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Mushroom head type electrostatic spinning sprayer with controllable free liquid level suitable for high-speed motion and using method of mushroom head type electrostatic spinning sprayer

An electrospinning, high-speed motion technology, applied in textile and papermaking, filament/thread forming, fiber processing, etc., can solve the problem of unstable free liquid surface, volatile solvent of spinning solution, Problems such as excessive free liquid level, to achieve the effect of simple and easy technology and reducing solvent volatilization

Active Publication Date: 2019-06-04
DONGHUA UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem to be solved by the present invention is to provide a controllable free liquid surface mushroom head type electrospinning nozzle suitable for high-speed movement and its use method, so as to solve the instability of the free liquid surface in the batch electrospinning process of the current high-speed movement of the nozzle , the free liquid surface of the spinning solution to be spun is too large, and the solvent of the spinning solution to be spun is volatile. At the same time, the precise design and control of the electric field and the curvature of the spinning solution during the electrospinning process is realized, and the narrow distribution of submicron fibers and nanofibers is realized. batch preparation of

Method used

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  • Mushroom head type electrostatic spinning sprayer with controllable free liquid level suitable for high-speed motion and using method of mushroom head type electrostatic spinning sprayer
  • Mushroom head type electrostatic spinning sprayer with controllable free liquid level suitable for high-speed motion and using method of mushroom head type electrostatic spinning sprayer
  • Mushroom head type electrostatic spinning sprayer with controllable free liquid level suitable for high-speed motion and using method of mushroom head type electrostatic spinning sprayer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] Next, nanofibers are prepared by using a polymer solution prepared from polyacrylonitrile (PAN) and N-N dimethylformamide (DMF). The mass fraction of the prepared PAN polymer solution is 10%. The metal drum 10 is grounded, and the distance between the metal cylindrical drum 10 and the controllable free-surface mushroom head type electrospinning nozzle suitable for high-speed motion is 20 cm; The relative height forms the ring-shaped slit channel 14 of certain width to be 0.5mm; Turn on the drive motor 9 of the metal cylindrical cylinder 10 of the receiving device, and set the rotating speed of the cylinder 10 to be 60r / min; Open the switch of the liquid supply control device 16, through the peristaltic pump to Inject a certain amount of high polymer spinning solution 1 into the annular slit channel 14 until the surface solution is completely full; set the reciprocating speed of the mushroom-head type electrospinning nozzle suitable for high-speed movement to a controlla...

Embodiment 2

[0051] This embodiment is similar to Embodiment 1, except that: the mass fraction of the prepared PAN polymer solution is 12%; the metal cylindrical drum 10 and the controllable free liquid surface mushroom head type electrospinning nozzle suitable for high-speed motion The distance of the spinning solution is adjusted to 18cm; the ring-shaped slit channel 14 of a certain width formed between the spinning solution curvature control module 13 and the polytetrafluoroethylene seat 2 is 0.6mm; the rotating speed of the drum 10 is set to 80r / min; suitable for high-speed motion The reciprocating speed of the mushroom-head electrospinning nozzle with controllable free liquid surface is set to 1200mm / s; the voltage of switch 4 of the high voltage generator is adjusted to 80KV.

Embodiment 3

[0053] This embodiment is similar to Embodiment 1, except that: the mass fraction of the prepared PAN polymer solution is 14%; the metal cylindrical drum 10 and the controllable free surface mushroom head type electrospinning nozzle suitable for high-speed motion The distance is adjusted to 25cm; the ring-shaped slit channel 14 of a certain width formed between the spinning solution curvature control module 13 and the polytetrafluoroethylene seat 2 is 0.7mm; the rotating speed of the drum 10 is set to 90r / min; suitable for high-speed motion The reciprocating speed of the mushroom head electrospinning nozzle with controllable free liquid surface was set to 1500mm / s.

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Abstract

The invention relates to a mushroom head type electrostatic spinning sprayer with controllable free liquid level suitable for high-speed motion and a using method of the mushroom head type electrostatic spinning sprayer. The mushroom head type electrostatic spinning sprayer with the controllable free liquid level suitable for high-speed motion comprises a bowl-shaped metal sprayer module, a spinning solution curvature regulating and control module, a spinning solution fluid form control module and an installation regulating device. According to the invention, the spinning solution fluid form control module and the spinning solution curvature regulating and control module which are made of polytetrafluoroethylene are adopted, so that the spinning solution curvature on the surface of the sprayer can be restrained from obviously fluctuating in a movement process of the sprayer, and meanwhile, the electric field of the spinning sprayer is not interfered. On the basis of not interfering with regulation and control of the electric field, the free liquid level of a spinning solution can be stabilized, the curvature of the spinning solution can be regulated and controlled, volatilization of a solvent can be reduced, the requirement of high-speed movement of the sprayer can be met, and batch preparation of narrow-distribution submicron fibers and nano fibers in high-speed movement of the sprayer can be realized.

Description

technical field [0001] The invention belongs to the technical field of nanofibers and textile machinery, and in particular relates to a controllable free-surface mushroom-head electrostatic spinning nozzle suitable for high-speed motion and a use method thereof. Background technique [0002] When polymer fiber diameters are reduced from the micrometer scale to the submicrometer or nanometer scale, a surprising set of properties emerges. Such as a very large volume specific surface area, the volume specific surface area of ​​nanofibers is basically 1000 times that of microfibers; it can be flexibly functionalized on the surface; it shows superior effects and mechanical properties compared with other known material forms, such as surface And interface effect, small size effect, quantum size effect and quantum tunneling effect and stiffness, tensile strength, etc. These outstanding properties make nanofibers the material of choice for many important applications, and have grea...

Claims

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Application Information

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IPC IPC(8): D01D5/00
Inventor 覃小红熊健王荣武
Owner DONGHUA UNIV