A kind of polyurethane material composition, polyurethane shoe material and preparation method thereof
A polyurethane material and composition technology, which is applied to shoe soles, footwear, clothing, etc., can solve the problems of unfavorable clean room environment, loss of antistatic effect, secondary dust pollution, etc., and achieves good physical and mechanical properties, good and easy to remove. The effect of reducing the pollution performance and reducing the dust generation
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[0034] Polyols are used as raw materials for the preparation of polyurethane materials. The selection of different polyols has a great influence on the properties of the prepared polyurethane materials. Specifically, polyols include but are not limited to polyester polyols, polyether polyols, and polycarbonate polyols. At least one; further, the polyol is a polyester polyol and / or polyether polyol with a molecular weight of 1500-2500; further, the polyester polyol is a bifunctional carbonate diol, adipic acid Polyester diol; adipate polyester diol is polyethylene adipate, polyethylene propylene adipate, polybutylene adipate or polydiethylene adipate Diol esters; polyester polyols may also contain polyester diols, polyamide polyester diols, and the like obtained by using carboxylic acids, diols, diamines, and the like other than the above in combination. The polyether polyol is a difunctional polyether diol, and the polycarbonate polyol, for example, polyol obtained by esterify...
Embodiment 1~5
[0089] The composition of the raw materials for preparing polyurethane shoe soles described in Examples 1 to 5 is shown in Table 1.
[0090] The preparation method of the polyurethane shoe sole described in Examples 1 to 5 is as follows: firstly dry the polyol in raw material A and the isocyanate in raw material B at 70°C respectively for later use, then dry the antistatic agent at 95°C, and add it to the polyol Stir evenly, then add quaternary ammonium salt modified fluorine finishing agent, catalyst, chain extender, foaming agent, foam stabilizer in turn, and mix evenly to form material A; finally mix the mixed material A with the baked material B Mix evenly through a pouring machine, pour into a shoe sole mold to form, after 3 minutes of curing, demould to make easy decontamination antistatic polyurethane material sole.
[0091] Table 1
[0092]
[0093]
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