A kind of heat-shrinkable film and its preparation method and application
A heat-shrinkable film and outer layer technology, applied in the field of polymer materials for packaging, can solve the problems of inability to scan and identify product labels, poor toughness of POF shrinkable film, high shrinkage temperature, etc., achieve fast shrinkage speed, reduce package breakage rate, The effect of low shrinkage temperature
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Embodiment 1
[0058] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 33% for the outer layer, 34% for the middle layer, and 33% for the inner layer; The components are shown in Table 1 below:
[0059] Table 1
[0060]
[0061] The melt index of the high-pressure low-density polyethylene in the outer layer component is 0.25g / 10min, and the density is 0.924g / cm 3 , specifically preferred 2420D produced by China Sea Shell Petrochemical Co., Ltd.; the melt index of the ethylene-vinyl acetate copolymer is 0.25g / 10min, and the density is 0.930g / cm 3 , the vinyl acetate (VA) content is 12%, specifically the 3135 that the preferred U.S. DuPont company produces.
[0062] The melt index of the ethylene-vinyl acetate copolymer described in the middle layer component is 1.5g / 10min, and the density is 0.930g / cm 3 , the ...
Embodiment 2
[0075] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 33% for the outer layer, 45% for the middle layer, and 22% for the inner layer; The components are shown in Table 3 below:
[0076] table 3
[0077]
[0078] Except that the anti-adhesive masterbatch is natural silica, the melt index, density and manufacturer of the components of each layer of the heat shrinkable film in this example are the same as in Example 1. The preparation method of the heat-shrinkable film of this embodiment is the same as that of Example 1, and the process parameters of the extruder are as shown in Table 4:
[0079] Table 4
[0080] temperature zone 1 Zone 2 Zone 3 District 4 District 5 pressure (bar) outer layer 141 145 147 143 142 182-238 Middle 135 138 143 141 137 165-25...
Embodiment 3
[0082] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 25% for the outer layer, 50% for the middle layer, and 25% for the inner layer; The composition components are shown in Table 5 below:
[0083] table 5
[0084]
[0085]
[0086] Except that the anti-adhesive masterbatch is synthetic silica, the melt index, density and manufacturer of the components of each layer of the heat shrinkable film in this example are the same as those in Example 1. The preparation method of the heat-shrinkable film of this embodiment is the same as that of Example 1, and the process parameters of the extruder are as shown in Table 6:
[0087] Table 6
[0088] temperature zone 1 Zone 2 Zone 3 District 4 District 5 pressure (bar) outer layer 141 145 147 143 142 172-218 Middle ...
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