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Preparation method of P92 steel with Al-Ca composite reamed wire refined inclusions

A technology of inclusions and al-ca, applied in the field of iron and steel materials, can solve the problems of CaO nano-grain refinement and inclusions, and achieve the effect of shortening the steelmaking process and reducing costs

Active Publication Date: 2021-09-07
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, Al-Ca composite hinge wire is added during the smelting process, and Al is directly generated in the melt. 2 o 3 The method of refining inclusions of CaO nanocrystals is rarely reported

Method used

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  • Preparation method of P92 steel with Al-Ca composite reamed wire refined inclusions
  • Preparation method of P92 steel with Al-Ca composite reamed wire refined inclusions
  • Preparation method of P92 steel with Al-Ca composite reamed wire refined inclusions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] (1) Alloy composition (mass percent) is:. 0.11wt% C, 0.4wt% Mn, 0.2wt% Si, 0.12wt% P, 0.01wt% S, 8.68wt% Cr, 0.29wt..... .% Ni, 0.46wt.% Mo, 0.18wt.% V, 1.67wt.% W, 0.01wt.% Ti, 0.001wt.% B, 0.007wt.% Al, 0.001wt.% Ca, 0.03wt.% . N, 0.003wt (corresponding to 30ppm)% O, the balance of Fe;

[0051] (2) using a vacuum melting furnace heating method, heating the alloy melted into molten steel, the molten steel after completely melted, alloying operation, and then heated superheater 55 ℃, molten steel surface to be stabilized;

[0052] (3) figure 2 Shown, after LF refining operations, by feeding filament yarn feeding method using a stirring machine such as a center fed toward the molten steel 10 figure 1 φ0.7mm shown Al-Ca composite hinge wire;

[0053] (4) while feeding the wire, the bottom-blown inert gas flow field is formed in the melt;

[0054] Measuring the oxygen concentration, oxygen free VD refining operation at around 10ppm (5) completion of feeding wire;

[0055] (6) ...

Embodiment 2

[0063] (1) Alloy composition (mass percent) is:. 0.11wt% C, 0.4wt% Mn, 0.2wt% Si, 0.12wt% P, 0.01wt% S, 8.68wt% Cr, 0.29wt..... .% Ni, 0.46wt.% Mo, 0.18wt.% V, 1.67wt.% W, 0.01wt.% Ti, 0.001wt.% B, 0.007wt.% Al, 0.001wt.% Ca, 0.03wt.% N, 0.003wt. (corresponding to 30ppm)% O, balance of Fe.

[0064] (2) using a vacuum melting furnace heating method, heating the alloy melted into molten steel, the molten steel after completely melted, alloying operation, and then heated superheater 80 ℃, molten steel surface to be stabilized;

[0065] (3) figure 2 Shown, after LF refining operation, feeding by using a filament yarn feeding method of stirring molten steel feeding machine 12 as the center figure 1 φ1.5mm shown Al-Ca composite hinge wire;

[0066] (4) while feeding the wire, the bottom-blown inert gas flow field is formed in the melt;

[0067] Measuring the oxygen concentration, oxygen free VD refining operation at around 10ppm (5) completion of feeding wire;

[0068] (6) VD after the ...

Embodiment 3

[0074] (1) Alloy chemical composition (mass percent) is: 0.11 wt.% C, 0.4 wt.% MN, 0.2 wt.% Si, 0.12 wt.% P, 0.01 wt.% S, 8.68 wt.% Cr, 0.29 wt .% Ni, 0.46 wt.% MO, 0.18 wt.% V, 1.67 wt.% W, 0.01 wt.% Ti, 0.001 wt.% B, 0.007 wt.% Al, 0.001 wt.% CA, 0.03 wt.% N, 0.003 wt.% (Equivalent to 30 ppm) O, margin Fe.

[0075] (2) Using the electric furnace to heat the heating method, the alloy is heated into a steel liquid. After all the steel fluid is melted, the alloy operation is performed, and the heat rise is 95 ° C, and the surface of the steel is stabilized.

[0076] (3) figure 2 As shown, after the LF furnace refining operation, the filament machine is fed into the steel liquid center by feeding the filament. figure 1 The φ2.7 mm Al-CA composite hinge is shown;

[0077] (4) While feeding, the bottom inert gas forms a flow field in the melt;

[0078] (5) After the filament is completed, the oxygen concentration is measured, and the free oxygen is carried out at 10 ppm or the VD refi...

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Abstract

The invention discloses a preparation method of P92 steel with Al-Ca composite reamed wire refined inclusions, and belongs to the technical field of steel and iron materials. The method comprises the steps that Al-(1.5-30) wt.% Ca composite reamed wires are fed into molten steel with the oxygen concentration of 5-100 ppm through a wire feeding and stirring method, a flow field is formed in a melt in an inert gas bottom blowing mode, molten steel containing O, Al and Ca is obtained, then pouring is conducted at the cooling speed not lower than 500 K / min, and finally the P92 steel with the inclusion grade of A+B+C+D+DS smaller than or equal to 1.5 is obtained. The method is suitable for preparing the P92 steel.

Description

Technical field [0001] The present invention belongs to the technical field of steel materials, a method for preparing a steel P92 Al-Ca composite hinge wire refined inclusions. Background technique [0002] P92 steel is T / P91 steel foundation developed new improved steel, is a novel ferritic heat-resistant steel. P92 steel with good heat resistant properties, weldability and process performance, and the stress corrosion cracking susceptibility and low production cost without, is widely used in high pressure boiler superheater and reheater tubes, and thermal power stations the main steam pipe. The main advantages of the P92 steel is at the same operating temperature, pressure, or the design life conditions, can further reduce the quality of power plant boiler and duct systems. At the same overall size, the temperature can be further improved design of the structure, thereby improving the thermal efficiency of the system, P92 steel in recent years been more and more applications...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C7/00C21C7/072
CPCC21C7/0056C21C7/0006C21C7/072
Inventor 陈晓华于惠雯王自东赵思远王艳林陈凯旋
Owner UNIV OF SCI & TECH BEIJING