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A kind of preparation method of welding wire for aluminum and aluminum alloy robot with ZN+CU/RE composite coating

A composite coating and electrochemical technology, applied in the direction of liquid chemical plating, coating, metal material coating process, etc., can solve the problem of affecting welding wire feeding and arc stability, not being able to adapt to robot welding, and dense aluminum oxide film Refractory and other problems, to achieve the effect of eliminating the surface and internal pores of the weld, excellent welding comprehensive process performance, and good compactness

Active Publication Date: 2020-01-10
江苏恒熠金属制品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the manufacturing process of existing aluminum and aluminum alloy welding wire, the surface oxide skin is usually removed by mechanical scraping, but the waste of material is large, especially after the treatment, the surface of the welding wire is uneven, the roughness is large, and the pits and scratches are detailed, which affects the welding process. Filamentity and arc stability, increased contact tip wear
At the same time, the aluminum oxide film that may be formed on the surface of the welding wire is dense and infusible, and a series of defects such as incomplete penetration, slag inclusion, and pores are prone to occur during welding, and the amount of welding smoke is large
In addition, aluminum and aluminum alloy welding wire welding needs to use a welding power source with a special Teflon wire feeding hose in order to reduce the wire feeding resistance of the welding wire, but the replacement frequency is high, the overall cost is high, and the production efficiency is low
Although the surface of the welding wire can be coated with copper to improve the surface quality of the welding wire, there is a phenomenon that the copper chipping is easy to fall off, and it is not suitable for robot welding, especially the accumulation of copper chipping in the non-Teflon wire feeding hose is more serious
Therefore, the application of aluminum and aluminum alloy welding wire, especially in robotic automated welding, is greatly limited

Method used

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  • A kind of preparation method of welding wire for aluminum and aluminum alloy robot with ZN+CU/RE composite coating
  • A kind of preparation method of welding wire for aluminum and aluminum alloy robot with ZN+CU/RE composite coating
  • A kind of preparation method of welding wire for aluminum and aluminum alloy robot with ZN+CU/RE composite coating

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Embodiment 1

[0020] A preparation method of welding wire for aluminum and aluminum alloy robots with electrochemical Zn+Cu composite coating, the substrates are respectively SA1 4043 and SA1 5356 aluminum alloy wire rods, wherein the diameter of the wire rods is 9.5 mm, and the specific preparation steps are as follows:

[0021] (1) Pre-treatment includes ultrasonic + lye degreasing treatment, 2 high-pressure cold water rinses, ultrasonic + activation solution to remove oxide film, 2 high-pressure cold water rinses, completely remove grease, scale and oxide film on the surface of the wire rod, and make the substrate clean active crystal surface. Wherein, the lye is composed of 45g / L sodium hydroxide, 60g / L sodium carbonate, 56g / L sodium phosphate, 20g / L sodium silicate, 5g / L sodium pyrophosphate and tap water, and the degreasing reaction temperature is 60°C. The reaction time is 240s; the activation solution is composed of 500ml / L nitric acid and tap water, the reaction temperature for deo...

Embodiment 2

[0025] A preparation method of electrodeposited Zn+Cu / Re composite coating aluminum and aluminum alloy welding wire for robots. The substrates are respectively SA1 4043 and SA1 5356 aluminum alloy wire rods, wherein the diameter of the wire rod is 6.5 mm. The specific preparation steps as follows:

[0026](1) Pre-treatment includes ultrasonic + lye degreasing treatment, 2 high-pressure cold water rinses, ultrasonic + activation solution to remove oxide film, 2 high-pressure cold water rinses, completely remove grease, scale and oxide film on the surface of the wire rod, and make the substrate clean active crystal surface. Wherein, the lye is composed of 30g / L sodium hydroxide, 25g / L sodium carbonate, 40g / L sodium phosphate, 25g / L sodium silicate, 10g / L sodium pyrophosphate and tap water, and the degreasing reaction temperature is 60°C. The reaction time is 180s; the activation solution is composed of 400ml / L nitric acid and tap water, the reaction temperature for deoxidation ...

Embodiment 3

[0030] A preparation method of electrodeposited Zn+Cu / Re composite coating aluminum and aluminum alloy welding wire for robots. The substrates are respectively SA1 4043 and SA1 5356 aluminum alloy wire rods, wherein the diameter of the wire rods is 2.5 mm. Specific preparation steps as follows:

[0031] (1) Pre-treatment includes ultrasonic + lye degreasing treatment, 2 high-pressure cold water rinses, ultrasonic + activation solution to remove oxide film, 2 high-pressure cold water rinses, completely remove grease, scale and oxide film on the surface of the wire rod, and make the substrate clean active crystal surface. Wherein, the lye is composed of 15g / L sodium hydroxide, 20g / L sodium carbonate, 50g / L sodium phosphate, 30g / L sodium silicate, 15g / L sodium pyrophosphate and tap water, and the degreasing reaction temperature is 60°C. The reaction time is 90s; the activation solution is composed of 300ml / L nitric acid and tap water, the reaction temperature for deoxidation fil...

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Abstract

The invention relates to the field of welding wire manufacturing, in particular to a preparation method of an aluminum and aluminum alloy welding wire electrochemically plated with a Zn+Cu / Re composite coating and applied to robot welding. A pure aluminum or aluminum alloy wire rod is used as the matrix. Pretreatment, electrochemical plating of the Zn+Cu / Re composite coating and post-treatment areconducted on the surface. The electrochemically plated Zn+Cu / Re composite coating has the functions of reducing welding smoke, improving the porosity resistance of the welding wire and improving solid lubrication and meanwhile fills up pits in the surface of the welding wire matrix, and the electric conductivity and surface quality of the welding wire are improved; the bonding force and strengthof the Zn+Cu / Re composite coating are high, the aluminum or copper peeling phenomenon is avoided, the Zn+Cu / Re composite coating is high in compactness, good in rust resistance and resistant to wear,Zn can reduce welding smoke and splashes, and Re can refine plating layer crystals and reduce the void ratio; and meanwhile, molten bath stirring is enhanced, a molten bath is purified, crystals are refined, pores on the surface and on the inner portion of a welding joint are thoroughly eradicated, and the porosity resistance of the welding wire is improved.

Description

technical field [0001] The invention relates to the field of welding wire manufacturing, in particular to a method for preparing electrodeposited Zn+Cu / Re composite coating aluminum and aluminum alloy welding wire for robots. [0002] technical background [0003] Due to the advantages of low density, small specific gravity, high electrical and thermal conductivity, good casting and machining performance, aluminum and aluminum alloys have been widely used in aviation, aerospace, vehicles, ships, electrical appliances, construction and chemical industries. With the development of industrial automation, most aluminum and aluminum alloy components need to be welded by advanced robots. Therefore, higher requirements are put forward for the surface quality and welding performance of aluminum and aluminum alloy welding wires. [0004] In the manufacturing process of existing aluminum and aluminum alloy welding wire, the surface oxide skin is usually removed by mechanical scraping,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C18/40C23C18/18C25D3/38C25D5/34
CPCC23C18/1844C23C18/40C25D3/38C25D5/34
Inventor 栗卓新张天理
Owner 江苏恒熠金属制品有限公司
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