A device and conversion method for removing and converting tar in biomass synthesis gas

A synthesis gas and biomass technology, applied in chemical instruments and methods, separation methods, combustible gas purification, etc., can solve the problems of difficult tar removal, difficult regeneration, and easy clogging of adsorbents, so as to avoid catalyst carbon deposition and deactivation Effect

Active Publication Date: 2019-08-02
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The purpose of the present invention is to solve the problems in the prior art that the removal of tar is difficult, and the adsorbent is easy to block and difficult to regenerate, and proposes a device and conversion method for the removal and conversion of tar in biomass synthesis gas, and the tar is synthesized by dry adsorption The gas is purified, and then the tar is catalyzed and oxidized in situ to regenerate the adsorbent. At the same time, the energy released by the tar is used to produce water vapor to realize the utilization of tar energy.

Method used

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  • A device and conversion method for removing and converting tar in biomass synthesis gas

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Embodiment 1

[0034] A device for removing and converting tar in biomass synthesis gas, comprising a tar removal reactor, and the tar removal reactor is respectively connected to a synthesis gas inlet pipeline, a purified synthesis gas outlet pipeline, an air inlet pipeline, a smoke Gas outlet pipeline, cooling water inlet pipeline and cooling water outlet pipeline, the air inlet pipeline is connected to the air preheater, and a set of casing-type reaction tubes are arranged inside the tar removal reactor, and the The sleeve-type reaction tube is composed of an inner tube and an outer tube, the inner tube communicates with the cooling water inlet pipeline and the cooling water outlet pipeline, and the outer tube is gas-permeable The filter tube is loaded with a catalyst that catalyzes tar oxidation, and the annular space formed by the inner tube and the outer tube communicates with the synthesis gas inlet pipeline and the flue gas outlet pipeline.

[0035] The device for removing and conver...

Embodiment 2

[0048] The difference between this example and Example 1 is that in the device for removing and converting tar in biomass synthesis gas described in this example, the described tar removal reactor adopts two pairs of the first tar The removal reactor 1 and the second tar removal reactor 2, the synthesis gas inlet 1-A of the first tar removal reactor 1 and the synthesis gas inlet 2-A of the second tar removal reactor 2 pass through the The syngas inlet pipeline of a switching valve is connected, the air inlet 2-A of the first tar removal reactor 1 and the air inlet 2-B of the second tar removal reactor 2 pass through the air inlet with the second switching valve Pipeline connection; the synthesis gas outlet 1-C of the first tar removal reactor 1 is connected to the first control valve, and the synthesis gas outlet 2-C of the second tar removal reactor 2 is connected to the second control valve; the first tar removal The flue gas outlet 1-D of the removal reactor 1 is connected ...

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Abstract

The invention provides a device for removing and converting tar in a biomass synthesis gas and a conversion method. The device comprises a tar removal reactor, wherein the tar removal reactor is connected with a synthesis gas inlet pipe, a purified synthesis gas outlet pipe, an air inlet pipe, a smoke outlet pipe, a cooling water inlet pipe and a cooling water outlet pipe separately; the air inlet pipe is connected with an air preheater; a group of sleeve type reaction tubes are arranged in the tar removal reactor; each sleeve type reaction tube comprises an inner tube and an outer tube; each inner tube communicates with the cooling water inlet pipe and the cooling water outlet pipe; each outer tube is a gas-permeable filter tube; each filter is loaded with a catalyst for catalyzing tar oxidation; and an annular space formed by the inner tubes and the outer tubes communicates with the synthesis gas inlet pipe and the smoke outlet pipe. Removal and purification of the synthesis gas and tar energy utilization are achieved, an adsorbent is regenerated and the utilization of biomass can be improved.

Description

[0001] Technical field: [0002] The invention relates to a device and a conversion method for removing and converting tar in biomass synthesis gas, belonging to the technical field of biomass resource utilization. [0003] Background technique: [0004] Biomass gasification to produce synthesis gas or hydrogen-rich gas is one of the important ways of biomass thermochemical conversion and utilization. At present, the key problem in practical application is that the presence of tar in the gas product will easily lead to pipeline blockage and affect the normal operation of downstream equipment. operation, and reduces the effective utilization of biomass. [0005] At present, the main technologies for tar removal and purification include physical methods and chemical methods. Physical methods mainly include gas wet scrubbing, gas dry filtration and electrostatic removal. Wet water washing or liquid absorbents have good tar removal ability, but the purification process not only w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D46/00C10K1/04C10K1/26C10K1/32
CPCY02P20/129
Inventor 肖军孙亭亭沈来宏
Owner SOUTHEAST UNIV
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