Nail polish water-based polyurethane resin and preparation method thereof
A water-based polyurethane and nail polish technology, which is applied in the field of water-based polyurethane, can solve the problems of reducing the protective effect of the coating film on nails, poor oil resistance and temperature resistance of the coating, and contrary to the concept of green and environmental protection development, so as to improve fastness and hydrolysis. Stability, good stability, improve the effect of anti-flocculation stability
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Embodiment 1
[0028] Embodiment 1 environment-friendly type nail polish aqueous polyurethane resin
[0029] The environment-friendly nail polish water-based polyurethane resin of the present embodiment comprises the following raw materials prepared by weight:
[0030]
[0031]
[0032] The preparation method of above-mentioned environment-friendly solvent-free nail polish aqueous polyurethane resin comprises the following steps:
[0033] (1) Under the protection of dry nitrogen, add 80 grams of polytetrahydrofuran ether glycol and 26.7 grams of isophorone diisocyanate after vacuum dehydration at 120 ° C for 2 hours into the reactor, and control the temperature at 70-90 °C under mechanical stirring. ℃ for 2 hours;
[0034] (2) Reduce the temperature of the reaction system to 40-60°C, add 5.6 grams of 1,6-hexanediol and 3.5 grams of dimethylol propionic acid, and react at 70-85°C for 3 hours;
[0035] (3) Reduce the temperature of the reaction system to below 50°C, add 2.45 grams of t...
Embodiment 2
[0036] Embodiment 2 environment-friendly type nail polish aqueous polyurethane resin
[0037] The environment-friendly nail polish water-based polyurethane resin of the present embodiment comprises the following raw materials prepared by weight:
[0038]
[0039]
[0040] The preparation method of above-mentioned environment-friendly solvent-free nail polish aqueous polyurethane resin comprises the following steps:
[0041] (1) Under the protection of dry nitrogen, 40 grams of polytetrahydrofuran ether glycol, 40 grams of polypropylene glycol, and 44.4 grams of isophorone diisocyanate after vacuum dehydration at 120 ° C for 2 hours were added to the reactor and controlled under mechanical stirring. The temperature is 70 ~ 90 ℃ to react for 2 hours;
[0042] (2) Reduce the temperature of the reaction system to 40-60°C, add 4.0 grams of diethylene glycol, 5.0 grams of dimethylol butyric acid, and react at 70-85°C for 3 hours;
[0043] (3) Reduce the temperature of the re...
Embodiment 3
[0044] Embodiment 3 environment-friendly type nail polish aqueous polyurethane resin
[0045] The environment-friendly nail polish water-based polyurethane resin of the present embodiment comprises the following raw materials prepared by weight:
[0046]
[0047]
[0048] The preparation method of above-mentioned environment-friendly solvent-free nail polish aqueous polyurethane resin comprises the following steps:
[0049] (1) Under the protection of dry nitrogen, add 40 grams of polycaprolactone diol, 40 grams of polybutylene adipate diol, and 34.8 grams of toluene diisocyanate after vacuum dehydration at 120 ° C for 2 hours into the reactor , under mechanical stirring, control the temperature at 70-90°C for 2 hours;
[0050] (2) Reduce the temperature of the reaction system to 40-60°C, add 5.6 grams of diethylene glycol, 3.5 grams of bishydroxysulfonate, and react at 70-85°C for 3 hours;
[0051](3) Reduce the temperature of the reaction system to below 50°C, add 2....
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