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Preparation method of weather resistance type static crushing agent

A static crushing agent, weather-resistant technology, used in chemical instruments and methods, earthwork drilling, inorganic chemistry, etc., can solve the problem of slow hydration reaction speed, low crushing efficiency, and crushing effect The water-cement ratio has a great influence on problems such as improving the hydration rate, not easy to aggregate, and increasing the hydration space.

Inactive Publication Date: 2017-09-15
闫博文
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The main technical problem to be solved by the present invention is to provide a weather-resistant crushing agent for the defects that the hydration reaction speed of the existing static crushing agent is slow, the crushing efficiency is low, and the crushing effect is greatly affected by the ambient temperature, water temperature, and water-cement ratio. The preparation method of static breaking agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0021] First, place the three-necked flask in an ice-water bath at 0°C, and mix the acrylic acid monomer and deionized water in the three-necked flask at a mass ratio of 1:1, stir and mix, and vent the air with nitrogen, and then under a nitrogen atmosphere, Place the three-necked flask at room temperature, dropwise add 30% sodium hydroxide solution into the three-necked flask, adjust the pH to 6.5, and keep stirring for 10 minutes to prepare the matrix mixture, which is weighed in parts by weight 45 parts of matrix mixture, 10 parts of 0.5% hydrogen peroxide, 10 parts of vitamin C and 25 parts of N,N'-methylenebisacrylamine were placed in a three-necked flask, heated in a water bath at 45°C for 3 hours, and then heated in a water bath After completion, the filter residue was filtered and vacuum freeze-dried to prepare a porous water-absorbing resin. Then, according to the mass ratio of 1:1:10, nano-iron powder, nano-aluminum powder and porous water-absorbing resin were placed ...

example 2

[0024]First, place the three-necked flask in an ice-water bath at 3°C, and mix the acrylic acid monomer and deionized water in the three-necked flask at a mass ratio of 1:1, stir and mix, and vent the air with nitrogen, and then under a nitrogen atmosphere, Place the three-necked flask at room temperature, add 30% sodium hydroxide solution dropwise into the three-necked flask, adjust the pH to 6.8, and keep stirring for 13 minutes to prepare the matrix mixture, which is weighed in parts by weight 48 parts of matrix mixture, 13 parts of 0.5% hydrogen peroxide, 13 parts of vitamin C and 28 parts of N,N'-methylenebisacrylamine were placed in a three-necked flask, heated in a water bath at 50°C for 4 hours, and then heated in a water bath After completion, the filter residue was filtered and vacuum freeze-dried to prepare a porous water-absorbing resin. Then, according to the mass ratio of 1:1:10, nano-iron powder, nano-aluminum powder and porous water-absorbing resin were placed i...

example 3

[0027] First, place the three-necked flask in an ice-water bath at 5°C, and mix the acrylic acid monomer and deionized water in the three-necked flask according to the mass ratio of 1:1, stir and mix and exhaust the air with nitrogen, and then under nitrogen atmosphere, Place the three-necked flask at room temperature, add 30% sodium hydroxide solution dropwise to the three-necked flask, adjust the pH to 7.0, and keep stirring for 15 minutes to prepare the matrix mixture, which is weighed in parts by weight 50 parts of matrix mixture, 15 parts of 0.5% hydrogen peroxide, 15 parts of vitamin C and 30 parts of N,N'-methylenebisacrylamine were placed in a three-necked flask, heated in a water bath at 55°C for 5 hours, and then heated in a water bath After completion, the filter residue was filtered and vacuum freeze-dried to prepare a porous water-absorbing resin. Then, according to the mass ratio of 1:1:10, nano-iron powder, nano-aluminum powder and porous water-absorbing resin we...

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Abstract

The invention discloses a preparation method of a weather-resistant static crushing agent, belonging to the technical field of silent crushing. In the present invention, the acrylic acid monomer is mixed with deionized water to adjust the pH, and then the base mixed solution is heated and filtered with hydrogen peroxide and vitamin C, and the filter cake is collected to freeze-dry the porous water-absorbing resin, and nano-iron powder, nano-aluminum powder and porous The water-absorbent resin is mixed and sieved to obtain mixed ball mill powder, the calcium hydroxide slurry is mixed, and phosphoric acid solution is added dropwise for reaction, and then filtered and the filter cake is collected for calcining, and the calcined powder is collected and mixed with sodium chloride and mixed ball mill powder for milling and sieving to produce After obtaining the crushing agent matrix powder, place it in a mold for pressing and forming, and finally demould and dry and cool to obtain a weather-resistant static crushing agent. The static crushing agent prepared by the present invention has fast hydration reaction speed, high crushing efficiency, and the crushing effect is affected by Ambient temperature, water temperature, and water-cement ratio have little influence, and have broad application prospects.

Description

technical field [0001] The invention discloses a preparation method of a weather-resistant static breaker, which belongs to the technical field of breaker preparation. Background technique [0002] Static breaker is a new material that uses material expansion force to break and cut brittle media. It can be widely used in rock and concrete crushing, as well as cutting and mining of stone and various precious brittle materials. It has the characteristics of no shock wave, no vibration, no flying stone, no noise and no harmful gas hazard. [0003] Static breaking agent is a substance containing elements such as aluminum, magnesium, calcium, iron, oxygen, silicon, and chromium. It is a non-flammable, non-explosive, and non-toxic substance. It is mixed with an appropriate amount of water to form a fluid slurry and directly loaded into the blasthole. In the middle, after hydration, a huge expansion pressure is generated and applied to the hole wall to quietly break the concrete s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B26/20C01F11/18C08F220/06C08F222/38E21C37/00
CPCC04B26/20C01F11/181C08F220/06E21C37/00
Inventor 闫博文王艳芹孙冬
Owner 闫博文