Traditional Chinese medicine antibacterial PU foaming shoe material with good moisture absorption performance and preparation method thereof

A technology of hygroscopicity and traditional Chinese medicine, which is applied in footwear, shoe soles, applications, etc., can solve the problems of being unable to meet the needs of consumers with diverse functions, and not being able to take into account low-density mechanical properties, strength and other comprehensive properties. Achieve broad market application prospects, light weight, and low compression set

Pending Publication Date: 2020-09-22
QUANZHOU YUANLI SHOES MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 1. Low density and good mechanical properties cannot be well taken into account, or due to poor foaming effect, the mechanical properties and other properties are greatly reduced, and the comprehensive properties such as strength are poor;
[0007] 2. The rebound rate is average, the compression permanent deformation is large, the elasticity is poor, and the permanent deformation is easy to occur during use;
[0008] 3. It does not have antibacterial properties, or uses silver antibacterial agents, which affects mechanical properties, etc., and is toxic, unhealthy, and does not have health care functions, and cannot meet the needs of consumers for diverse functions.

Method used

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  • Traditional Chinese medicine antibacterial PU foaming shoe material with good moisture absorption performance and preparation method thereof
  • Traditional Chinese medicine antibacterial PU foaming shoe material with good moisture absorption performance and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A traditional Chinese medicine antibacterial PU foam shoe material with good hygroscopic performance is made of the following raw materials by weight:

[0045] 80-90 parts of polyurethane, 10-14 parts of styrene-ethylene-butadiene-styrene block copolymer, 4-6 parts of oxidized polyethylene, 4-6 parts of epoxy soybean oil, 2-2.6 parts of cnidium, 1.4-1.8 parts of dandelion, 2.4-3.6 parts of carboxymethyl cellulose, 1.8-2.2 parts of 4-methylbenzenesulfonyl hydrazide, 0.6-0.75 parts of triethylenediamine, 0.08-0.1 parts of triallyl isocyanurate 5-9 parts of filler, 1.2-1.6 parts of zinc oxide, 2.5-4 parts of stearic acid, 1.5-2.7 parts of zinc stearate;

[0046] Wherein, the mixed powder of Fructus Cnidii and Dandelion is coated with epoxy soybean oil;

[0047] Wherein, the polyurethane is a mixture of polyester polyurethane and polyether polyurethane, and the mass ratio of the two is 1: (0.55-0.65).

[0048] In this embodiment, the traditional Chinese medicine antibacte...

Embodiment 2

[0068] A traditional Chinese medicine antibacterial PU foam shoe material with good hygroscopic performance is made of the following raw materials by weight:

[0069] 80 parts of polyurethane, 10 parts of styrene-ethylene-butadiene-styrene block copolymer, 4 parts of oxidized polyethylene, 4 parts of epoxy soybean oil, 2 parts of cnidium, 1.4 parts of dandelion, 2.4 parts of carboxymethyl cellulose 1.8 parts of 4-methylbenzenesulfonyl hydrazide, 0.6 parts of triethylenediamine, 0.08 parts of triallyl isocyanurate, 5 parts of filler, 1.2 parts of zinc oxide, 2.5 parts of stearic acid, stearic acid Zinc 1.5 parts;

[0070] Wherein, the mixed powder of Fructus Cnidii and Dandelion is coated with epoxy soybean oil;

[0071] Wherein, the polyurethane is a mixture of polyester polyurethane and polyether polyurethane, and the mass ratio of the two is 1:0.55.

[0072] In this embodiment, the Fructus Cnidii is the powder of Fructus Cnidii seeds, and the dandelion is the powder of dri...

Embodiment 3

[0089] A traditional Chinese medicine antibacterial PU foam shoe material with good hygroscopic performance is made of the following raw materials by weight:

[0090] 90 parts of polyurethane, 14 parts of styrene-ethylene-butadiene-styrene block copolymer, 6 parts of oxidized polyethylene, 6 parts of epoxy soybean oil, 2.6 parts of cnidium, 1.8 parts of dandelion, 3.6 parts of carboxymethyl cellulose 2.2 parts of 4-methylbenzenesulfonyl hydrazide, 0.75 parts of triethylenediamine, 0.1 part of triallyl isocyanurate, 9 parts of filler, 1.6 parts of zinc oxide, 4 parts of stearic acid, stearic acid Zinc 2.7 parts;

[0091] Wherein, the mixed powder of Fructus Cnidii and Dandelion is coated with epoxy soybean oil;

[0092] Wherein, the polyurethane is a mixture of polyester polyurethane and polyether polyurethane, and the mass ratio of the two is 1:0.65.

[0093] In this embodiment, the Fructus Cnidii is the powder of Fructus Cnidii seeds, and the dandelion is the powder of drie...

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Abstract

The invention discloses a traditional Chinese medicine antibacterial PU foaming shoe material with good moisture absorption performance and a preparation method thereof. The material is prepared fromthe following raw materials in parts by weight: 80-90 parts of polyurethane, 10-14 parts of styrene-ethylene-butadiene-styrene block copolymer, 4-6 parts of polyethylene oxide, 4-6 parts of epoxidizedsoybean oil, 2-2.6 parts of fructus cnidii, 1.4-1.8 parts of dandelion, 2.4-3.6 parts of carboxymethyl cellulose, 1.8-2.2 parts of 4-methylbenzenesulfonyl hydrazine, 0.6-0.75 part of triethylene diamine, 0.08-0.1 part of triallyl isocyanurate, 5-9 parts of a filling material, 1.2-1.6 parts of zinc oxide, 2.5-4 parts of stearic acid and 1.5-2.7 parts of zinc stearate. The traditional Chinese medicine antibacterial PU foaming shoe material with the good moisture absorption performance is small in density and light in weight; the antibacterial rate is high, and the antibacterial performance is good; the tensile strength is high and the mechanical property is good; the resilience rate is high, the compression set rate is low, and the elasticity is good; the comprehensive performance is excellent, and durability and antibiosis are achieved.

Description

technical field [0001] The invention relates to the field of PU foam materials, in particular to a traditional Chinese medicine antibacterial PU foam shoe material with good hygroscopic performance and a preparation method thereof. Background technique [0002] With the rapid development of the footwear industry, the varieties of sole materials are increasingly diversified. The polyvinyl chloride and rubber solid soles that dominate the traditional footwear industry have been gradually replaced by the emerging rubber and plastic foam shoes. The main materials of foam soles generally include polyvinyl chloride (PVC), polyethylene (PE), styrene-butadiene-styrene copolymer (SBS), polyurethane (PU), ethylene-vinyl acetate copolymer (EVA) )Wait. [0003] Polyurethane material is the abbreviation of polyurethane, the English name is polyurethane, it is a kind of polymer material. Polyurethane is an emerging organic polymer material, known as the "fifth largest plastic", and is ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/06C08L75/08C08L53/02C08L23/30C08L91/00C08L1/28C08K13/06C08K9/10C08K5/00C08K3/34C08K3/36C08K3/22C08K5/09C08K5/098C08K5/17C08K5/3492C08J9/10A43B13/04
CPCC08J9/105C08J9/0061C08J9/0066C08J9/0071C08J9/009C08J9/0095C08J9/0023C08J9/0028A43B13/04C08J2375/06C08J2475/08C08J2453/02C08J2423/30C08J2491/00C08J2401/28C08K13/06C08K9/10C08K5/0058C08K3/34C08K3/36C08K3/22C08K2003/2241C08K2201/011C08K2003/2296C08K5/09C08K5/098C08K5/17C08K5/34924C08J2203/04
Inventor 张连锋
Owner QUANZHOU YUANLI SHOES MATERIAL
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