A kind of deep blue light thermally activated delayed fluorescent material and its application

一种热活化延迟、荧光材料的技术，应用在发光材料、有机化学、磷有机化合物等方向，能够解决TADF材料寥寥无几、重金属Ir配合物匮乏等问题，达到减小单三重能级差、减小高能级、高效率的效果

Active Publication Date: 2020-04-10
WUHAN CHINA STAR OPTOELECTRONICS SEMICON DISPLAY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, TADF materials that meet the above conditions are still relatively scarce compared with heavy metal Ir complexes, especially in the field of deep blue light where phosphorescent heavy metal materials need to be broken through, there are very few TADF materials.

Method used

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  • A kind of deep blue light thermally activated delayed fluorescent material and its application
  • A kind of deep blue light thermally activated delayed fluorescent material and its application
  • A kind of deep blue light thermally activated delayed fluorescent material and its application

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Embodiment Construction

[0053] A deep blue thermally activated delayed fluorescent material and technical solutions for its application in the present invention will be further described in detail with reference to the accompanying drawings and examples.

[0054] One embodiment of the present invention provides a deep blue photothermally activated delayed fluorescence material, the structural formula of which constitutes the compound is as follows:

[0055]

[0056] Further, compound 2 and compound 3 are derived from compound 1 through the matching of functional groups derived from different raw materials, the structural formulas of which are as follows:

[0057]

[0058] further, see Figure 1~6 As shown, it illustrates the distribution of the highest electron-occupied orbital (HOMO) and the lowest electron-unoccupied orbital (LUMO) of the three compounds involved in the present invention through theoretical calculation.

[0059] Further, the compound 1, compound 2 and compound 3, the lowest ...

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Abstract

The present invention provides a deep blue light thermally activated delayed fluorescence (Thermally Activated Delayed Fluorescence, TADF) material, its constituent compound molecules have an ultra-fast reverse intersystem crossing rate, and when it is used as a host doped in an electroluminescent device When it is in the light-emitting layer, the blue-light fluorescent and phosphorescent electroluminescent devices using it as the host material can achieve very high efficiency.

Description

technical field [0001] The invention relates to the field of materials that can be used in flat-panel display devices, in particular, a deep blue light thermally activated delayed fluorescent material and a preparation method thereof. Background technique [0002] It is known that organic light-emitting diodes (organic light-emitting diodes, OLEDs) do not require a backlight source for their active light emission, high luminous efficiency, large viewing angle, fast response speed, wide temperature range, and relatively simple production and processing technology. The advantages of low driving voltage, low energy consumption, lighter and thinner, flexible display and huge application prospects have attracted the attention of many researchers. In OLEDs, however, the dominant luminescent guest material is crucial. [0003] The luminescent guest materials used in early OLEDs are fluorescent materials. Since the ratio of singlet and triplet excitons in OLEDs is 1:3, the theoreti...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07F9/6568C09K11/06H01L51/50H01L51/54
CPCC09K11/06C07F9/65685H10K85/657H10K85/6572H10K50/11C07F9/65683C07F7/0816H10K85/40H10K2101/20C07F9/64C09K2211/1007C09K2211/1014C09K2211/1018
Inventor 罗佳佳
Owner WUHAN CHINA STAR OPTOELECTRONICS SEMICON DISPLAY TECH CO LTD
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