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A kind of heat-shrinkable film and its preparation method and application

A heat-shrinkable film and outer layer technology, applied in the field of polymer materials for packaging, can solve the problems of inability to scan and identify product labels, poor toughness of POF shrinkable film, high shrinkage temperature, etc., achieve fast shrinkage speed, reduce package breakage rate, The effect of low shrinkage temperature

Active Publication Date: 2021-12-21
江门市华龙膜材股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still many problems in the use of these two types of shrink films. For example, POF shrink film has poor toughness and is easy to break the package; ordinary PE shrink film has high shrinkage temperature, slow shrinkage speed, and low efficiency. If the outer layer of the package is PE The film is easy to melt and stick when passing through the drying tunnel, and its transparency is poor. It is impossible to scan and identify the packaged product label. It needs to be labeled on the outside of the film, which increases the process and reduces the efficiency.

Method used

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  • A kind of heat-shrinkable film and its preparation method and application
  • A kind of heat-shrinkable film and its preparation method and application
  • A kind of heat-shrinkable film and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 33% for the outer layer, 34% for the middle layer, and 33% for the inner layer; The components are shown in Table 1 below:

[0059] Table 1

[0060]

[0061] The melt index of the high-pressure low-density polyethylene in the outer layer component is 0.25g / 10min, and the density is 0.924g / cm 3 , specifically preferred 2420D produced by China Sea Shell Petrochemical Co., Ltd.; the melt index of the ethylene-vinyl acetate copolymer is 0.25g / 10min, and the density is 0.930g / cm 3 , the vinyl acetate (VA) content is 12%, specifically the 3135 that the preferred U.S. DuPont company produces.

[0062] The melt index of the ethylene-vinyl acetate copolymer described in the middle layer component is 1.5g / 10min, and the density is 0.930g / cm 3 , the ...

Embodiment 2

[0075] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 33% for the outer layer, 45% for the middle layer, and 22% for the inner layer; The components are shown in Table 3 below:

[0076] table 3

[0077]

[0078] Except that the anti-adhesive masterbatch is natural silica, the melt index, density and manufacturer of the components of each layer of the heat shrinkable film in this example are the same as in Example 1. The preparation method of the heat-shrinkable film of this embodiment is the same as that of Example 1, and the process parameters of the extruder are as shown in Table 4:

[0079] Table 4

[0080] temperature zone 1 Zone 2 Zone 3 District 4 District 5 pressure (bar) outer layer 141 145 147 143 142 182-238 Middle 135 138 143 141 137 165-25...

Embodiment 3

[0082] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 25% for the outer layer, 50% for the middle layer, and 25% for the inner layer; The composition components are shown in Table 5 below:

[0083] table 5

[0084]

[0085]

[0086] Except that the anti-adhesive masterbatch is synthetic silica, the melt index, density and manufacturer of the components of each layer of the heat shrinkable film in this example are the same as those in Example 1. The preparation method of the heat-shrinkable film of this embodiment is the same as that of Example 1, and the process parameters of the extruder are as shown in Table 6:

[0087] Table 6

[0088] temperature zone 1 Zone 2 Zone 3 District 4 District 5 pressure (bar) outer layer 141 145 147 143 142 172-218 Middle ...

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Abstract

The invention provides a high-performance heat-shrinkable film, which has the advantages of low shrinkage temperature, fast shrinkage speed, low water vapor transmission rate, high transparency and the like. The heat-shrinkable film is prepared by a three-layer co-extrusion blown film method, including an outer layer, a middle layer, and an inner layer; the mass ratio of the outer layer: the middle layer: the inner layer is 1-3:1-3:1-3 ; The outer layer includes high-pressure low-density polyethylene, ethylene-vinyl acetate copolymer, anti-adhesive masterbatch, smooth masterbatch and antistatic masterbatch; the middle layer includes ethylene-vinyl acetate copolymer and propylene-based elastomer; The inner layer includes high-pressure low-density polyethylene, metallocene low-density polyethylene, propylene-based elastomer, anti-adhesive masterbatch, smooth masterbatch, and antistatic masterbatch. The heat shrinkable film of the present invention improves the tensile strength and elastic modulus, and effectively reduces the rate of bag breakage; the heat shrinkage rate is as high as 75% after being treated at 130°C for 20 seconds, the light transmittance is greater than 90%, and the haze and gloss are very high Big improvement.

Description

technical field [0001] The invention belongs to the technical field of polymer materials for packaging, and relates to a heat-shrinkable film, in particular to a heat-shrinkable film with good shrinkage efficiency and high transparency, a preparation method and an application thereof. Background technique [0002] With the increase of national environmental protection and energy saving efforts, some products packed in cartons are increasingly replaced by plastic packaging, and the increase in the consumption of plastic packaging products will definitely promote the technological progress and rapid development of the plastic packaging machinery industry. The economic macro and micro conditions are getting better, and social demand will show a steady growth, which is expected to stimulate the growth of plastic product consumption. In order to meet the requirements of the new era, plastic packaging materials are also required to meet the increasing packaging quality and efficie...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B27/32B32B27/08B32B27/30B32B27/18B32B33/00C08L23/06C08L23/08C08L101/02C08J5/18B29D7/01B65D65/02
CPCB32B27/32B32B27/08B32B27/306B32B27/18B32B27/327B32B33/00B29D7/01C08J5/18B65D65/02C08J2323/06C08J2423/08C08J2323/08C08J2400/10B32B2307/558B32B2307/54B32B2307/406B32B2250/246B32B2250/03
Inventor 文斌森魏洪媚
Owner 江门市华龙膜材股份有限公司