3D (three-dimensional) printing light-cured resin and preparation method thereof

A light-curing resin and 3D printing technology, applied in the direction of additive processing, etc., can solve the problems of low molding efficiency and fast curing, and achieve the effects of fast molding speed, improved processing efficiency, and high light sensitivity

Inactive Publication Date: 2017-07-25
HANS LASER TECH IND GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of the above-mentioned deficiencies in the prior art, the purpose of the present invention is to provide a 3D printing photocurable resin and its preparation method, aiming to solve the problem that the existing 3D printing photocurable resin cannot be quickly cured in a short time and the molding efficiency is low. question

Method used

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  • 3D (three-dimensional) printing light-cured resin and preparation method thereof
  • 3D (three-dimensional) printing light-cured resin and preparation method thereof
  • 3D (three-dimensional) printing light-cured resin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] In parts by weight, add 1 part of benzoin dimethyl ether as a photoinitiator to 20 parts of 1,6-hexanediol diacrylate, and then ultrasonically vibrate evenly in a water bath at 40 ° C to dissolve the photoinitiator until transparent , to obtain an intermediate mixture; then add 20 parts of hyperbranched polyester acrylate, 15 parts of aliphatic urethane acrylate, and 15 parts of aromatic urethane acrylate into the intermediate mixture in turn, adding 1 part of peacock Stone green is used as a dyeing agent, 0.1 part of BYK-056 from BYK is added as a leveling agent, and 0.1 part of phenyl o-hydroxybenzoate is added as an ultraviolet light absorber. Finally, after 10 minutes of ultrasonic vibration, the 3D printing photocurable resin is prepared. .

[0052] The 3D printing light-curing resin prepared in this example was printed by a molecular sieve ultra-fast 3D printing equipment, and it was found that the curing time of a single layer of the resin was within 0.5s, and a ...

Embodiment 2

[0054] In parts by weight, 10 parts of 2-phenylbenzyl-2-dimethylamine-1-(4-morpholinebenzylphenyl) butanone was added to 40 parts of trimethylolpropane triacrylate as photoinitiator in a water bath at 60°C, and ultrasonically vibrate evenly to dissolve the photoinitiator until transparent to obtain an intermediate mixture; then add 35 parts of hyperbranched polyester acrylate, 15 parts of aliphatic urethane acrylate, 20 parts of Acrylic resin oligomer composed of a mixture of aromatic urethane acrylates, adding 10 parts of eosin Y as a dyeing agent, adding 5 parts of BYK-501A from BYK as a leveling agent, adding 5 parts of 2-hydroxy-4- Methoxybenzophenone is the ultraviolet light absorber, and after 30 minutes of ultrasonic vibration, the 3D printing photocurable resin is prepared.

[0055] The 3D printing light-curing resin prepared in this example was printed through a molecular sieve ultra-fast 3D printing device, and it was found that the curing time of a single layer of r...

Embodiment 3

[0057] In parts by weight, 2 parts of benzoin dimethyl ether and 1 part of 1-hydroxycyclohexyl phenyl ketone were added as photoinitiators to 7.5 parts of 1,6-hexanediol diacrylate, 7.5 parts of trimethylolpropane Triacrylate, 15 parts of polydipentaerythritol hexaacrylate; then ultrasonically vibrated in a water bath at 50°C to dissolve the photoinitiator until transparent to obtain an intermediate mixture; then add 30 parts of hyperbranched polyester to the intermediate mixture in sequence Acrylic resin oligomer composed of a mixture of acrylate, 15 parts of aliphatic urethane acrylate and 15 parts of aromatic urethane acrylate, adding 6 parts of malachite green as a dyeing agent, adding 3 parts of BYK-056 from BYK as a fluid As a leveling agent, add 2 parts of phenyl o-hydroxybenzoate as a UV light absorber, and finally oscillate with ultrasonic waves for 15 minutes to prepare a 3D printing photocurable resin.

[0058] The 3D printing light-curing resin prepared in this exa...

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Abstract

The invention discloses a 3D (three-dimensional) printing light-cured resin and a preparation method thereof. The 3D printing light-cured resin is prepared from the following components in parts by weight: 50 to 70 parts of acrylic resin oligomers, 20 to 40 parts of a reactive diluent, 1 to 10 parts of a photoinitiator, 1 to 10 parts of a coloring agent and 0.1 to 5 parts of a flatting agent. The 3D printing light-cured resin disclosed by the invention has the advantages of high light sensitivity and fast forming speed; the purpose of enabling resin monolayer curing time to be within 0.5s can be realized; 3D printing equipment can achieve a forming speed of 220 to 360mm/h; and the processing efficiency of the 3D printing equipment is greatly improved.

Description

technical field [0001] The invention relates to the field of photocurable resins, in particular to a 3D printing photocurable resin suitable for rapid curing of molecular sieve ultrafast 3D printing equipment and a preparation method thereof. Background technique [0002] Since the emergence of 3D printing technology in the 1980s, 3D printing equipment suitable for different fields and with different functions have been developed at home and abroad. The 3D printing equipment of DLP (Digital Light Processing, digital light processing) technology is a very important one among many technical routes. At the same time, the ultra-fast 3D printing equipment improved by molecular sieve is an upgraded product in terms of processing efficiency of traditional DLP technology 3D printing equipment. Therefore, this kind of molding requires 3D printing photocurable resin to be highly sensitive to light and capable of curing in a short time. [0003] At present, the 3D printing photocurab...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/01C08F220/20B33Y70/00C08L51/08C08K5/07C08K3/22
CPCC08F283/01B33Y70/00C08K3/22C08K5/07C08K2003/2272C08F220/20C08L51/08
Inventor 李喜露袁剑刘武高云峰
Owner HANS LASER TECH IND GRP CO LTD
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