The invention belongs to the technical field of
high polymer material synthesis and preparation, and particularly relates to a preparation method of MBS (
methyl methacrylate-butadiene-
styrene) resin, which comprises the following steps: by taking
styrene,
acrylate monomers and toughened rubber particles as raw materials, under the combined action of an
antioxidant, an initiator and a
chain transfer agent, optimizing the technical process and adjusting the technical parameters, thereby obtaining the MBS resin. Three-stage key process steps of internal circulation prepolymerization,
polymerization in a second-stage reactor and
grafting in a
static mixer are set, and the feeding proportion of reaction materials, catalytic materials and the like, and the
reaction temperature, the stirring speed, the
retention time, the
solid content proportion and the like of each process step are accurately controlled. The prepared MBS resin is pure, low in
odor, uniform in rubber particle distribution, adjustable in rubber content, high in
grafting rate, good in transparency, low in
haze and good in
impact resistance. Compared with a traditional
emulsion polymerization method, the preparation method has the advantages that the technological process is shortened, the operation stability is good, the investment and production cost is reduced, the environmental
pollution is reduced, and the preparation method has good market prospects and application and popularization values.