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An agricultural vegetable greenhouse film that can specifically filter light waves below 390nm

A vegetable greenhouse and light wave technology, applied in the field of polymer film materials, can solve the problems of no positive effect on agricultural pest control, not suitable for the use of greenhouse films, poor filtering effect of ultraviolet filter glass powder, etc., to achieve excellent tensile properties, accelerate Degradation, anti-erosion effect

Active Publication Date: 2021-03-23
山东隆昌新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the preparation method of a long-acting light-converting agricultural plastic film of the present invention, the polyvinylidene chloride emulsion is automatically immersed in the Eu alkaline earth metal sulfide doped with rare earth ions, so that the metal sulfide is effectively wrapped, and the metal sulfide is prevented from directly contacting with the sulfide. Oxygen, water and carbon dioxide in the air react directly to increase the service life of the film. Although this invention improves the service life of the film, it has no positive effect on the control of agricultural pests
[0008] The patent with the notification number CN 108164830 A discloses a polypropylene material for filtering ultraviolet rays, including the following raw material components: polypropylene, modified ultraviolet filter glass powder, polymethyl methacrylate microbeads, SiO 2 / Al 2 o 3 / ZnO, the modified UV filter glass powder is prepared by the reaction of UV filter glass powder, Span 60, acrylic acid, methyl methacrylate, butyl methacrylate and 184 photoinitiator, and the UV filter glass powder is made of UV Filter glass, glass beads, high borate glass and rutile titanium dioxide reaction prepared, polymethyl methacrylate beads from sodium chloride aqueous solution, methyl methacrylate, Span 80, hydroxyethyl acrylate, poly Prepared by the reaction of oxyethylene lanolin ether, sorbitan monopalmitate and dibenzoyl peroxide, SiO 2 / Al 2 o 3 / ZnO is produced by the reaction of zinc oleate, aluminum tristearate, dimethyl silicone oil, ammonium carbonate, triethanolamine and Schiff base surfactants. Although this invention has excellent UV filter performance, the UV filter used Optical glass powder has poor filtering effect on 200-400nm ultraviolet light, and is not suitable for use in greenhouse films

Method used

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  • An agricultural vegetable greenhouse film that can specifically filter light waves below 390nm
  • An agricultural vegetable greenhouse film that can specifically filter light waves below 390nm
  • An agricultural vegetable greenhouse film that can specifically filter light waves below 390nm

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] An agricultural vegetable greenhouse film capable of specifically filtering light waves below 390nm, comprising the following components in parts by weight:

[0037] 85 parts of polyvinyl chloride resin, 42 parts of polyvinylidene fluoride resin, 15 parts of nano zinc oxide coated with cerium oxide, 0.4 parts of dicumyl peroxide, 12 parts of bismaleamic acid, 6 parts of starch, 4 parts of chitin , 2 parts of polyoxyethylene lauryl ether, 0.6 parts of tricresyl phosphate, 1.2 parts of leveling agent BYK-346, 3.5 parts of dispersant, 2 parts of BYK-011, 14 parts of toughening filler, phthalic acid di(2 -8 parts of ethylhexyl ester.

[0038] The preparation method of nano zinc oxide coated with cerium oxide is as follows:

[0039]Add nano-zinc oxide and KH550 into its ionized water, ultrasonically oscillate and stir for 30 minutes, add ethanol solution of cerium nitrate, raise the temperature to 45°C, add aqueous oxalic acid solution dropwise, keep stirring for 1.2 hours,...

Embodiment 2

[0047] An agricultural vegetable greenhouse film capable of specifically filtering light waves below 390nm, comprising the following components in parts by weight:

[0048] 90 parts of polyvinyl chloride resin, 50 parts of polyvinylidene fluoride resin, 18 parts of nano zinc oxide coated with cerium oxide, 0.2 parts of dicumyl peroxide, 10 parts of bismaleamic acid, 5 parts of starch, 4 parts of chitin , 3 parts of polyoxyethylene lauryl ether, 0.5 parts of tricresyl phosphate, 1.6 parts of leveling agent BYK-346, 4.5 parts of dispersant, 3 parts of BYK-017, 15 parts of toughening filler, dioctyl phthalate 9 servings.

[0049] The preparation method of nano zinc oxide coated with cerium oxide is as follows:

[0050] Add nano-zinc oxide and KH550 into its ionized water, ultrasonically oscillate and stir for 30 minutes, add ethanol solution of cerium nitrate, raise the temperature to 40°C, add aqueous oxalic acid solution dropwise, keep stirring for 2 hours, adjust the pH to 11...

Embodiment 3

[0058] An agricultural vegetable greenhouse film capable of specifically filtering light waves below 390nm, comprising the following components in parts by weight:

[0059] 85 parts of polyvinyl chloride resin, 43 parts of polyvinylidene fluoride resin, 12 parts of nano zinc oxide coated with cerium oxide, 0.3 parts of dicumyl peroxide, 12 parts of bismaleamic acid, 6 parts of starch, 1 part of chitin , 1 part of polyoxyethylene lauryl ether, 0.6 parts of tricresyl phosphate, 1.3 parts of leveling agent BYK-346, 4 parts of dispersant, 2 parts of BYK-025, 6 parts of toughening filler, di-n-octyl phthalate 15 parts of ester.

[0060] The preparation method of nano zinc oxide coated with cerium oxide is as follows:

[0061] Add nano-zinc oxide and KH550 into its ionized water, ultrasonically oscillate and stir for 30 minutes, then add ethanol solution of cerium nitrate, raise the temperature to 50°C, add aqueous oxalic acid solution dropwise, keep stirring for 2 hours, adjust th...

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Abstract

The invention provides an agricultural vegetable greenhouse film capable of specifically filtering light waves below 390 nm, and relates to the field of polymer film materials. The film comprises thefollowing components in parts by weight: 80-100 parts of polyvinyl chloride resin, 40-55 parts of polyvinylidene fluoride resin, 10-20 parts of cerium oxide coated nano zinc oxide, 0.1-0.5 parts of dicumyl peroxide, 5-15 parts of bismaleamic acid, 3-8 parts of starch, 1-5 parts of chitin, 1-5 parts of lauryl alcohol polyoxyethylene ether, 0.2-1 part of triphenyl phosphate, 1-2 parts of leveling agents BYK-346, 1-5 parts of dispersant agents, 1-5 parts of defoaming agents, 5-10 parts of toughening filler, and 10-16 parts of plasticizer. The vegetable greenhouse film has excellent tensile property and good light transmittance, and can specifically filter ultraviolet light with wavelengths below 390 nm.

Description

technical field [0001] The invention relates to the field of polymer film materials, in particular to an agricultural vegetable greenhouse film which can specifically filter light waves below 390nm. Background technique [0002] The vegetable greenhouse is a frame-covered structure with excellent thermal insulation performance. It appears that people can eat off-season vegetables. Generally, vegetable greenhouses use a bamboo structure or steel structure skeleton, covered with one or more layers of thermal insulation plastic film, thus forming a greenhouse space. The film can well prevent the loss of carbon dioxide produced by the growth of internal vegetables, so that the inside of the shed Has a good thermal insulation effect. [0003] In recent years, with the gradual promotion of greenhouses, more and more people are engaged in the production of vegetables in greenhouses. Greenhouses not only provide a comfortable growth environment for vegetables, but also provide fav...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A01G9/14C08L27/06C08L27/16C08L71/02C08L3/02C08L5/08C08L91/06C08K13/06C08K9/10C08K3/22C08K5/20C08K5/523C08K5/101C08K3/26C08K3/34C08J5/18
CPCA01G9/1438C08J5/18C08J2327/06C08J2403/02C08J2427/16C08J2471/02C08K3/34C08K5/101C08K5/20C08K5/523C08K9/10C08K13/06C08K2003/2296C08K2003/265C08K2201/011Y02A40/25
Inventor 章立兰
Owner 山东隆昌新材料科技股份有限公司
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