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Ultraviolet aging without loss of viscosity hot-melt pressure-sensitive adhesive and preparation method thereof

A hot-melt, pressure-sensitive adhesive technology, applied in the direction of adhesive types, adhesives, hydrocarbon copolymer adhesives, etc., can solve the problem of large coating volume, surface hardening and loss of adhesion, and the inability to meet UV aging resistance at the same time Performance and other issues

Active Publication Date: 2020-06-19
HUIZHOU NENGHUI CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing self-adhesive film waterproof coiled material hot-melt pressure-sensitive adhesive mainly uses thermoplastic styrene-butadiene rubber SIS (styrene-isoprene-styrene block copolymer) as the base material, and then supplemented with various additives to meet various requirements. However, the surface becomes hard and loses adhesion after UV aging without coverage; or butyl rubber is used as the substrate, but the coating amount is large and cannot meet the latest national standard GB / T 23457-2017 "Pre-paved waterproof roll" UV aging resistance and other performance requirements in "Material", the bonding performance will decrease after UV aging, and it will not be able to achieve a good waterproof effect

Method used

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  • Ultraviolet aging without loss of viscosity hot-melt pressure-sensitive adhesive and preparation method thereof
  • Ultraviolet aging without loss of viscosity hot-melt pressure-sensitive adhesive and preparation method thereof
  • Ultraviolet aging without loss of viscosity hot-melt pressure-sensitive adhesive and preparation method thereof

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Effect test

Embodiment 1

[0035] This embodiment provides a UV-aging non-sticky hot-melt pressure-sensitive adhesive and a preparation method thereof.

[0036] In parts by weight, the raw materials for the preparation of the ultraviolet aging non-sticky hot-melt pressure-sensitive adhesive include:

[0037]

[0038]

[0039] In this embodiment, the rubber plasticizer is naphthenic rubber softening oil, and the antioxidant is tetrakis [β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester, and the anti-ultraviolet auxiliary The agent is 2-(2′-hydroxyl-5′-methylphenyl)benzotriazole.

[0040] The preparation method of the ultraviolet aging without loss of viscosity hot-melt pressure-sensitive adhesive is as follows:

[0041] Add butyl rubber, SEBS (hydrogenated styrene-butadiene block copolymer), rubber plasticizer and antioxidant into the kneader according to the required ratio; then, slowly heat to 150°C and stir until all materials After melting, the reaction is stable for 5 m...

Embodiment 2

[0043] This embodiment provides a UV-aging non-sticky hot-melt pressure-sensitive adhesive and a preparation method thereof.

[0044] In parts by weight, the raw materials for the preparation of the ultraviolet aging non-sticky hot-melt pressure-sensitive adhesive include:

[0045]

[0046]

[0047] In this embodiment, the rubber plasticizer is polyisobutylene rubber, the antioxidant is tris[2.4-di-tert-butylphenyl] phosphite, and the anti-ultraviolet additive is bis(2,2,6,6-tetramethyl -4-piperidinyl) sebacate.

[0048] The preparation method of the ultraviolet aging without loss of viscosity hot-melt pressure-sensitive adhesive is as follows:

[0049] Add butyl rubber, SEBS (hydrogenated styrene-butadiene block copolymer), rubber plasticizer and antioxidant into the kneader according to the required ratio; then, slowly heat to 155°C and stir until all materials After melting, the reaction is stable for 8 minutes; then, under stirring, add the remaining other material...

Embodiment 3

[0051] This embodiment provides a UV-aging non-sticky hot-melt pressure-sensitive adhesive and a preparation method thereof.

[0052] In parts by weight, the raw materials for the preparation of the ultraviolet aging non-sticky hot-melt pressure-sensitive adhesive include:

[0053]

[0054]

[0055] In this embodiment, the rubber plasticizer is polyisobutylene rubber, the antioxidant is tris[2.4-di-tert-butylphenyl] phosphite, and the anti-ultraviolet additive is bis(2,2,6,6-tetramethyl -4-piperidinyl) sebacate.

[0056] The preparation method of the ultraviolet aging without loss of viscosity hot-melt pressure-sensitive adhesive is as follows:

[0057]Add butyl rubber, SEBS (hydrogenated styrene-butadiene block copolymer), rubber plasticizer and antioxidant into the kneader according to the required ratio; then, slowly heat to 160°C and stir until all materials After melting, the reaction is stable for 10 minutes; then, under stirring, add the remaining other material...

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Abstract

The invention provides a hot melt pressure sensitive adhesive not losing viscosity in the case of ultraviolet aging and a preparation method thereof. The hot melt pressure sensitive adhesive is prepared from the following raw materials in parts by weight: 1-5 parts of butyl rubber, 5 to 15 parts of hydrogenated styrene-butadiene block copolymer, 25 to 35 parts of hydrogenated synthetic resin, 25 to 35 parts of a rubber plasticizer, 0.3 to 1 part of an antioxidant, 15 to 25 parts of poly-alpha-methylstyrene monomer resin, 2 to 10 parts of titanium dioxide, 1 to 5 parts of a vulcanization accelerator, and 0.5 to 1.5 parts of an anti-UV additive. The hot melt pressure sensitive adhesive of specific raw material formula is prepared by simultaneously adding titanium dioxide, the vulcanization accelerator and the anti-UV additive to the butyl rubber. When in use under the condition of no covering, the hot melt pressure sensitive adhesive does not loss the bonding function even if in the caseof ultraviolet aging and is a product not losing viscosity in the case of ultraviolet aging.

Description

technical field [0001] The invention relates to the technical field of hot-melt pressure-sensitive adhesives, in particular to a hot-melt pressure-sensitive adhesive that does not lose viscosity after ultraviolet aging and a preparation method thereof. Background technique [0002] Since the publication of GB 50108-2008 "Technical Specifications for Waterproofing of Underground Engineering" and GB / T 23457-2009 "Pre-laid / Wet-laid Waterproof Membrane", the application fields of polymer self-adhesive waterproof membranes have become wider and wider. The existing self-adhesive film waterproof coiled material hot-melt pressure-sensitive adhesive mainly uses thermoplastic styrene-butadiene rubber SIS (styrene-isoprene-styrene block copolymer) as the base material, and then supplemented with various additives to meet various requirements. However, the surface becomes hard and loses adhesion after UV aging without coverage; or butyl rubber is used as the substrate, but the coating a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J201/00C09J123/22C09J153/02C09J125/16C09J11/04C09J11/06C09J11/08
CPCC08K2003/2241C08K2003/2296C08K2201/011C08L2201/08C08L2205/035C09J11/04C09J11/06C09J11/08C09J123/22C09J201/00C08L23/22C08L53/025C08L25/16C08K13/02C08K3/22C08K5/3475C08K5/3435C08L101/00
Inventor 汤仪标江强吴兆辉杜敏耀
Owner HUIZHOU NENGHUI CHEM CO LTD