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A kind of oil shale liquefaction method

An oil shale and reactor technology, which is applied in the field of oil shale liquefaction, can solve the problems of low calorific value of bio-oil, and achieve the effects of high quality, high energy utilization rate, and reduction of energy consumption and investment cost.

Active Publication Date: 2018-06-29
SHENYANG AEROSPACE UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] At present, the liquefaction is mainly concentrated on biomass, but the oxygen content of biomass is relatively high, and the calorific value of bio-oil produced is relatively low, and oil shale liquefaction has not been reported at home and abroad. Therefore, the present invention discloses a Liquefaction method of oil shale in sub / supercritical ethanol

Method used

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  • A kind of oil shale liquefaction method

Examples

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Effect test

Embodiment 1

[0019] Example 1: First add 20g of oil shale powder and 200ml of ethanol into a clean intermittent high-temperature and high-pressure reactor, then stir evenly with a glass rod, then seal the reactor, replace the air in the reactor with high-purity nitrogen, and turn on the power Heat the reactor at a heating rate of 4-5.5°C / min, the temperature is heated to 280°C, the reaction time is 30min, the pressure is 5MPa, and the ethanol solvent is kept in a sub / supercritical state during the liquefaction reaction, and then after the reaction, Remove the jacket and use a fan to cool the reactor. When it cools down to about 30°C, open the exhaust valve and collect the gas by drainage. Then open the reactor, pour out the mixture of oil and residue, and clean the inner wall of the reactor with organic solvents. and the pipeline in the still to obtain the organic liquid and the residue mixture. Finally, the above mixture is filtered through an organic filter membrane and extracted with ace...

Embodiment 2

[0020] Embodiment two: basic steps are identical with embodiment, wherein when heating in reactor, temperature is heated to 320 ℃, and reaction time is 30min, and pressure is at 20MPa, and the oil production rate under this condition is 3.42%.

Embodiment 3

[0021] Embodiment three: basic steps are identical with embodiment, wherein when heating in reactor, temperature is heated to 360 ℃, and reaction time is 210min, and pressure is at 30MPa, and the oil production rate under this condition is 18.15%.

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Abstract

The invention discloses an oil shale liquefaction method, which belongs to the field of petrochemical industry. The method comprises the following steps: performing stirring, dissolving, gas replacing, heating reaction, cooling, gas collecting, washing and filtering, thus obtaining a liquid product and solids, vaporizing the liquid product in a constant-temperature rotating evaporator, removing a solvent ethanol to obtain oil shale, and finally drying the separated solid at a constant temperature to obtain residues. The oil shale liquefaction method has the advantages that oil shale is adopted as a raw material to prepare shale oil, so that relevant problems caused by increasing shortage of fossil energy and the utilization of the fossil energy can be alleviated; the oil shale resource is large in reserves, so that the mass development and application can be facilitated; and the drying pretreatment for the oil shale is not needed, so that the energy consumption and investment cost in the reaction process are reduced, the energy utilization rate is high, the reaction product is easy to separate, the industrialized application is facilitated, both produced gas and solid byproducts can be collected and reutilized, and energy conservation and environmental protection are achieved.

Description

technical field [0001] The invention relates to an oil shale liquefaction method. Background technique [0002] With the rapid development of social economy and the improvement of people's living standards, human needs and dependence on fossil energy have become increasingly obvious. my country's energy resources are not rich, and the per capita energy resources are far less than the world's average level. In particular, the proven oil reserves are only the world's largest. 2.3% of the total, China has become the world's second largest oil consumer next to the United States, and its dependence on imported oil has exceeded 60%. The contradiction between oil supply and demand is an unavoidable problem in China's energy development. It not only hinders the country's economic development, but also threatens national security. Therefore, it is necessary to find a resource that can replace oil to solve this contradiction, and oil shale has become an ideal substitute. Oil shale, a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G1/00
CPCC10G1/002C10G1/008C10G2300/80
Inventor 杨天华周兵开兴平李秉硕李润东
Owner SHENYANG AEROSPACE UNIVERSITY
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