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Preparation method of aerogel-based photocatalytic material

A technology of photocatalytic materials and airgel, which is applied in the direction of catalyst activation/preparation, chemical instruments and methods, separation methods, etc., can solve the problems of low photocatalytic efficiency, small visible light response, and low solar energy utilization efficiency, and achieve photocatalytic The effect of improving efficiency

Inactive Publication Date: 2019-07-12
FOSHAN GAOMING DISTRICT ZHUAHE NEW MATERIAL TECH CO LTD
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Problems solved by technology

[0007] The technical problem mainly solved by the present invention is that the current existing photocatalysts have a wide band gap and can only absorb and utilize ultraviolet light with a wavelength less than 387nm in sunlight, and only about 3% to 5% of sunlight can be utilized. The response of visible light is small, and the photocatalytic efficiency is low, which leads to the defects of low solar energy utilization efficiency, and a preparation method of airgel-based photocatalytic materials is provided.

Method used

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  • Preparation method of aerogel-based photocatalytic material

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Embodiment Construction

[0024]Add 50-60mL absolute ethanol into 6-8mL tetraethyl orthosilicate along the wall of the beaker, stir for 10-15min, add 3-4mL water into the beaker, stir for 10-12min, then add 15 % hydrochloric acid to adjust the pH of the solution in the beaker to 1.8-2.2, and let it stand for 3-4 hours to obtain a silica sol for later use; Add 18-20mL tetrabutyl titanate into the three-necked flask at a dropping rate of 2-3mL / min from the dropping funnel, start the stirrer at the same time, start stirring at a speed of 200-300r / min, and add tetrabutyl titanate dropwise After completion, add 4-6mL triethanolamine to the three-necked flask and stir for 1-2 hours to obtain a uniform solution; mix 1-2mL water, 8-10mL absolute ethanol, and 2-4mL hydrochloric acid with a mass fraction of 20%, pour into In the above-mentioned three-necked flask, continue to stir and mix for 2-3 hours, and then let it stand for 5-6 hours to obtain a light yellow titanium dioxide sol, and then add 1-3 mL of poly...

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Abstract

The invention discloses a preparation method of an aerogel-based photocatalytic material, and belongs to the technical field of photocatalytic material preparation. Iron ions doped in titanium dioxidesol is subjected to a reaction with photo-generated electrons and holes in titanium dioxide, and a prepared titanium dioxide film is of a nano anatase structure; because band gap energy of the anatase phase is higher than that of the rutile phase, the surface of titanium dioxide is coated with a layer of silica gel, and the surface area of silicon dioxide is larger, so that hydroxyl groups serveas trapping sites of holes to stop combination of electron-hole pairs; besides, titanium dioxide and silicon dioxide are partially compounded, silicon dioxide or Ti-O-Si bonds hinder mutual contact among particles, and accordingly, a powdery nano material prepared from the prepared photocatalytic material can be cured on a massive matrix to improve photocatalytic reaction efficiency; the used matrix raw materials are biomass raw materials and are healthy, nontoxic and easy to degrade and recycle, and the application prospect is broad.

Description

technical field [0001] The invention discloses a preparation method of an airgel-based photocatalytic material, and belongs to the technical field of photocatalytic material preparation. Background technique [0002] Photocatalytic materials refer to a type of semiconductor catalyst material required for photochemical reactions that occur through the material under the action of light, and are chemical reactions that occur under the action of light. Photochemical reactions require molecules to absorb electromagnetic radiation of a specific wavelength, and are excited to generate molecular excited states, which then undergo chemical reactions to generate new substances, or become intermediate chemical products that trigger thermal reactions. The activation energy of photochemical reactions comes from the energy of photons. In the utilization of solar energy, photoelectric conversion and photochemical conversion have always been very active research fields. There are many pho...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/745B01J31/38B01J37/02B01J37/34B01J35/10B01D53/86B01D53/72B01D53/58
CPCB01J23/745B01J37/0215B01J37/0228B01J37/0232B01J37/343B01J31/38B01D53/8668B01D53/8634B01J35/60B01J35/39
Inventor 胡次兵何伟仁陈可
Owner FOSHAN GAOMING DISTRICT ZHUAHE NEW MATERIAL TECH CO LTD
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