Special high-flame-retarding unsaturated polyester resin adhesive for quartz stone sheet material

A technology of quartz stone plate and polyester resin, applied in the direction of non-polymer adhesive additives, aldehyde/ketone condensation polymer adhesives, adhesive types, etc., which can solve poor toughness, poor flame retardancy, etc. Problems, achieve the effect of improving strength and toughness, optimizing curing density, and improving bond strength

Inactive Publication Date: 2017-05-31
安徽艾蒂贝生物股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Unsaturated polyester resin is one of the most widely used types of resins. It is widely used in the fields of structure, anti-corrosion, and insulating materials. It is also widely used in the field of adhesives, but the general-purpose unsaturated polyester resin is still There are some shortcomings, such as poor toughness after curing, poor flame retardancy, etc., which limit the application of unsaturated polyester resin adhesives

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A high flame-retardant unsaturated polyester resin adhesive for quartz stone plates proposed by the present invention, its raw materials include by weight: 50 parts of unsaturated polyester resin, 15 parts of styrene, 20 parts of pentaerythritol triacrylate, methyl 2 parts of isooctyl acrylate, 1.5 parts of 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-propanone, 2,4,6-trimethylbenzoyl di 0.5 part of phenyl phosphorus oxide, 1 part of methyl ethyl ketone peroxide, 0.05 part of leveling agent, 0.1 part of defoamer, 0.2 part of silane coupling agent, 5 parts of fumed silica, 1 part of zinc stannate, modified aluminum hydroxide 10 parts, 2 parts of bisphenol A bis(diphenyl phosphate), 5 parts of phenolic resin, 1 part of ammonium polyphosphate.

Embodiment 2

[0017] A high flame-retardant unsaturated polyester resin adhesive for quartz stone plates proposed by the present invention, its raw materials include by weight: 30 parts of unsaturated polyester resin, 30 parts of styrene, 8 parts of pentaerythritol triacrylate, methyl 12 parts of isooctyl acrylate, 0.2 parts of 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-propanone, 2,4,6-trimethylbenzoyl di 1.5 parts of phenyl phosphorus oxide, 0.2 parts of methyl ethyl ketone peroxide, 0.15 parts of leveling agent, 0.05 parts of defoaming agent, 0.5 parts of silane coupling agent, 2 parts of fumed silica, 5 parts of zinc stannate, modified aluminum hydroxide 2 parts, 8 parts of bisphenol A bis(diphenyl phosphate), 1 part of phenolic resin, 5 parts of ammonium polyphosphate.

Embodiment 3

[0019] A high flame-retardant unsaturated polyester resin adhesive for quartz stone plates proposed by the present invention, its raw materials include by weight: 35 parts of unsaturated polyester resin, 25 parts of styrene, 12 parts of pentaerythritol triacrylate, methyl 10 parts of isooctyl acrylate, 1 part of 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-propanone, 1 part of 2,4,6-trimethylbenzoyl di 1.3 parts of phenyl phosphorus oxide, 0.5 parts of methyl ethyl ketone peroxide, 0.13 parts of leveling agent, 0.07 parts of defoamer, 0.38 parts of silane coupling agent KH-560, 2.8 parts of fumed silica, 5 parts of zinc stannate, modified 4 parts of aluminum hydroxide, 6 parts of bisphenol A bis(diphenyl phosphate), 2.5 parts of phenolic resin, 4.5 parts of ammonium polyphosphate;

[0020] Wherein, the modified aluminum hydroxide is prepared according to the following process: add 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, silane coupling agent KH-560 in the reactio...

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PUM

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Abstract

The invention discloses a special high-flame-retarding unsaturated polyester resin adhesive for a quartz stone sheet material. The special high-flame-retarding unsaturated polyester resin adhesive is prepared from the following raw materials: unsaturated polyester resin, styrene, pentaerythritol triacrylate, methyl methacrylate isooctyl, 2-methyl-1-(4-methylthiophenyl)-2-morpholinyl-1-acetone, 2,4,6-trimethylbenzoyl diphenyl phosphine oxide, methyl ethyl ketone peroxide, a flatting agent, a de-foaming agent, a silane coupling agent, gas-phase silicon dioxide, zinc stannate, modified aluminum hydroxide, bisphenol A bi(diphenyl phosphate), phenol-formaldehyde resin and ammonium polyphosphate. The special high-flame-retarding unsaturated polyester resin adhesive for the quartz stone sheet material, provided by the invention, has excellent flame-retarding performance, high binding performance and good impacting toughness.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a high flame-retardant unsaturated polyester resin adhesive specially used for quartz stone plates. Background technique [0002] Quartz is a mineral resource with very stable physical and chemical properties. Quartz stone is an abbreviation for the plates produced by quartz stone plate manufacturers. Non-toxic, non-toxic and radiation-free, etc., it has been widely used in public buildings, hotels, restaurants, banks, hospitals, exhibitions, laboratories, etc. Door sets and other fields. During the use of quartz stone plates, adhesives need to be used for splicing. [0003] Unsaturated polyester resin is one of the most widely used types of resins. It is widely used in the fields of structure, anti-corrosion, and insulating materials. It is also widely used in the field of adhesives, but the general-purpose unsaturated polyester resin is still There are some shortcomings, s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J167/06C09J161/06C09J11/04C09J11/06
CPCC09J167/06C08L2201/02C09J11/04C09J11/06C08L61/06C08K13/06C08K5/54C08K3/36C08K3/24C08K9/04C08K9/06C08K2003/2227C08K5/523C08K2003/323
Inventor 杨立新
Owner 安徽艾蒂贝生物股份有限公司
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