Photochromic interlayer film, light-transmitting laminate, and camera system for automobiles
A technology of photochromic and photochromic dyes, applied in the field of interlayer films for light-transmitting laminates, can solve the problems of complex manufacturing process, weakened discoloration effect, weak weather resistance, etc., and achieve the effect of maintaining impact resistance
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preparation example Construction
[0166] The preparation method of the intermediate film may be a method of putting each of the above-mentioned components into an extruder, performing melt extrusion, and co-extruding through a feed block, but the present invention is not limited thereto.
[0167] A light-transmitting laminate according to another embodiment of the present invention has a first light-transmitting layer, a second light-transmitting layer, and the above-described intermediate layer between the first light-transmitting layer and the second light-transmitting layer. membrane.
[0168] The first light-transmitting layer and the second light-transmitting layer may be light-transmitting glass or light-transmitting plastic, respectively.
[0169]The translucent laminate may have a visible light transmittance of 70% or more before color change due to the photochromic layer, and may have a visible light transmittance of 10% to 60% after color change. The above features make the visibility through the tr...
experiment example 1
[0198] 1) Manufacture of full-surface photochromic interlayer film
[0199] The composition that will be used to prepare single-layer photochromic intermediate film is put into twin-screw (Twin Screw) extruder (manufacturer: SM Platec) with the composition shown in following Table 1 and is extruded, to obtain Figure 1A The interlayer film samples of the structure (each with a thickness of 800 μm).
[0200] Table I
[0201]
[0202]
[0203] 2) Evaluation of the physical properties of the entire photochromic interlayer film
[0204] After manufacturing a laminated glass in which the coextruded polyvinyl acetal films laminated with the full-surface photochromic interlayer films manufactured in the samples 1 to 10 described above, the following physical properties were evaluated.
[0205] Color measurement for color development / decolorization
[0206] In a laminator at a temperature of 130°C, 2.1T (mm, the same below) thickness glass of 70 mm × 70 mm and each sample manu...
experiment example 2
[0227] 1) Preparation of intermediate film of photochromic sunshade belt
[0228] The composition of layer A and the composition of layer C below were melt-extruded using two twin-screw extruders (manufacturer: SM Platech) and a feed block for co-extrusion to form a film.
[0229] Layer A: a composition comprising 70wt% of the first polyvinyl acetal resin, 29wt% of the plasticizer and 1wt% of the first ultraviolet absorber
[0230] Layer C: a composition comprising 72.79wt% of a first polyvinyl acetal resin, 26.96wt% of a plasticizer, 0.15wt% of a first ultraviolet absorber and 0.10wt% of a photochromic dye
[0231] The extruded film is a co-extrusion structure laminated by feed blocks into a film, and the layer structure is laminated in the form of A / C / A, and the C layer is only present in a part of the PVB film with a width of 200mm and a width of 1580mm ( refer to Figure 4A part). This type of sheet was formed through a die of an extruder, cooled in a casting roll (Cast...
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Abstract
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