Stress distributing film, optical member, and electronic member
A stress dispersion, plastic film technology, applied in non-polymer adhesive additives, layered products, chemical instruments and methods, etc., can solve problems such as damage to optical components and electronic components, and achieve the effect of excellent stress dispersion.
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[0093] Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited to these Examples. In addition, the test and evaluation method in an Example etc. are as follows. In addition, when described as "part", unless otherwise specified, it means "weight part", and when described as "%", unless otherwise specified, it means "weight%".
[0094]
[0095] The weight average molecular weight (Mw) of a polymer is measured using the Tosoh Corporation GPC apparatus (HLC-8220GPC). In addition, weight average molecular weight (Mw) was calculated|required from the polystyrene conversion value.
[0096] The measurement conditions are as follows.
[0097] Sample concentration: 0.2% by weight (THF solution)
[0098] Sample injection volume: 10μl eluent
[0099] THF flow rate: 0.6ml / min
[0100] Measuring temperature: 40°C
[0101] Sample column: TSKguardcolumn SuperHZ-H (1 piece) + TSKgel SuperHZM-H (2 pieces)
[0102] Reference column: TSKgel ...
Embodiment 2、4、6、8、10、12、14、16、18、20、22、24
[0107] (Examples 2, 4, 6, 8, 10, 12, 14, 16, 18, 20, 22, 24, Comparative Examples 2, 4, 6, 8)
[0108] The obtained adhesive composition was applied to a base material "Lumirror S10" (thickness 38 μm, manufactured by Toray Co., Ltd.) made of polyester resin with a liquid supply roll so that the thickness after drying was 22 μm, and dried at a temperature of 130 ℃, drying time of 30 seconds, curing and drying. In this way, an adhesive layer is formed on the substrate. Next, the surface of the pressure-sensitive adhesive layer was bonded to the silicone-treated surface of a base material made of a polyester resin having a thickness of 25 μm that had been subjected to silicone treatment on the other surface to obtain a pressure-sensitive adhesive sheet (A).
[0109]
[0110] Using "SAICA SDN-20 type" manufactured by Daipla Wintes Co., the indentation energy was calculated in the following procedure at a measurement temperature: 25° C. and an indentation speed: 5 μm / sec.
[01...
Embodiment 1、2
[0143] In the solution of the (meth)acrylic polymer (1), with respect to 100 parts by weight of the solid content of the solution of the (meth)acrylic polymer (1), the overall solid content becomes 25% by weight, Diluted with ethyl acetate, stirred with a disperser, and obtained the adhesive composition (1) containing an acrylic resin. The results are shown in Table 1.
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