Coated substrates and methods of preparing the same
A substrate and coating technology, applied in the direction of coating, primer, electrophoretic plating, etc., can solve the problems of low film forming rate, weakening, and inability to obtain characteristics or characteristics.
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example 1 and example 2
[0119] Preparation and Application of Treatment Solution Containing Catalyst
[0120] A catalyst-containing solution was first prepared from the components listed in Table 1.
[0121] Table 1
[0122]
[0123] 1 Triethylenediamine catalyst, commercially available from Evonik Industries.
[0124] 2 Nonionic surfactants commercially available from DOW.
[0125] 3 Hydrotropes, nonionic surfactant solubilizers and electrostatic agents are commercially available from Alfa Chemicals.
[0126] Example 1 and Example 2 were weighed into separate containers and mixed with a wooden spatula until uniform.
example 3
[0128] Preparation of Liquid Coating Compositions
[0129] Liquid coating compositions were prepared from the ingredients listed in Table 2. The components of the liquid coating composition were added in the order listed, stirring with a wooden spatula after each addition.
[0130] Table 2
[0131]
[0132] 4 Pentafunctional acrylate, commercially available from Allnex.
[0133] 5 Dimethicone flow additive commercially available from BYK-Chemie GMBH.
[0134] 6 Hydroxyphenyl triazine UV absorber, commercially available from BASF.
[0135] 7 A hindered amine light stabilizer, commercially available from BASF.
[0136] 8 5% by weight solution of triethylenediamine in n-butyl acetate.
[0137] 9 Pentaerythritol tetrakis(3-mercaptopropionate), commercially available from BRUNO BOCK Chemische Fabrik GmdH & Co. KG.
example 4
[0139] Preparation and evaluation of coated substrates
[0140] Half of the 4 inch by 12 inch split metal panels were immersed in the treatment solutions of Examples 1 and 2 for 1 minute. After removal, dry the submerged section using a forced-air hand dryer. The panels were then coated with the formulation of Example 3 on both sides of the panels using a Devilbiss HVLP gun equipped with a 1.4 mm nozzle and 30 psi pressure. The resulting panels were then cured at room temperature for 24 hours.
[0141] The coated substrates were tested by the R-value test previously described herein. The average edge coverage of each coated substrate was also tested.
[0142] Edge coverage was tested using FE-SEM analysis. For edge coverage testing, small squares were cut from each panel's unfinished areas (upper right and upper left) and areas treated with a panel cutter (lower right and left edges) and placed in epoxy In resin overnight. Once cured, the base was sanded, polished, and p...
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