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A kind of composite color cake and preparation method thereof

A composite color and carrier technology, applied in the field of polymer chemistry and polymers, can solve the problems of poor pigment dispersion, difficulty in satisfying customers, and large color difference between batches, and achieve small color difference, high safety, and easy operation Effect

Active Publication Date: 2017-12-01
FOSHAN SHUNDE BAOSITE PIGMENT +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the dispersibility of the pigment in the color cake is not good, resulting in insufficient coloring power of the product
[0005] In addition, the color masterbatches currently on the market have the problem that the color difference is difficult to control, the color difference between batches is large, and it is difficult to meet the requirements of customers.

Method used

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  • A kind of composite color cake and preparation method thereof
  • A kind of composite color cake and preparation method thereof
  • A kind of composite color cake and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Embodiment 1, a kind of composite color cake

[0038] The color cake described in Example 1 of the present invention is composed of the following components in parts by weight: 20 parts of polyethylene, 20 parts of titanium dioxide, 20 parts of titanium yellow, 1 part of iron red, 0.5 parts of carbon black, and 1 part of calcium zinc stabilizer , 25 parts of plasticizer, 100 parts of antimony trioxide, 0.5 parts of zinc stearate and 2 parts of nano calcium carbonate. Wherein, the titanium dioxide is rutile-type titanium dioxide with an average particle size of 0.15 μm, wherein particles with a particle size between 0.5 and 5 μm account for 2.5%, and the average particle size of the carbon black is 5 nm. The particle size of nano calcium carbonate is 0.01μm, and the specific surface area is 33m 2 / g, the plasticizer consists of epoxidized soybean oil and 911P in a weight ratio of 1:0.1.

[0039] Preparation:

[0040] A) Weigh each raw material, put it into a mixing ta...

Embodiment 2

[0042] Embodiment 2, a kind of composite color cake

[0043]The color cake described in Example 2 of the present invention is composed of the following components in parts by weight: 40 parts of polyvinyl chloride, 28 parts of titanium dioxide, 24 parts of titanium yellow, 3.6 parts of iron red, 0.8 part of carbon black, 4 parts of calcium zinc stabilizer parts, 54 parts of plasticizer, 150 parts of antimony trioxide, 2 parts of zinc stearate and 3 parts of nano calcium carbonate. Wherein, the titanium dioxide is rutile-type titanium dioxide with an average particle size of 0.18 μm, wherein particles with a particle size between 0.5 and 5 μm account for 3.6%, and the average particle size of the carbon black is 9.7 nm. The particle size of the nano-calcium carbonate is 0.05 μm, and the specific surface area is 41m 2 / g, the plasticizer consists of epoxidized soybean oil and 911P in a weight ratio of 1:0.5.

[0044] The preparation method is as in Example 1.

Embodiment 3

[0045] Embodiment 3, a kind of composite color cake

[0046] The color cake described in Example 3 of the present invention is composed of the following components in parts by weight: 60 parts of polypropylene, 40 parts of titanium dioxide, 30 parts of titanium yellow, 6 parts of iron red, 3 parts of carbon black, and 5 parts of calcium zinc stabilizer , 55 parts of plasticizer, 200 parts of antimony trioxide, 4 parts of zinc stearate and 6 parts of nano calcium carbonate. Wherein, the titanium dioxide is rutile-type titanium dioxide with an average particle size of 0.2 μm, wherein particles with a particle size between 0.5 and 5 μm account for 4.8%, and the average particle size of the carbon black is 13 nm. The particle size of nano calcium carbonate is 0.06μm, and the specific surface area is 52m 2 / g, the plasticizer is composed of epoxidized soybean oil and 911P in a weight ratio of 1:1.

[0047] The preparation method is as in Example 1.

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Abstract

The invention belongs to the field of high polymer chemistry and polymers, and particularly relates to a compound masterbatch and a preparation method thereof. The compound masterbatch is prepared from the following components in parts by weight: 20-60 parts of a carrier, 20-40 parts of titanium dioxide, 20-30 parts of titanium yellow, 1-6 parts of iron oxide red, 0.5-3 parts of carbon black, 1-5 parts of a stabilizing agent, 25-55 parts of a plasticizer, 100-200 parts of antimonous oxide, 0.5-4 parts of a lubricating agent and 2-6 parts of nano-calcium carbonate. According to the compound masterbatch, nano-calcium carbonate is added into the compound masterbatch to serve as a dispersing agent, the grain size and specific surface area of nano-calcium carbonate are strictly controlled, and the problem of poor dispersibility of high-content titanium dioxide can be solved; furthermore, the crystal form and the grain size of titanium dioxide are selected, and the proportion of titanium dioxide with different grain sizes is controlled, so that titanium dioxide has higher dispersibility and covering power, and a compound masterbatch with high quality is prepared and is suitable for large-scale application.

Description

technical field [0001] The invention belongs to the field of polymer chemistry and polymers, and in particular relates to a composite color cake and a preparation method thereof. Background technique [0002] The color cake is a mixture of resin and a large amount of pigments or dyes prepared into a high-concentration color. When processing, a small amount of color masterbatch is mixed with uncolored resin to achieve the colored resin or product with the designed pigment concentration. Color cake is widely used in polyvinyl chloride, polyethylene, polypropylene, polystyrene, ABS, nylon, PC, PMMA, PET and other resins to produce colorful fibers, clothing, daily plastics, wires and cables, household Electrical appliances, agricultural films, auto parts, health care equipment and other products. [0003] Chinese patent application CN104004300A discloses a color masterbatch formula, including 75-85% carrier, 5-6% additive, 3-5% dispersant, 2-3% pearl powder, 1-2% pigment, 1-2% ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L91/00C08L23/06C08L27/06C08L23/12C08K13/02C08K3/22C08K3/04C08K5/098C08K3/26
CPCC08K2201/003C08K2201/006C08K2201/011C08L23/12C08L27/06C08L91/00C08L2201/08C08L23/06C08K13/02C08K2003/2241C08K2003/2272C08K3/04C08K3/2279C08K5/098C08K2003/265
Inventor 黄少明毕俊涛鄢麒麟
Owner FOSHAN SHUNDE BAOSITE PIGMENT
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