Mechanoluminescent element and preparation method thereof
A stress luminescence and component technology, which is applied in the application of optical methods for fluid pressure measurement, luminous paint, and measurement of force by measuring the change of optical properties of materials when they are stressed. It can solve weak luminous intensity and low light detection difficulties. problem, to achieve the effect of high compressive strength and enhanced photoluminescence effect
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Embodiment 1
[0128] A blue mechanoluminescent ceramic material with a chemical composition of Ca 0.98 Al 3 o 4 N: 0.01Eu 2+ , 0.01Nd 3+ .
[0129] With high purity CaCO 3 、Al 2 o 3 , AlN, Eu 2 o 3 and Nd 2 o 3 As a raw material, according to the chemical composition Ca 0.98 Al 3 o 4 N:0.01Eu 2+ , 0.01Nd 3+ The ratio of each element in the formula is accurately weighed raw materials; agate balls are used as grinding balls, absolute ethanol is used as a ball milling medium, agate balls, absolute ethanol and raw materials are put into a ball milling tank at the same time, and ball milling is carried out on a planetary ball mill. feed for 5 hours to form a slurry-like mixture, the mass ratio of the absolute ethanol to the raw material is 2:3; the obtained slurry-like mixture is placed in an oven, and dried for 5 hours at 80 ° C, and then The raw materials obtained after drying are passed through a 200-mesh sieve to obtain uniformly mixed raw materials; a certain amount of unifo...
Embodiment 2
[0131] A blue mechanoluminescent ceramic material with a chemical composition of Ca 0.98 Al 3 o 4 N: 0.01Eu 2+ , 0.01Sm 3+ .
[0132] With high purity CaCO 3 、Al 2 o 3 , AlN, Eu 2 o 3 and Sm 2 o 3 As a raw material, according to the chemical composition Ca 0.98 Al 3 o 4 N:0.01Eu 2+ , 0.01Sm 3+ The ratio of each element in the formula is accurately weighed raw materials; agate balls are used as grinding balls, absolute ethanol is used as a ball milling medium, agate balls, absolute ethanol and raw materials are put into a ball milling tank at the same time, and ball milling is carried out on a planetary ball mill. feed for 10 hours to form a slurry-like mixture, the mass ratio of the absolute ethanol to the raw material is 2:3; the obtained slurry-like mixture is placed in an oven, and dried for 4 hours at 80 ° C, and then The raw materials obtained after drying are passed through a 200-mesh sieve to obtain uniformly mixed raw materials; a certain amount of unif...
Embodiment 3
[0134] A blue mechanoluminescent ceramic material with a chemical composition of Ca 0.92 Al 3 o 4 N: 0.04Eu 2+ , 0.02Nd 3+ , 0.02Sm 3 + .
[0135] With high purity CaCO 3 、Al 2 o 3 , AlN, Eu 2 o 3 、Nd 2 o 3 and Sm 2 o 3 As a raw material, according to the chemical composition Ca 0.92 Al 3 o 4 N: 0.04Eu 2+ , 0.02Nd 3+ , 0.02Sm 3+ The ratio of each element in the formula is accurately weighed raw materials; agate balls are used as grinding balls, absolute ethanol is used as a ball milling medium, agate balls, absolute ethanol and raw materials are put into a ball milling tank at the same time, and ball milling is carried out on a planetary ball mill. feed for 20 hours to form a slurry-like mixture, the mass ratio of the absolute ethanol to the raw material is 2:3; the obtained slurry-like mixture is placed in an oven, and dried at 80°C for 6 hours, and then The raw materials obtained after drying are passed through a 200-mesh sieve to obtain uniformly mixed ...
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