts of methyl methacrylate, 10-20 parts of iso-octyl acrylate, 20-80 parts of butyl acrylate, 0.5-5 parts of acrylic acid, 0.5-5 parts of methacrylic acid, 1-5 parts of methacrylamide, 5-20 parts of the anionic emulsifier, 1-5 parts of the cross-linking monomers, 0.5-2 parts of the special functional monomers, 0.2-1 part of the initiator, 0.1-0.5 parts of the oxidizing agent and 0.1-0.5 parts of the reducing agent.

Description

technical field [0001] The invention relates to the processing field of architectural coatings, in particular to a styrene-acrylic emulsion of an anti-fresh cement efflorescence primer and a preparation method thereof. Background technique [0002] With the gradual acceleration of urbanization in my country, the use of architectural coatings has become increasingly frequent. Traditional architectural coatings are usually applied after the cement is fully cured and formed. The reason is that after the cement-based putty is built on the interior and exterior walls, the cement will produce alkaline substances containing hydroxide radicals mainly calcium hydroxide during the forming process. , forming phenomena such as pan-alkaline and salting-out. This alkaline substance is extremely easy to appear through the paint film of architectural coatings, which seriously affects the normal use of architectural coatings. For this reason, the traditional cement curing and molding perio...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F212/08C08F220/14C08F220/18C08F220/06C08F220/56C08F222/14C08F222/16C08F220/28C08F212/36C08F4/40C08F2/26C09D125/14C09D133/08C09D133/12
CPCC08F2/26C08F4/40C08F212/08C08F220/14C08F220/18C08F220/1804C09D125/14C09D133/08C09D133/12C08F220/1808C08F220/06C08F220/56C08F222/103C08F222/102C08F220/282
Inventor 成煬霈黄祥斌罗云
Owner 上海巴德富实业有限公司
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