Unlock instant, AI-driven research and patent intelligence for your innovation.

Copper-hafnium-cobalt corrosion-resistant austenitic stainless steel and processing and heat treatment method thereof

A technology of austenitic stainless steel and heat treatment method, applied in the field of austenitic stainless steel, can solve the problems of increased contact resistance, inability to meet the requirements of bipolar plate materials, etc.

Inactive Publication Date: 2019-02-19
CENT SOUTH UNIV
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The passivation layer formed by 316L stainless steel without surface treatment in the fuel cell environment will lead to an increase in contact resistance, which cannot meet the requirements of bipolar plate materials

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Copper-hafnium-cobalt corrosion-resistant austenitic stainless steel and processing and heat treatment method thereof
  • Copper-hafnium-cobalt corrosion-resistant austenitic stainless steel and processing and heat treatment method thereof
  • Copper-hafnium-cobalt corrosion-resistant austenitic stainless steel and processing and heat treatment method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Select electrical pure iron, metal chromium sheet, metal nickel plate, 304 stainless steel waste, pure copper block, pure cobalt sheet, and metal hafnium as raw materials. The stainless steel composition is as follows: C=0.03, Ni=9.5, Cr=17.0, Hf= 0.42, Cu=0.2, Co=0.1, Mn=1.2, Si=0.8, P≤0.035, S≤0.030, Fe=balance.

[0052] After weighing the corresponding raw materials according to the composition requirements, vacuum induction melting is carried out, and the temperature of the molten pool is maintained at 1680°C during melting; the molten steel is calmed for 5 minutes before pouring, and the molten steel is vacuum poured at 1500°C.

[0053] The plate is hot-rolled by a flat-roll mill. The hot-rolling plan is to heat the cast slab to 1270°C, heat it for 5 hours and then roll it out of the furnace. The hot-rolling start temperature is 1160°C and the final rolling temperature is 1000°C. The total amount of hot rolling of the plate is 65%.

[0054] The plate is deformed b...

Embodiment 2

[0059] 304 stainless steel waste, pure copper block, pure cobalt sheet, and hafnium iron are selected as raw materials. The stainless steel composition is as follows: C=0.04, Ni=10.0, Cr=17.8, Hf=0.58, Cu=0.3, Co=0.5, Mn= 1.2, Si=0.7, P≤0.035, S≤0.030, Fe=balance.

[0060] After the corresponding raw materials are weighed according to the composition requirements, the argon shielded arc melting is carried out, and the temperature of the molten pool is maintained at 1720°C during melting; the molten steel is calmed for 10 minutes before pouring, and the molten steel is poured under argon shielding at 1600°C.

[0061] The plate is hot-rolled by a flat-roll mill. The hot-rolling plan is to heat the cast billet to 1290°C, hold it for 5 hours, and then roll it out of the furnace. The hot-rolling start temperature is 1190°C, and the final rolling temperature is 950°C. The total amount of plate hot rolling is 60%.

[0062] The plate is deformed by cold rolling, and the total reducti...

Embodiment 3

[0066]Select electrical pure iron, metal chromium sheet, metal nickel plate, pure copper block, pure cobalt sheet, hafnium iron, and graphite block as raw materials. The stainless steel composition is as follows: C=0.05, Ni=8.6, Cr=18.0, Hf=0.70 , Cu=0.4, Co=0.2, Mn=0.8, Si=0.5, P≤0.035, S≤0.030, Fe=balance.

[0067] After weighing the corresponding raw materials according to the composition requirements, they are induction smelted under the protection of argon gas.

[0068] The plate is hot-rolled with a flat roll mill. The hot-rolling plan is to heat the cast billet to 1280°C, keep it warm for 4 hours, and then roll it out of the furnace. The hot-rolling start temperature is 1180°C, and the final rolling temperature is 980°C. The total amount of hot rolling of the plate is 70%.

[0069] The plate is deformed by cold rolling, and the total reduction of cold rolling is 82%.

[0070] The plate is annealed at 1100°C, the holding time is 60 minutes, and nitrogen protection is u...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
hardnessaaaaaaaaaa
yield strengthaaaaaaaaaa
tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention discloses copper hafnium cobalt corrosion-resistant austenitic stainless steel and a processing and heat treatment method thereof. The austenitic stainless steel is prepared from, by mass, smaller than or equal to 0.07% of C, 8.0%-10.0% of Ni, 17.0%-19.0% of Cr, smaller than or equal to 1.04% of Hf, 0.2%-0.8% of Cu, 0.1%-0.5% of Co, smaller than or equal to 2.0% of Mn, smaller than or equal to 1.0% of Si, smaller than or equal to 0.035% of P, smaller than or equal to 0.030% of S and the balance Fe, wherein Hf is larger than or equal to 14.86*(C-0.01) and smaller than or equal to14.86*C. The processing and heat treatment method comprises the steps of hot-deformation cogging, cold deformation, HfC crushing and dispersing, high temperature solution treatment and grain coarsening. Under the oxygen feeding condition, the corrosion current density in a 0.5 mol / L H2SO4 electrolyte containing 5*10<-6> F<-1> at 80 DEG C ranges from 1.49 microamperes / cm<2> to 2.01 microamperes / cm<2>, and the corrosion current density is equal to that of a stainless steel bipolar plate material with a surface coating. The austenitic stainless steel has the advantages of being low in hardness and high in extension, and forming of a bipolar plate runner is facilitated.

Description

technical field [0001] The invention belongs to the field of austenitic stainless steel, relates to composition design, processing and heat treatment method of high corrosion resistance austenitic stainless steel, and can be widely used in energy, electric power, chemical industry and daily life. technical background [0002] A fuel cell is a device that directly converts the chemical energy between hydrogen fuel and oxidant into electrical energy through an electrode reaction. Due to its high efficiency, low pollution, short construction time, good reliability and maintainability, it is the fourth generation power generation technology after hydropower, thermal power and nuclear power. Among many fuel cells, the proton exchange membrane fuel cell is a new type of fuel cell that develops late, but it develops most rapidly. [0003] In a fuel cell, the conductive separators that support, collect, divide oxidants and reductants and guide the flow of oxidants and reductants on...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C21D1/18C21D1/26C21D1/74C21D1/773C21D8/02C21D8/06C21D8/10C22C33/06C22C38/02C22C38/04C22C38/42C22C38/52C22C38/58
CPCC22C38/42C21D1/18C21D1/26C21D1/74C21D1/773C21D8/0226C21D8/0236C21D8/065C21D8/105C21D2211/001C22C33/06C22C38/002C22C38/02C22C38/04C22C38/52C22C38/58
Inventor 罗丰华罗弘瑞李益民牟楠杨霆杨昊
Owner CENT SOUTH UNIV