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Application and preparation method of a ceramic material as a high-temperature stable piezoelectric energy harvesting material

A technology of ceramic materials and piezoelectric ceramics, applied in piezoelectric effect/electrostrictive or magnetostrictive motors, piezoelectric/electrostrictive/magnetostrictive devices, circuits, etc., can solve the problems of low piezoelectric activity, Unable to meet the requirements of high-power piezoelectric energy harvesting devices, etc., to achieve excellent results, improve high-temperature energy harvesting performance, and achieve significant economic and social value

Active Publication Date: 2020-07-31
BEIJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the piezoelectric ceramic material system, materials with high Curie temperature mainly include bismuth layer structure system and tungsten bronze structure system, but their piezoelectric activity is low, which cannot meet the requirements of high-power piezoelectric energy harvesting devices.

Method used

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  • Application and preparation method of a ceramic material as a high-temperature stable piezoelectric energy harvesting material
  • Application and preparation method of a ceramic material as a high-temperature stable piezoelectric energy harvesting material
  • Application and preparation method of a ceramic material as a high-temperature stable piezoelectric energy harvesting material

Examples

Experimental program
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Effect test

Embodiment 1

[0037] According to the chemical formula 0.37BiScO 3 -0.63PbTiO 3 , where the value of x is 0.63. Weigh Pb 3 o 4 、TiO 2 、 Bi 2 o 3 and Sc 2 o 3 , and ball milled in anhydrous ethanol medium for 12h. After the mixture was dried, it was calcined at 800°C for 2 hours; absolute ethanol was added for secondary ball milling, and the obtained powder was pressed into a ceramic green body by adding 5 wt% PVA binder, and calcined at 1150°C for 2 hours after debinding. The sintered ceramic sheet is printed and infiltrated with silver electrodes, in silicone oil at 120°C, at 40kV·cm -1 The voltage was polarized for 30min to obtain BSPT high temperature piezoelectric material.

Embodiment 2

[0039] According to the chemical formula 0.36BiScO 3 -0.64PbTiO 3 , where x takes a value of 0.64. Others are with embodiment 1.

Embodiment 3

[0041] According to the chemical formula 0.35BiScO 3 -0.65PbTiO 3 , where x takes a value of 0.65. Others are with embodiment 1.

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Abstract

The invention belongs to the field of piezoceramic materials and discloses application of a ceramic material as a high-temperature stable piezoelectric energy collection material and a preparation method. A matrix chemical composition of the ceramic material is (1-x)BiScO3-xPbTiO3, wherein x and 1-x refer to mole fractions of PbTiO3 and BiScO3 respectively, and a value range of x is 0.55-0.70. Theceramic material applied as the high-temperature stable piezoelectric energy collection material is high in energy conversion coefficient and low energy conversion coefficient temperature change rate, wherein at a temperature of 200 DEG C, the energy conversion coefficient is d33*g33=8950*10<-15>m<2> / N; in a wide temperature range of 25-300 DEG C, the energy conversion coefficient temperature change rate (d33*g33)N is smaller than or equal to + / -6%. The ceramic material is applied to high-temperature piezoelectric energy collection devices, waste vibration energy in high-temperature environments can be efficiently recycled, and remarkable social significance and economic value are achieved.

Description

technical field [0001] The invention belongs to the field of piezoelectric ceramic materials, in particular to a ceramic material with high conversion coefficient and low temperature change rate of the conversion coefficient, which is applied to high-temperature piezoelectric energy collection devices, and a preparation method thereof. Background technique [0002] With the increasingly serious problem of energy shortage, the development and utilization of new energy has become the focus of attention of all countries. Piezoelectric energy harvesting devices can efficiently recycle the discarded vibration energy in the environment, which is of great significance for realizing the self-power supply of micro-devices such as sensors, and has been widely used in medical, communication and other fields of life and work. At present, the most typical piezoelectric material is the PZT system material, whose Curie temperature is about 180-386°C, but the actual safe use temperature is ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L41/187C04B35/472C04B41/88
CPCC04B35/472C04B41/009C04B41/5116C04B41/88C04B2235/3224C04B2235/3298C04B2235/6562C04B2235/96H02N2/186H02N2/22C04B41/0072
Inventor 侯育冬赵海燕郑木鹏贾文旭朱满康
Owner BEIJING UNIV OF TECH
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