A kind of solid fluorescent carbon dot and its preparation method and application
A fluorescent carbon dot and solid technology, applied in the field of carbon dots, can solve the problems of less solid fluorescent carbon dots, complex preparation and purification methods, etc.
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[0033] The invention provides a method for preparing solid fluorescent carbon dots, comprising the following steps:
[0034] Mix rosin-like resin acid, water and ethylenediamine for hydrothermal reaction to obtain solid fluorescent carbon dots.
[0035] In the present invention, unless otherwise specified, the required preparation materials are commercially available products well known to those skilled in the art.
[0036] In the present invention, the abietic resin acid is preferably a resin acid having a tricyclic phenanthrene skeleton structure, more preferably one or more of abietic acid type resin acids, pimaric acid type resin acids and isopimaric acid type resin acids. kind.
[0037] In the present invention, the structural formula of described abietic acid type resin acid is preferably:
[0038]
[0039]
[0040] In the present invention, the structural formula of described pimaric acid type resin acid is as follows:
[0041]
[0042] In the present invent...
Embodiment 1
[0063] Mix and disperse 0.4g rosin (abietic acid) with 70mL deionized water evenly, pour it into a 100mL hydrothermal reaction kettle, and add 1mL ethylenediamine, after mixing evenly, carry out hydrothermal reaction at 200°C for 5h, and the obtained material After naturally cooling to room temperature, centrifuging, the obtained solution was freeze-dried to obtain a crude product; after adding the crude product to anhydrous ethanol for dissolution, the insoluble matter was separated by filtration, and the obtained insoluble matter was dried in an oven to obtain water-soluble carbon dots (product I); The resulting filtrate was concentrated and filtered, and dried in vacuo to obtain solid fluorescent carbon dots (product II).
[0064] It was determined that the solid fluorescent carbon dots (product II) had yellow fluorescence under the irradiation of a 365nm ultraviolet lamp, and the aqueous solution of the water-soluble carbon dots (product I) exhibited blue fluorescence emiss...
Embodiment 2
[0075] Mix 0.4g of dehydroabietic acid (dehydroabietic acid) with 70mL of deionized water and disperse evenly, pour it into a 100mL hydrothermal reaction kettle, add 1mL of ethylenediamine, mix well, and conduct a hydrothermal reaction at 200°C for 5h After the obtained material is naturally cooled to room temperature, it is centrifuged, and the obtained solution is freeze-dried to obtain a crude product. After the crude product is dissolved in absolute ethanol, the insoluble matter is filtered and separated, and the gained insoluble matter is vacuum-dried to obtain a water-soluble carbon point ( Product I); the resulting filtrate was concentrated and filtered, and dried in vacuo to obtain solid fluorescent carbon dots (product II).
[0076] It has been determined that the solid fluorescent carbon dots (product II) have yellow-green fluorescence under the irradiation of a 365nm ultraviolet lamp, and the aqueous solution of the water-soluble carbon dots (product I) emits blue fl...
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