Unlock instant, AI-driven research and patent intelligence for your innovation.

Transition metal complex as phosphorescent material, and preparation method and application of transition metal complex

A transition metal and phosphorescent material technology, applied in luminescent materials, platinum-based organic compounds, compounds containing elements of Group 8/9/10/18 of the periodic table, etc., can solve the problems of small color adjustment range and achieve luminous efficiency High, easy-to-use effects

Inactive Publication Date: 2018-11-06
YANTAI XIANHUA OPTOELECTRONICS INST CORP LTD
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Usually, in order to change the color of the emitted light, electron-donating groups and electron-withdrawing groups can be added to the ligands of the luminescent material to adjust the color of the emitted light, but this scheme has a small adjustment range for the color

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Transition metal complex as phosphorescent material, and preparation method and application of transition metal complex
  • Transition metal complex as phosphorescent material, and preparation method and application of transition metal complex
  • Transition metal complex as phosphorescent material, and preparation method and application of transition metal complex

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The synthesis of iridium complex Ir10, the reaction equation is as follows:

[0037] (1) Synthesis of chlorine-bridged dimers

[0038]

[0039] (2) Target synthesis

[0040]

Embodiment 2

[0042] The synthesis of iridium complex Ir7, reaction equation is as follows:

[0043] (1) Synthesis of chlorine-bridged dimers

[0044]

[0045] (2) Target synthesis

[0046]

Embodiment 3

[0048] The synthesis of iridium complex Ir9, the reaction equation is as follows:

[0049] (1) Synthesis of chlorine-bridged dimers

[0050]

[0051] (2) Target synthesis

[0052]

[0053] The transition metals involved in the complexes prepared in Examples 1-3 are represented by Ir, and Pd or Pt can also be used to prepare transition metal complexes, and the reaction principle and process are the same as those of Ir.

[0054] Such as figure 1 As shown, the structure of an organic electroluminescent device (OLED) includes a glass substrate 1, an anode layer 2, a hole injection layer 3, a hole transport layer 4, a light emitting layer 5, an electron transport layer 6, and an electron injection layer sequentially stacked and combined. layer 7 and cathode layer 8. The iridium phosphorescent material prepared by the present invention is applied in the light-emitting layer of the OLED, and Table 1 shows the composition of each layer of the OLED in application examples 1-3....

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
emission peakaaaaaaaaaa
current efficiencyaaaaaaaaaa
emission peakaaaaaaaaaa
Login to View More

Abstract

The invention belongs to the technical field of organic photoelectric materials, and particularly relates to a transition metal complex as a phosphorescent material, and a preparation method and an application of the transition metal complex. Due to collocation of Z1 and Z2, emitting light wavelength of the material can be adjusted in a wider wavelength range; at the same time, the emitting lightwavelength can be further adjusted precisely by changing heteroatoms on main ligands, so that an electroluminescent material with a predictable emitting color is obtained; the main ligands have the same skeleton structure; the emitting light wavelength can be adjusted in the wide range from green light to deep red light only by changing positions of functional groups and positions and categories of the heteroatoms on the main ligands; the prepared complex is high in luminous efficiency; the preparation methods of the luminous materials in different colors are basically the same; and the operation is simple.

Description

technical field [0001] The invention belongs to the technical field of organic photoelectric materials, and in particular relates to a class of transition metal complexes used as phosphorescent materials, a preparation method and applications thereof. Background technique [0002] The phenomenon of organic electroluminescence was first reported in 1963, but it was ignored due to its high voltage and low luminous efficiency. Until 1987, it was reported that OLED (Organic Light-Emitting Diode, English name Organic Light-Emitting Diode, OLED for short) device with multilayer structure appeared. Compared with traditional light-emitting diodes (LEDs) and liquid crystal displays (LCDs), OLED has the characteristics of self-illumination, clear and bright, light and thin, fast response, wide viewing angle, low power consumption, wide applicable temperature range, and simple manufacturing process. It meets the characteristics of "light, thin, small, colorful, economical, beautiful, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C07F15/00C09K11/06H01L51/50H01L51/54
CPCC09K11/06C07F15/0033C07F15/006C07F15/0086C09K2211/185H10K85/341H10K85/346H10K85/342H10K50/00
Inventor 陈跃丰佩川张国选胡灵峰杨阳王培祥张翠
Owner YANTAI XIANHUA OPTOELECTRONICS INST CORP LTD